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ESTABLISHED 1993

MSDS - Galbanum - Ferula galbaniflua - Essential Oil


GALBANUM ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Galbanum Oil   

Biological Definition

Ferula Galbaniflua Resin Oil is the essential oil obtained from the resin of the Galbanum, Ferula galbaniflua, Apiaceae

INCI Name

Ferula Galbaniflua Resin Oil

Synonyms & Trade Names

-

CAS-No

93165-40-3 / 8023-91-4

EC No.

296-925-4

EINECS No.

296-925-4

1.2

Relative identified uses of the substance or mixture and uses advised against

 

No additional data available.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952









02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements are displayed in Section 16.

 

Classification (EC 1272/2008)

 

Physical and Chemical Hazards : Flammable Liquid, Hazard Category 3,  H 226

Human health Asp. : Skin Corrosion / Irritation Category 2 ,H315

Sensitization - Skin Category 1, H317

Aspiration Hazard Category 1, H304

Environment :Hazardous to the Aquatic Environment - Acute Hazard Cat. 2

Hazardous to the Aquatic Environment - Long-term Hazard Cat. 2,                                                         H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

   GHS02GHS07GHS08GHS09

Flammablehttp://www.hse.gov.uk/chemical-classification/images/pictogram-gallery/irritant.gifEnvironmentally damaging

 

Signal Word

Danger

Contains

-

Hazard Statements

 

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

 

P210 Keep away from heat, sparks, open flames and hot surfaces. - No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical, ventilating and lighting equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing vapour or dust.

P264 Wash hands and other contacted skin thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/eye protection/face protection.

P301/310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303/361/353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

P331 Do not induce vomiting.

P333/313 If skin irritation or rash occurs: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction.

P391 Collect spillage.

P403/235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container to approved disposal site, in accordance with local regulations.

Supplementary Precautionary Statements

 

None

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.





03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2

Mixtures

 

≤ 81.0% beta-PineneCAS-No.: 127-91-3EC No.: 204-872-5

 

Classification (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1;H226-H304- H315-H317

 

 

≤ 6.5% alpha-Pinene CAS-No.: 80-56-8 EC No.: 201-291-9

 

Classification (EC 1272/2008) FL 3-ATO 5-SCI 2-SS 1B-AH 1;H226- H303-H304-H315-H317

 

 

≤ 6.0% Myrcene CAS-No.: 123-35-3 EC No.: 204-622-5

 

Classification (EC 1272/2008) FL 3-SCI 2-EDI 2A-AH 1;H226-H304- H315-H319

 

 

≤ 5.5% delta-3-CareneCAS-No.: 13466-78-9 EC No.: 236-719-3

 

Classification (EC 1272/2008) FL 3-ATO 5-SCI 2-SS 1B-AH 1;H226- H303-H304-H315-H317

 

 

 

 

≤ 2.5% dl-Limonene (racemic) CAS-No.: 138-86-3 EC No.: 205-341-0

 

Classification (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1-EH A1-EH C1; H226-H304-H315-H317-H410

 

 

≤ 2.0% beta-Phellandrene CAS-No.: 555-10-2 EC No.: 209-081-9

 

Classification (EC 1272/2008) FL 3-AH 1;H226-H304

 

 

1.5% Fenchone CAS-No.: 1195-79-5 EC No.: 214-804-6

 

Classification (EC 1272/2008) FL 4-SCI 3;H227-H316

 

 

1.5% 4-Carvomenthenol CAS-No.:  562-74-3EC No.: 209-235-5

 

Classification (EC 1272/2008) FL 4-ATO 4-ATD 5-SCI 2-EDI 2A-EH A3; H227-H302-H313-H315-H319-H402

 

 

1.0% Camphene CAS-No.:  79-92-5EC No.: 201-234-8

 

Classification (EC 1272/2008) FS 2-SCI 3-EDI 2A-EH A1-EH C1;H228- H316-H319-H410

 

 

1.0% p-Cymene CAS-No.: 99-87-6EC No.: 202-796-7

 

Classification (EC 1272/2008) FL 3-ATO 5-SCI 3-AH 1-EH A2-EH C2; H226-H303-H304-H316-H411

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Remove victim immediately from source of exposure. Seek medical attention if any discomfort continues.

