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MSDS - Pine Needle - Pinus sylvestris - Essential Oil


PINE NEEDLE SYLVESTRIS ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Pine Needle Oil Sylvestris

Biological Definition

Pinus Sylvestris Leaf Oil is the volatile oil obtained from the needles of the Scotch Pine, Pinus sylvestris L., Pinaceae

INCI Name

Pinus Sylvestris Leaf Oil

Synonyms & Trade Names

-

CAS-No

8023-99-2 / 84012-35-1

EC No.

- / 281-679-2

EINECS No.

- / 281-679-2

1.2

Relative identified uses of the substance or mixture and uses advised against

 

Perfumes, fragrances.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

Harmful

Dangerous for the environment

Classification (EC 1272/2008)

 

Physical and Chemical Hazards : Flam. Liq. 3 (H226)

Human health Asp. : Asp. Tox. 1 - H304

Skin Sens. 1 (H317)

Environment : Aquatic Chronic 1 - H410

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

     GHS07                GHS09              GHS08           GHS02

http://www.hse.gov.uk/chemical-classification/images/pictogram-gallery/irritant.gif      Environmentally damaging           Flammable

 

Signal Word

Danger

Contains

α-pinene, β-pinene, limonene, camphene

Hazard Statements

 

H226Flammable liquid and vapour.

H304May be fatal if swallowed and enters airways.

H317May cause an allergic skin reaction.

H411Very toxic to aquatic life with long lasting effects.

Precautionary Statements

 

P280 Wear protective gloves/protective clothing/eye protection/face protection

P210Keep away from heat/sparks/open flames/hot surfaces. No smoking.

 

P301/P330/P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P310Immediately call a POISON CENTER or doctor/physician.

P273Avoid release to the environment.

P501Dispose of contents/container to regional, national regulation.

Supplementary Precautionary Statements

 

None

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available

Adverse physio-chemical properties

No additional data available

Adverse effects on human health

No additional data available

03. COMPOSITION/INFORMATION ON INGREDIENTS

3.1

Substances

 

70-85% alpha-Pinene CAS-No.: 80-56-8 EC No.: 201-291-9

 

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

 

 

2-7%  beta-Pinene Cas. No: 127-91-3EC No: 204-872-5

 

Classification (EC 1272/2008);  Danger, Flam. Liq. 3 – H226, Skin Sens. 1 – H317 , Asp Tox. 1 – H304, Aquatic Chronic 1 – H410

 

 

3-7% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

 

 

1-5% Camphene CAS-No 79-92-5, EC 201-234-8

 

Classification (EC 1272/2008);  Flam. Sol. 1 – H228, Eye Irrit 2 – H319, Aquatic Acute 1 – H400

 

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Remove immediately from source of exposure into fresh air. Seek medical attention if any discomfort continues.

 Ingestion

DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Seek medical attention.

Skin Contact 

Remove contaminated clothing immediately and wash skin with soap and water. Seek medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Seek medical attention immediately. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

 

Observe risk of aspiration if vomiting occurs.

4.3

Indication of any immediate medical attention and special treatment needed

 

Treat symptomatically

05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Extinguishing media: Carbon dioxide (CO2). Powder. Foam.

Unsuitable extinguishing media: Full water jet.

5.2 

Special hazards arising from the product

 

Fires of liquids or liquid turning substances - In case of fire toxic fumes like carbon monoxide and carbon dioxide may be liberated. Burning produces heavy smoke

5.3 

Advice for firefighters

 

Move undamaged containers from immediate hazard area if it can be done safely. Use suitable breathing apparatus. Wear suitable equipment for self protection.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Wear protective clothing as described in Section 8 of this safety data sheet. Handle the product using protective gloves resistant to the chemicals exposed. Avoid contact with skin, eyes and clothing. Maintain adequate ventilation in the working area after spilling.

6.2 

Environmental Precautions

 

Do not discharge into drains, water courses or onto the ground. Contain spillages.

6.3 

Methods and material for containment and cleaning up.

 

Cover with an inert, inorganic, non-combustible absorbent material (e.g dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Dispose of in accordance with current laws and regulations.

