1.1 |
Product Identifier |
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Product Name |
Valerian Root Oil |
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Biological Definition |
The essential oil obtained by steam distillation of the root of Valeriana officinalis L. |
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INCI Name |
Valeriana officinalis root oil |
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Synonyms & Trade Names |
Valerian rhizome oil, Baldrian Oil |
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CAS-No |
97927-02-1 |
EC No. |
308-322-6 |
EINECS No. |
308-322-6 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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Perfumes, fragrances. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements displayed in Section 16. Human health May be fatal if swallowed and enters airways – H304 May cause an allergic skin reaction – H317 Causes serious eye irritation – H319 Very toxic to aquatic life with long lasting effects – H410 Environment The product contains a substance which may cause long term adverse effects in the aquatic environment. |
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Classification (EC 1272/2008) |
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Physical and Chemical Hazards : Not classified. Human health : Asp. Tox. 1 - H304 Skin Sens. 1 H317 Eye Irrit. 2 H319 Environment : Aquatic Chronic 3 - H410 |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS07 GHS09 GHS08
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Signal Word |
Danger |
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Contains |
Limonene. |
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Hazard Statements |
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H304May be fatal if swallowed and enters airways. H317May cause an allergic skin reaction. H319Causes serious eye irritation. H411Very toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P262 Do not get in eyes, on skin or on clothing P280 Wear protective gloves/protective clothing/eye protection/face protection P273 Avoid release to the environment P305/351/338 IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P301/310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. P331 Do NOT induce vomiting |
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Supplementary Precautionary Statements |
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P391 Collect spillage |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No. |
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Adverse physio-chemical properties |
Combustible but should not self-ignite. |
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Adverse effects on human health |
May cause sensitisation of skin & eyes. |
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3.1 |
Substances |
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15.0 – 32.0% CAMPHENE CAS: 79-92-5, EC: 201-234-8
Classification (EC 1272/2008) Eye Irrit. 2, H319, Aquatic Acute 1, H400, M Acute = 1, Aquatic Chronic 1, H410 M Chronic = 1
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4.0 – 8.0% Alpha-pinene CAS-No.: 80-56-8 EC No.: 201-291-9
Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317
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3.0 – 5.0% Beta-Pinene CAS: 127-91-3, EC: 204-872-5
Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317
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1.5 – 3.0% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304 Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410
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4.1 |
Description of first aid measures |
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Inhalation |
Remove immediately from source of exposure into fresh air. Get medical attention if any discomfort continues. |
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Ingestion |
DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Get medical attention. |
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Skin Contact |
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues. |
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Eye Contact |
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.
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4.2 |
Most important symptoms and effects, both acute and delayed |
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Observe risk of aspiration if vomiting occurs. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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Treat symptomatically. |
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5.1 |
Extinguishing Media |
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Extinguishing media: Carbon dioxide (CO2). Powder. Unsuitable extinguishing media: Full water jet. |
5.2 |
Special hazards arising from the product |
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B (Fires of liquids or liquid turning substances). In case of fire toxic fumes like carbon monoxide and carbon dioxide may be liberated. Burning produces heavy smoke. |
5.3 |
Advice for firefighters |
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Move undamaged containers from immediate hazard area if it can be done safely. Use suitable breathing apparatus. Wear suitable equipment for self protection. |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Wear protective clothing as described in Section 8 of this safety data sheet. Handle the product using protective gloves resistant to the chemicals exposed. Avoid contact with skin, eyes and clothing. Maintain adequate ventilation in the working area after spilling. |
6.2 |
Environmental Precautions |
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Do not discharge into drains, water courses or onto the ground. |
6.3 |
Methods and material for containment and cleaning up. |
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Cover with an inert, inorganic, non-combustible absorbent material (e.g dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or courses of ignition. Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
6.4 |
Reference to other sections |
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Wear protective clothing as described in Section 8 of this safety data sheet. |
7.1 |
Precautions for safe handling |
