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MSDS - Lime - Citrus aurantifolia - Essential Oil


LIME (Distilled) ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Lime Oil Distilled

Biological Definition

Citrus Aurantifolia Oil is the volatile oil obtained from the fruits of the Lime, Citrus aurantifolia, Rutaceae.

INCI Name

Citrus Aurantifolia Oil

Synonyms & Trade Names

Lime Oil WI Distilled

CAS-No

8008-26-2 / 90063-52-8

EC No.

- / 290-010-3

EINECS No.

- / 290-010-3

1.2

Relative identified uses of the substance or mixture and uses advised against

 

Flavours, Fragrances: Use in accordance with good manufacturing and industrial hygiene practices.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952









02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

 

Flammable Liquid, Hazard Category 3

Skin Corrosion / Irritation Category 2

Sensitization - Skin Category 1

Aspiration Hazard Category 1

Hazardous to the Aquatic Environment - Long-term Hazard Category 2

H226, Flammable liquid and vapour.

H304, May be fatal if swallowed and enters airways.

H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H411, Toxic to aquatic life with long lasting effects.

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

      GHS02GHS07           GHS08  GHS09

  flamme     C:\SharedDrive\Callum\Images & Logo\download.png  

 

Signal Word

Danger.

Contains

-

Hazard Statements

 

H226, Flammable liquid and vapour.

H304, May be fatal if swallowed and enters airways.

H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H411, Toxic to aquatic life with long lasting effects.

Precautionary Statements

 

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking.

P233, Keep container tightly closed.

P240, Ground/bond container and receiving equipment.

P241, Use explosion-proof electrical, ventilating and lighting equipment.

P242, Use only non-sparking tools.

P243, Take precautionary measures against static discharge.

P261, Avoid breathing vapour or dust.

P264, Wash hands and other contacted skin thoroughly after handling.

P272, Contaminated work clothing should not be allowed out of the workplace.

P273, Avoid release to the environment.

P280, Wear protective gloves/eye protection/face protection.

P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing.

Rinse skin with water/shower.

P331, Do not induce vomiting.

P333/313, If skin irritation or rash occurs: Get medical advice/attention.

P362, Take off contaminated clothing and wash before reuse.

P370/378, In case of fire:

P403/235, Store in a well-ventilated place. Keep cool.

P405, Store locked up.

P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Supplementary Precautionary Statements

 

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.





03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2

Mixtures

 

55.73% d-Limonene CAS-No: 5989-27-5; EC No.: 227-813-5

 

Classification (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1-EH  A1-EH C1;H226-H304- H315-H317-H410,-

 

 

17.35% γ-Terpinene (p-mentha-1,4-diene) CAS No99-85-4 ; EC No: 202-794-6

 

Classification (EC 1272/2008) FL 3-AH 1;H226-H304,-

 

 

9.65% Terpinolene CAS No: 586-62-9EC No: 209-578-0

 

Classification (EC 1272/2008)  SS 1B-AH 1-EH A1-EH C1; H304-H317-H410,-

 

 

8.3% p-Mentha-1,3-diene  CAS No: 99-86-5 EC No: 202-795-1

 

Classification (EC 1272/2008) FL 3-ATO 4-AH 1-EH C2;  H226-H302-H304-H411,-

 

 

 

3.51% p-Cymene  CAS No: 99-87-6EC No:  202-796-7

 

Classification (EC 1272/2008) FL 3-AH 1-EH C2;H226- H304-H411,-

 

 

3.5% Eucalyptol  CAS No: 470-82-6EC No: 207-431-5

 

Classification (EC 1272/2008) FL 3-SS 1B;H226-H317,-

 

 

3.5% 1,4-CineoleCAS No: 470-67-7EC No: 20-428-9

 

Classification (EC 1272/2008) FL 3;H226,-

 

 

3.475% alpha-TerpineolCAS No: EC No:

 

Classification (EC 1272/2008) SCI 2-EDI 2;H315-H319,-

 

 

2.835% α-Pinene  CAS No: 80-56-8 ; EC No: 201-291-9

 

Classification (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1-EH A1-EH C1;H226-H304- H315-H317-H410,-

 

 

2.665% β-Pinene  CAS No: 127-91-3 ; EC No: 20-872-5

 

Classification (EC 1272/2008). FL 3-SCI 2-SS 1B-AH 1-EH A1-EH C1;H226-H304- H315-H317-H410,-

 

 

1.5% Myrcene CAS No: 123-35-3 EC No: 204-622-5

 

Classification (EC 1272/2008) FL 3-SCI 2-EDI 2-AH 1; H226-H304-H315-H319,-

 

 

0.825% l-.beta.-BisaboleneCAS No: 495-61-4EC No: n/a

 

Classification (EC 1272/2008)  SCI 2-SS 1B-AH 1;H304- H315-H317,

 

 

0.736% Citral  CAS No: 5392-40-5  EC No: 226-394-6

 

Classification (EC 1272/2008). SCI 2-EDI 2-SS 1B;H315- H317-H319,-

 

