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MSDS - Dill - Peucedanum graveolens - Essential Oil


DILL SEED ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Dill Seed Oil

Biological Definition

Anethum Graveolens Seed Oil is an essential oil obtained from the seeds of the Dill, Anethum graveolens L., Apiaceae. It contains carvone (50%), D-limonene, phellandrene and other terpenes.

INCI Name

Anethum Graveolens Seed Oil

Synonyms & Trade Names

-

CAS-No

90028-03-8 / 8006-75-5

EC No.

289-790-8 / -

EINECS No.

289-790-8 / -

1.2

Relative identified uses of the substance or mixture and uses advised against

 

No additional data available.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952









02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

 

Flammable Liquid, Hazard Category 3.  H226

Aspiration toxicity Category 1 - (H304)

Skin corrosion/irritation Category 2 - (H315)

Skin sensitisation Category 1 - (H317)

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

      GHS02GHS07          GHS08  GHS09

  flamme     C:\SharedDrive\Callum\Images & Logo\download.png  

 

Signal Word

Danger.

Contains

Limonene

Hazard Statements

 

H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H410: Very toxic to aquatic life with long lasting effects.

Precautionary Statements

 

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 

P370+P378: In case of fire: Use water to extinguish. 

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. 

P331: Do NOT induce vomiting. 

P280: Wear protective gloves/protective clothing/eye protection/face protection. 

P501: Dispose of contents in accordance with local, state or national legislation. 

P261: Avoid breathing dust/fume/gas/mist/vapours/spray. 

P321: Specific treatment (see Medical Advice on this label). 

P333+P313: If skin irritation or rash occurs: Get medical advice/attention. 

P362+P364: Take off contaminated clothing. And wash it before reuse. 

P302+P352: IF ON SKIN: Wash with plenty of water. 

P273: Avoid release to the environment.

P391: Collect spillage.

Supplementary Precautionary Statements

 

P264: Wash hands and exposed skin thoroughly after handling. 

P332+P313: If skin irritation occurs: Get medical advice/attention. 

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.





03. COMPOSITION/INFORMATION ON INGREDIENTS

3.1

Substances

 

45 - 55% Carvone CAS No: 2244-16-8  EC No:  218-827-2

 

Classification (EC 1272/2008)  Skin Sens. 1 – H317

 

 

<43% Limonene CAS-No: 5989-27-5EC No: 227-813-5

 

Classification (EC 1272/2008) Flam Liq. 3 - H226, Asp. Tox. 1 - H304, Skin Irrit. 2 - H315,  Skin Sens. 1 - H317,  Aquatic Acute 1  - H400,  Aquatic Chronic 1 - H410

 

 

< 4% (Z)-dihydro Carvone  CAS No: 99-49-0   EC No:  202-759-5

 

Classification (EC 1272/2008) Skin Sens. 1 – H317

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Remove from exposure area to fresh air. Obtain medical advice if discomfort occurs.

Ingestion

Wash mouth out with water and obtain medical advice immediately. DO NOT INDUCE VOMITING!

Skin Contact 

Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical advice if irritation persists or there is any sign of tissue damage.

Eye Contact   

Flush with plenty of water for at least 15 minutes. Remove contact lenses. Seek medical advice.

4.2

Most important symptoms and effects, both acute and delayed

 

Symptoms

Contact: may cause an allergic reaction.

4.3

Indication of any immediate medical attention and special treatment needed

 

Treat symptomatically.




05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.             

5.2 

Special hazards arising from the product

 

Specific hazards arising from the Thermal decomposition can lead to release of irritating and toxic gases and vapours.

5.3 

Advice for firefighters

 

Standard procedure for chemical fires. Spray extinguishing media to base of flames. Wear protective clothing. Avoid inhalation of vapours. Wear suitable respiratory equipment, if insufficient ventilation. Closed containers may build up pressure when exposed to heat and should be cooled with water spray.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

6.2 

Environmental Precautions

 

Do not discharge into drains, water courses or onto the ground. Keep away from surface and ground water. See section 12 for additional information.