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Handle in accordance with good hygiene and safety practice. Provide earthing of containers, equipment, pumps and ventilation facilities. Take precautionary measures against static discharges. Keep away from food, drink and animal feed products. When using do not smoke, drink or eat. Wear suitable clothing to avoid contact with skin, eyes and clothing. Avoid inhalation of product vapours. Provide adequate ventilation of working area. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Keep product in its original container well sealed, in a dry, ventilated area, away from potential sources of ignition and protected from light. Stock according to local / national regulations and always follow the precautions indicated on labels. |
7.3 |
Specific end use(s) |
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No additional data available. |
8.1 |
Control parameters |
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No additional data available. |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Provide eyewash station. |
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Engineering Measures |
Provide adequate ventilation. |
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Respiratory Equipment |
For high concentrations use respiratory equipment. |
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Hand Protection |
Chemical resistant gloves (PVC). |
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Eye Protection |
Wear approved safety goggles. |
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Other Protection |
Wear appropriate clothing to prevent any possibility of skin contact. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. |
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Personal Protection |
Avoid contact with skin and eyes. Avoid inhalation of vapours. |
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Skin Protection |
Wear apron or protective clothing in case of splashes. |
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only eliminate by authorised companies. |
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Mobile Liquid |
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Colour |
Pale yellow to red/brown |
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Odour |
Characteristic – warm, woody with balsamic undertones. |
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Relative Density |
0.930 - 0.984 @ 20°C |
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Flash Point (°C) |
75 |
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Refractive Index |
1.445 - 1.500 @ 20°C |
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Melting Point (°C) |
-21.1 |
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Boiling Point (°C) |
270 @760mm Hg |
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Vapour Pressure |
1.13 x 10-11 mm Hg @ 25°C |
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Solubility in Water @20°C |
Insoluble in water. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10.1 |
Reactivity |
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Avoid contact with; strong oxidising agents, strong reducing agents, acids, bases, acid anhydride and alkali metals. |
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10.2 |
Chemical stability |
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Stable under the recommended handling and storage conditions.
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10.3 |
Possible hazardous reactions |
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No hazardous reactions at proper usage and handling. |
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10.4 |
Conditions to Avoid |
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Temperatures more than room temperature will benefit the transfer from liquid to vapour phase and formation of explosive atmospheres. Storing the product in open containers will benefit the formation of peroxides and derogate the quality. |
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10.5 |
Incompatible materials |
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No additional data available. |
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10.6 |
Hazardous Decomposition Products |
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No dangerous decomposition products known. |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
LD50 (oral) in mg/kg: 15000 LD50 (dermal) in mg/kg: > 5000 |
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Skin corrosion / irritation |
No additional data available. |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
No additional data available. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
No additional data available. |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12.1 |
Toxicity |
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No additional data available. |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available. |
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12.6 |
Other adverse effects |
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Do not allow product to enter streams, sewers or other waterways. Water Hazard Class; WGK-2. |
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13.1 |
Waste treatment methods |
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Collect and dispose of waste product in accordance with local authority guidelines using a hazardous chemical disposal company. Product remainders should not intrude soil or waters. |
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14.1 |
UN number |
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UN No. Road |
3082 |
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UN No. SEA |
3082 |
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UN No. AIR |
3082 |
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14.2 |
UN proper shipping name |
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ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class: 9 ADR/RID/ADN Class:9 - Miscellaneous dangerous substances and articles. IMDG Class:9 ICAO Class/Division:9
Transport Labels
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant
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14.6 |
Special precautions for user |
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See sections 6-8. |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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Packed and transferred according to transport regulations. |
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H304May be fatal if swallowed and enters airways. H317May cause an allergic skin reaction. H319Causes serious eye irritation. H411Very toxic to aquatic life with long lasting effects. |
Other Information |
None |
Revision Date |
04/03/2016 |
Reason for revision |
New format and updated SDS |
Rev No/Repl, SDS Generated |
02 |