 

0.495% Camphene  CAS No: 79-92-5EC No: 201-234-8

 

Classification (EC 1272/2008) FS 2-EDI 2-EH A1-EH C1; H228-H319-H410,-

 

 

0.495% Beta-CaryophylleneCAS No: 87-44-5EC No: 201-746-1

 

Classification (EC 1272/2008) AH 1;H304,-

 

 

0.495% alpha-PhellandreneCAS No: 99-83-2EC No: 202-792-5

 

Classification (EC 1272/2008) FL 3-AH 1;H226-H304,-

 

 

0.33% Decanal CAS No: 112-31-2; EC No: 203-872-5

 

Classification (EC 1272/2008) EDI 2-EH C3;H319-H412,-

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Remove from exposure area to fresh air. Obtain medical advice immediately.

Ingestion

Wash mouth out with water and obtain medical advice immediately.

Skin Contact 

Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical advice if irritation persists or there is any sign of tissue damage.

Eye Contact   

Flush with plenty of water and seek medical advice.

4.2

Most important symptoms and effects, both acute and delayed

 

May be fatal if swallowed and enters airways.

Causes skin irritation.

May cause an allergic skin reaction.

4.3

Indication of any immediate medical attention and special treatment needed

 

None expected, see Section 4.1 for further information.

 




05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Suitable extinguishing media:CO2, Dry powder, Foam.

 

5.2 

Special hazards arising from the product

 

In case of fire, Carbon monoxide, Unidentified organic compounds may be liberated.

5.3 

Advice for firefighters

 

In case of insufficient ventilation, wear suitable respiratory equipment.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.

6.2 

Environmental Precautions

 

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

 

Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations.

6.4 

Reference to other sections

 

See sections 8 and 13.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Keep away from heat, sparks, open flames and hot surfaces. - No smoking.

7.2 

Conditions for safe storage, including any incompatibilities

 

Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

7.3 

Specific end use(s) 

 

Flavours, Fragrances: Use in accordance with good manufacturing and industrial hygiene practices.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

Workplace exposure limits: Not Applicable

8.2 

Exposure controls 

Protective Equipment

 

 

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7.

Hand Protection

Wear protective gloves/eye protection/face protection.

Eye Protection

Wear protective gloves/eye protection/face protection.

Other Protection

No additional data available.  

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.





09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid, Virtually colourless to pale yellow / green.

Colour

Virtually colourless to pale yellow / green.

Odour

Characteristic – Fresh, citrus, lime

Relative Density

0.849 – 0.859 @ 20°C

Flash Point (°C)

40

Refractive Index

1.470 to 1.478 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.

 




10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

Presents no significant reactivity hazards, by itself or in contact with water.

10.2 

Chemical stability

 

Stable under normal temperature and storage conditions and recommended use.

10.3 

Possible hazardous reactions

 

Not expected under normal temperature conditions and recommended use.

10.4 

Conditions to Avoid

 

Avoid extreme heat.

10.5 

Incompatible materials

 

Avoid contact with strong acids, alkalis and oxidising agents.

10.6 

Hazardous Decomposition Products

 

Not expected under normal temperature conditions and recommended use.




11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: 5934.41

Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: n/a

Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: n/a

Inhalation Route: n/a

 

Skin corrosion / irritation

Causes skin irritation (H315).

 

Serious eye damage / irritation

No additional data available.

 

Respiratory or skin sensitisation

May cause an allergic skin reaction (H317).

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

No additional data available.

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available.

 

STOT-repeated exposure

No additional data available.

 

Aspiration hazard

May be fatal if swallowed and enters airways (H304).

 

Photo-toxicity

No additional data available.

 

Other Information

No additional data available.





12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

Marine pollutant. Toxic to aquatic life with long lasting effects.

12.2 

Persistence & degradability

 

No additional data available.

12.3 

Bioaccumulation Potential

 

No additional data available.

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

 

12.6 

Other adverse effects

 

Do not discharge into the environment especially not into waterways, sewers and the sea.




13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal.




14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

UN 1169

 

UN No. SEA

UN 1169

 

UN No. AIR

UN 1169

14.2 

UN proper shipping name

 

Extracts, Aromatic, Liquid.

14.3 

Transport hazard class(es)

 

ADR/RID/ADN Class:3 Flammable Liquid. 

IMDG Class:3 Flammable Liquid.

ICAO Class/Division:3 Flammable Liquid.

 

Transport Labels

 

File:HAZMAT Class 3 Flammable Liquids.png

14.4 

Packing group

 

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant.

 

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14.6 

Special precautions for user

 

No additional data available.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

No additional data available.





15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.




16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H226, Flammable liquid and vapour.

H304, May be fatal if swallowed and enters airways.

H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H411, Toxic to aquatic life with long lasting effects.

Other Information

Complies with REACH guidance for SDS as circulated by ECHA 2011.

Revision Date

22/08/2016

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Lime, Citrus aurantifolia