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MSDS - Cypress - Cupressus sempervirens - Essential Oil


CYPRESS ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Cypress Oil

Biological Definition

Cupressus Sempervirens Leaf Oil is the volatile oil obtained from the leaves of the Cypress, Cupressus sempervirens L., Pinaceae.

INCI Name

Cupressus Sempervirens Leaf Oil

Synonyms & Trade Names

 

CAS-No

84696-07-1

EC No.

283-626-9

EINECS No.

283-626-9

1.2

Relative identified uses of the substance or mixture and uses advised against

 

Fragrance composition. 

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952









02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

 

Flammable liquid, Category 3 (Flam. Liq. 3, H226).

Skin irritation, Category 2 (Skin Irrit. 2, H315).

Skin sensitisation, Category 1B (Skin Sens. 1B, H317).

Aspiration hazard, Category 1 (Asp. Tox. 1, H304).

Hazardous to the aquatic environment - Acute hazard, Category 1 (Aquatic Acute 1, H400).

Hazardous to the aquatic environment - Chronic hazard, Category 1 (Aquatic Chronic 1, H410).

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

      GHS02GHS07           GHS08  GHS09

  flamme     C:\SharedDrive\Callum\Images & Logo\download.png  

 

Signal Word

Danger.

Contains

PINENES (ALPHA OR BETA)

EC 236-719-3 DELTA-3-CARENE

EC 227-813-5 D-LIMONENE

Hazard Statements

 

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

 

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/...

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P391 Collect spillage.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplementary Precautionary Statements

 

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

The substance does not satisfy the PBT or vPvP criteria in accordance with annexe XIII of the REACH regulations EC 1907/2006.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.





03. COMPOSITION/INFORMATION ON INGREDIENTS

3.1

Substances

 

50-100% Pinenes (Alpha or Beta)  CAS No:EC No

 

Classification (EC 1272/2008) GHS09, GHS07, GHS08, GHS02,  Dgr Flam. Liq. 3, H226,  Asp. Tox. 1, H304,  Skin Sens. 1, H317, Aquatic Acute 1, H400,  M Acute =1,  Aquatic Chronic 1, H410,  M Chronic =1

 

 

10-25% Delta-3-Carene CAS No13466-78-9EC No: 236-719-3

 

Classification (EC 1272/2008) GHS08, GHS02, GHS07,Dgr Asp. Tox. 1, H304,  Flam. Liq. 3, H226,  Skin Irrit. 2, H315, Skin Sens. 1B, H317

 

 

2.5-10% Hydrocarbons CAS No : N/AEC No: N/A

 

Classification (EC 1272/2008) GHS08,  Dgr Asp. Tox. 1, H304

 

 

2.5-10% Terpinyl Acetate CAS No8007-35-0EC No: 232-357-5

 

Classification (EC 1272/2008) GHS09,  Wng Aquatic Chronic 2, H411

 

 

2.5-10% CedrolCAS No77-53-2EC No: 201-035-6

 

Classification (EC 1272/2008)  GHS09,  Wng Aquatic Chronic 2, H411

 

 

< 10.5% d-Limonene CAS-No: 5989-27-5 EC No.: 227-813-5

 

Classification (EC 1272/2008) GHS08, GHS02, GHS07, GHS09,  Dgr Asp. Tox. 1, H304,  Flam. Liq. 3, H226,  Skin Irrit. 2, H315, Skin Sens. 1B, H317,  Aquatic Acute 1, H400,  M Acute = 1, Aquatic Chronic 1, H410,  M Chronic = 1

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Remove from exposure area to fresh air. Obtain medical advice if discomfort continues.

Ingestion

Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.

Seek medical attention immediately, showing the label. If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital immediately by ambulance. Show the label to the doctor.

Skin Contact 

Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. Watch out for any remaining product between skin and clothing, watches, shoes, etc. In the event of an allergic reaction, seek medical attention. If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.

Eye Contact   

Flush with plenty of water and seek medical advice.

4.2

Most important symptoms and effects, both acute and delayed

 

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

 

No additional data available.




05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Suitable extinguishing media:CO2, Dry powder, Foam.

Keep packages near the fire cool, to prevent pressurised containers from bursting. Prevent the effluent of fire-fighting measures from entering drains or waterways.  

5.2 

Special hazards arising from the product

 

A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not breathe in smoke.

In the event of a fire, the following may be formed: carbon monoxide (CO) and carbon dioxide (CO2)

5.3 

Advice for firefighters

 

Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Consult the safety measures listed under headings 7 and 8.

For non first aid workerAvoid any contact with the skin and eyes.

For first aid workerFirst aid workers will be equipped with suitable personal protective                                           equipment (See section 8).

6.2 

Environmental Precautions

 

Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.

Prevent any material from entering drains or waterways.

If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures.

Use drums to dispose of collected waste in compliance with current regulations (see section 13).

6.3 

Methods and material for containment and cleaning up.

 

Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal. Clean preferably with a detergent, do not use solvents.

6.4 

Reference to other sections

 

See sections 8 and 13.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Requirements relating to storage premises apply to all facilities where the substance is handled.

Individuals with a history of skin sensitisation should not, under any circumstance, handle this substance.

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention:

Handle in well-ventilated areas. Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations higher than the occupational exposure limits. Never inhale this               substance. Prevent the accumulation of electrostatic charges with connections to earth. Use the               mixture in premises free of naked flames or other sources of ignition and ensure that electrical               equipment is suitably protected. Keep packages tightly closed and away from sources of heat, sparks               and naked flames. Do not use tools which may produce sparks. Do not smoke. Prevent access by               unauthorised personnel.