 Ingestion

Immediately rinse mouth and provide fresh air. Seek medical attention immediately.

Skin Contact 

Remove contaminated clothing immediately and wash skin with soap and water. Seek medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Seek medical attention immediately. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

 

May be fatal if swallowed and enters airways.

Causes skin irritation.

May cause an allergic skin reaction.

4.3

Indication of any immediate medical attention and special treatment needed

 

None expected, see Section 4.1 for further information.




05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Extinguishing media : Carbon dioxide (CO2). Dry chemical Powder.  Foam.

 

5.2 

Special hazards arising from the product

 

In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds.

5.3 

Advice for firefighters

 

In case of insufficient ventilation, wear suitable respiratory equipment.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.

6.2 

Environmental Precautions

 

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

 

Cover with an inert, inorganic, non-combustible absorbent material (e.g dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Dispose of in accordance with current laws and regulations.

6.4 

Reference to other sections

 

Wear protective clothing as described in Section 8 of this safety data sheet.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Handle in accordance with good hygiene and safety practice.

7.2 

Conditions for safe storage, including any incompatibilities

 

Keep product in its original container well sealed, in a dry, ventilated area, away from potential sources of ignition and protected from light. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

7.3 

Specific end use(s) 

 

Flavours, Fragrances: Use in accordance with good manufacturing and industrial hygiene practices.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

No additional data available.  

8.2 

Exposure controls 

Protective Equipment

 

 

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material 

Hand Protection

Chemical resistant gloves (PVC)

Eye Protection

Wear approved safety goggles.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.





09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid

Colour

Colourless to pale yellow

Odour

Characteristic – green leafy, turpentine, balsamic

Relative Density

0.867  -  0.890 @ 20°C

Flash Point (°C)

42°C

Refractive Index

1.475  -  1.485 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.




10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

Presents no significant reactivity hazard, by itself or in contact with water.

10.2 

Chemical stability

 

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

 

No additional data available.

10.4 

Conditions to Avoid

 

Avoid heat, flames and other sources of ignition.

10.5 

Incompatible materials

 

Avoid contact with strong acids, alkalis or oxidising agents.

10.6 

Hazardous Decomposition Products

 

Not expected.




11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: >5000

Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: >5000

Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: Not Available

Inhalation Route: Not Available

 

Skin corrosion / irritation

Causes skin irritation.

May cause an allergic skin reaction.

 

Serious eye damage / irritation

No additional data available.

 

Respiratory or skin sensitisation

No additional data available.

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

No additional data available.

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available.

 

STOT-repeated exposure

No additional data available.

 

Aspiration hazard

No additional data available.

 

Photo-toxicity

No additional data available.

 

Other Information

May be fatal if swallowed and enters airways.





12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

Toxic to aquatic life with long lasting effects.

12.2 

Persistence & degradability

 

No additional data available.

12.3 

Bioaccumulation Potential

 

No additional data available.

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.

12.6 

Other adverse effects

 

Do not allow product to enter streams, sewers or other waterways.




13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal.




14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

UN 1169

 

UN No. SEA

UN 1169

 

UN No. AIR

UN 1169

14.2 

UN proper shipping name

 

EXTRACTS, AROMATIC, LIQUID

14.3 

Transport hazard class(es)

 

ADR/RID/ADN Class:3

IMDG Class:3

ICAO Class/Division:3

 

 

 

 

 

Transport Labels

 

 

14.4 

Packing group

 

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant

 

 

14.6 

Special precautions for user

 

No additional data available.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

No additional data available.





15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

 

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

 

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.




16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None

Revision Date

18/09/2015

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Galbanum, Ferula galbaniflua