6.3 

Methods and material for containment and cleaning up.

 

Remove ignition sources. Ensure adequate ventilation. Absorb with inert, non-combustible, inorganic absorbent material, sweep up and remove to an approved disposal container. Dispose of according to current local authority guidelines.

6.4 

Reference to other sections

 

See sections 4, 8 and 13.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Apply good manufacturing practice & industrial hygiene practices, ensuring proper workplace ventilation. Keep original container closed. Avoid contact with skin and eyes. Observe good personal hygiene, and do not eat, drink or smoke whilst handling.
Keep away from heat, sparks and open flame. Avoid exposing to high temperatures during processing. 

7.2 

Conditions for safe storage, including any incompatibilities

 

Keep container tightly closed in a dry and well-ventilated place.

7.3 

Specific end use(s) 

 

No additional data available.  

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

No additional data available.  

8.2 

Exposure controls 

Protective Equipment

 

 

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation, especially in confined areas.

Respiratory Equipment

Avoid breathing vapours. Respiratory equipment should not be necessary with adequate ventilation.

Hand Protection

Avoid all skin contact. Wear chemical resistant gloves (PVC).

Eye Protection

Avoid contact with eyes. Wear approved safety goggles with built in side shield.

Other Protection

No additional data available.  

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.





09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid

Colour

Pale yellow.  

Odour

Characteristic

Relative Density

Approx. 0.900 @ 20°C

Flash Point (°C)

48 °C

Refractive Index

Approx. 1.485 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.




10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

Stable under normal temperature and storage conditions and recommended use.

10.2 

Chemical stability

 

Stable under normal temperature and storage conditions and recommended use.

10.3 

Possible hazardous reactions

 

Not expected under normal temperature conditions and recommended use.

10.4 

Conditions to Avoid

 

Avoid heat, sparks and open flames.
Avoid exposure to air over prolonged periods.

10.5 

Incompatible materials

 

No additional data available.

10.6 

Hazardous Decomposition Products

 

Not expected under normal temperature conditions and recommended use. In case of combustion; CO2 and CO may be released.




11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

No additional data available.

 

Skin corrosion / irritation


Causes skin irritation.

 

Serious eye damage / irritation

No additional data available.

 

Respiratory or skin sensitisation

May cause an allergic skin reaction.

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

No additional data available.

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available.

 

STOT-repeated exposure

No additional data available.

 

Aspiration hazard

May be fatal if swallowed and enters airways

 

Photo-toxicity

No additional data available.

 

Other Information

No additional data available.





12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

Very toxic to aquatic life with long lasting effects.

12.2 

Persistence & degradability

 

No additional data available.

12.3 

Bioaccumulation Potential

 

No additional data available.

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

No additional data available.

12.6 

Other adverse effects

 

Do not discharge into the environment especially not into waterways, sewers and the sea.




13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Do not release into the environment. Collect waste into suitable containers and contact hazardous chemical disposal company. Containers must be completely empty before disposal.




14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

UN 1169

 

UN No. SEA

UN 1169

 

UN No. AIR

UN 1169

14.2 

UN proper shipping name

 

Extracts, Aromatic, Liquid.

14.3 

Transport hazard class(es)

 

ADR/RID/ADN Class:3 Flammable Liquid. 

IMDG Class:3 Flammable Liquid.

ICAO Class/Division:3 Flammable Liquid.

 

Transport Labels

File:HAZMAT Class 3 Flammable Liquids.png

14.4 

Packing group

 

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant.

 

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14.6 

Special precautions for user

 

No additional data available.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

No additional data available.

 





15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.




16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

Other Information

No additional data available.

Revision Date

13/02/2017

Reason for revision

Updated to new SDS format 

Rev No/Repl, SDS Generated

03 replaces version 02

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Dill, Peucedanum graveolens