6.4 

Reference to other sections

 

Sections 7 and 8

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Handle in accordance with good hygiene and safety practice. Provide earthing of containers, equipment, pumps and ventilation facilities. Take precautionary measures against static discharges. Wear personal protective clothing (see section 8). Do not breathe gas/fume/vapour/spray. Use only in well-ventilated areas. When using do not eat, drink, smoke, sniff.

7.2 

Conditions for safe storage, including any incompatibilities

 

Keep product container tightly closed, in a dry, ventilated area, away from potential sources of ignition and protected from light.

7.3 

Specific end use(s) 

 

No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

No additional data available

8.2 

Exposure controls 

Protective Equipment

 

      http://www.hse.gov.uk/workplacetransport/images/mandatory-overalls-2.gif

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

If adequate ventilation is not provided, use respiratory equipment.

Hand Protection

Wear chemical resistant gloves (PVC) according to EN374. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Take recovery periods for skin regeneration.

Eye Protection

Wear approved safety goggles according to EN166.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Avoid contact with skin and eyes. Avoid inhalation of vapours.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Mobile Liquid

Colour

Colourless to slight yellow

Odour

 Characteristic

Relative Density

0.857  -  0.875 @ 20°C

Flash Point (°C)

36

Refractive Index

1.465 - 1.475 @ 20°C

Melting Point (°C)

No additional data available

Boiling Point (°C)

No additional data available

Vapour Pressure

No additional data available

Solubility in Water @20°C

Insoluble in water. Soluble in Ethanol at a ratio of 1:5

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.

10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

Avoid contact with; strong oxidising agents, strong reducing agents, acids, bases, acid anhydride and alkali metals.

10.2 

Chemical stability

 

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

 

No hazardous reactions at proper usage and handling.

10.4 

Conditions to Avoid

 

Temperatures more than room temperature will benefit the transfer from liquid to vapour phase and formation of explosive atmospheres. Storing the product in open containers will benefit the formation of peroxides and derogate the quality.

10.5 

Incompatible materials

 

No additional data available

10.6 

Hazardous Decomposition Products

 

No dangerous decomposition products known.

11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

LD50 (oral) in mg/kg: > 5000

LD50 (dermal) in mg/kg: > 5000

 

Skin corrosion / irritation

No additional data available

 

Serious eye damage / irritation

No additional data available

 

Respiratory or skin sensitisation

No additional data available

 

Germ Cell Mutagenicity

No additional data available

 

Carcinogenicity

No additional data available

 

Reproductive toxicity

No additional data available

 

STOT-single exposure

No additional data available

 

STOT-repeated exposure

No additional data available

 

Aspiration hazard

No additional data available

 

Photo-toxicity

No additional data available

 

Other Information

No additional data available

12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

No additional data available

12.2 

Persistence & degradability

 

No additional data available.

12.3 

Bioaccumulation Potential

 

No additional data available

12.4 

Mobility in soil

 

No additional data available

12.5 

Results of PBT and vPvB Assessment

 

No additional data available

12.6 

Other adverse effects

 

Do not allow product to enter streams, sewers or other waterways. Water Hazard Class; WGK-2

13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Collect and dispose of waste product in accordance with local authority guidelines using a hazardous chemical disposal company. Product remainders should not intrude soil or waters.

14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

1272

 

UN No. SEA

1272

 

UN No. AIR

1272

14.2 

UN proper shipping name

 

Pine Oil

14.3 

Transport hazard class(es)

 

ADR/RID/ADN Class; 3 Flammable Liquid

ADR/RID/ADN Class: 3 Flammable Liquid

IMDG Class: 3 Flammable Liquid

ICAO Class/Division: 3 Flammable Liquid

 

Transport Labels

 

Vehicle label 250mm x 250mm Class 3

 

14.4 

Packing group

 

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant

 

 

14.6 

Special precautions for user

 

See sections 6-8

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

Packed and transferred according to transport regulations.

15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.

16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H226Flammable liquid and vapour.

H228     Flammable Soild

H304May be fatal if swallowed and enters airways.

H315     Causes skin irritation

H317May cause an allergic skin reaction.

H319     Causes serious eye irritation.

H400     Very toxic to aquatic life.

H410     Very toxic to aquatic life with long lasting effects.

H411Very toxic to aquatic life with long lasting effects.

Other Information

None

Revision Date

28/07/2015

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Pine Needle, Pinus sylvestris