Recommended equipment and procedures:

For personal protection, see section 8. Observe precautions stated on label and also industrial safety regulations.

Prohibited equipment and procedures:

No smoking, eating or drinking in areas where the substance is used. Never open the packages under pressure.

7.2 

Conditions for safe storage, including any incompatibilities

 

Storage

Keep the container tightly closed in a dry, well-ventilated place.

Keep away from food and drink, including those for animals.

Keep away from all sources of ignition - do not smoke.

Keep well away from all sources of ignition, heat and direct sunlight.

Avoid accumulation of electrostatic charges.

Packaging

Always keep in packaging made of an identical material to the original.

7.3 

Specific end use(s) 

 

No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

Occupational exposure limits :

- ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) :

CAS TWA :   STEL : Ceiling : Definition : Criteria :

13466-78-9 20 ppm      -   -   -   -

 

8.2 

Exposure controls 

Protective Equipment

 

 

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Provide adequate ventilation.

Hand Protection

Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must be selected according to the application and duration of use at the workstation. Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.

Recommended properties:  - Impervious gloves in accordance with standard EN374

Eye Protection

Avoid contact with eyes. Use eye protectors designed to protect against liquid splashes. Before handling, wear safety goggles in accordance with standard EN166.

Other Protection

No additional data available.  

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area. Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas.

Skin Protection 

Avoid skin contact. Wear suitable protective clothing. Suitable type of protective clothing:  In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact. In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact. Work clothing worn by personnel shall be laundered regularly. After contact with the product, all parts of the body that have been soiled must be washed.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.





09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid, pale yellow to yellow.

Colour

Pale yellow to yellow.

Odour

Characteristic – woody terpenic, rustic.

Relative Density

0.863 – 0.885 @ 20°C

Flash Point (°C)

31.0

Refractive Index

1.466 – 1.477 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.




10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

No additional data available.

 

10.2 

Chemical stability

 

This substance is stable under the recommended handling and storage conditions in section 7.

10.3 

Possible hazardous reactions

 

No additional data available.

10.4 

Conditions to Avoid

 

Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, furnaces etc.) must not be allowed on the premises.

Avoid:

- accumulation of electrostatic charges.

- heating

- heat

- flames and hot surfaces

10.5 

Incompatible materials

 

No additional data available.

10.6 

Hazardous Decomposition Products

 

The thermal decomposition may release/form:    carbon monoxide (CO) and carbon dioxide (CO2)




11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

Acute toxicity:

DELTA-3-CARENE (CAS: 13466-78-9)

Oral route : LD50 = 4800 mg/kg

 

Skin corrosion / irritation

May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours.

 

Serious eye damage / irritation

No additional data available.

 

Respiratory or skin sensitisation

May cause an allergic reaction by skin contact.  

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

Monograph(s) from the IARC (International Agency for Research on Cancer):

CAS 5989-27-5 : IARC Group 3 : The agent is not classifiable as to its carcinogenicity to humans.

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available.

 

STOT-repeated exposure

No additional data available.

 

Aspiration hazard

May be fatal if swallowed and enters airways.

Aspiration toxicity includes severe acute effects such as chemical pneumonia, varying degrees of pulmonary injury or death following aspiration.

 

Photo-toxicity

No additional data available.

 

Other Information

No additional data available.

 





12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

Very toxic to aquatic life with long lasting effects. No aquatic toxicity data available for the substances.

The product must not be allowed to run into drains or waterways.

 

12.2 

Persistence & degradability

 

HYDROCARBONS

Biodegradability: no degradability data is available, the substance is considered as not degrading quickly.

12.3 

Bioaccumulation Potential

 

No additional data available.

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

No additional data available.

12.6 

Other adverse effects

 

Do not discharge into the environment especially not into waterways, sewers and the sea.




13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Proper waste management of the substance and/or its container must be determined in accordance with Directive 2008/98/EC.    Do not pour into drains or waterways.

Waste:

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals. Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company. Do not contaminate the ground or water with waste.  Do not dispose of waste into the environment.

Soiled packaging:

Empty container completely. Keep label(s) on container. Give to a certified disposal contractor




14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

UN 1169

 

UN No. SEA

UN 1169

 

UN No. AIR

UN 1169

14.2 

UN proper shipping name

 

Extracts, Aromatic, Liquid.

14.3 

Transport hazard class(es)

 

ADR/RID/ADN Class:3 Flammable Liquid. 

IMDG Class:3 Flammable Liquid.

ICAO Class/Division:3 Flammable Liquid.

 

Transport Labels

 

File:HAZMAT Class 3 Flammable Liquids.png

14.4 

Packing group

 

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant.

 

C:\Users\t\Desktop\icons\dang to env.jpg

14.6 

Special precautions for user

 

ADR/RID

Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel

3 F1 III 3 30 5 L 601 640E E1 3 D/E

 

IMDG

Class 2°Label Pack gr. LQ EMS Provis. EQ

3   - III 5 L F-E,S-D 223 955 E1

 

IATA

Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ

3 - III 355 60 L 366 220 L A3 E1

3 - III Y344 10 L - - A3 E1

 

For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG.

For excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

No additional data available.





15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.




16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None.

Revision Date

22/08/2016

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Cypress, Cupressus sempervirens