MSDS - Neroli Light - Citrus aurantium/ Parfum - Essential Oil

1.1

Product Identifier 

Product Name 

Neroli Oil Light.  

Biological Definition

Obtained from the steam distillation of the flowers of the bitter orange tree, Citrus aurantium L. var. amara L., Rutaceae and then by formulated blending of the oil with other citrus oils, citrus oil derivatives and fractions and other aromatic ingredients such that the final profile replicates in a general way the profile and odour characteristics of true Neroli Oil (Natural).

INCI Name

Citrus Aurantium Amara Flower Oil, Parfum.

Synonyms & Trade Names

Neroli Phase Oil.

CAS-No

68916-04-1 / 72968-50-4 / -

EC No.

277-143-2 / -

EINECS No.

277-143-2 / -

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements  displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards : FL4 H227

Human health Asp. : Tox. 1 – AH1 H304, Skin Irrit 2 – SCI2 H315, Skin Sens 1 – SS1 H317

Environment : Aquatic Chronic 2 – EHC2 H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS08            GHS09         GHS07

Signal Word

Danger

Contains

Linalyl acetate, Linalool, Limonene, Geranyl acetate, Phenyl ethyl alcohol.

Hazard Statements

H304                May be fatal if swallowed and enters airways.

H315                Causes skin irritation.

H317                May cause an allergic skin reaction.

H411                Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210                 Keep away from heat/sparks/open flames/hot surfaces – no smoking.

P241                 Use explosion proof electrical/ventilating/lighting/equipment.

P262                 Do not get in eyes, on skin or on clothing.

P273                 Avoid release to the environment.

P280                 Wear protective gloves/eye protection/face protection.

P301/310        IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303/361/353 If on skin (or hair): remove/take of immediately all contaminated clothing. Rinse skin with water/shower.

P331                 Do NOT induce vomiting.

P405                 Store locked up.

P501                 Dispose of contents/container to …

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

20-30% Linalyl Acetate CAS-No.: 115-95-7 EC No.: 204-116-4

Classification (EC 1272/2008) FL4, SCI3, EHA2

11-21% Linalool CAS-No.: 78-70-6 EC No.: 201-134-4

Classification (EC 1272/2008) FL4, SCI2, AT05, EHA3

9-19% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) AH1, EHC1, FL3, SCI2, SS1

6-10% Geranyl Acetate CAS-No.: 105-87-3 EC No.: 203-341-5

Classification (EC 1272/2008) EHC2, SCI3, EHA2

2-7% Phenyl Ethyl Alcohol CAS-No.: 60-12-8 EC No.: 200-456-2

Classification (EC 1272/2008) ATO5, EDI2A

1.5 – 3.5% Citronellol CAS-No.: 106-22-9 EC No.: 203-375-0

Classification (EC 1272/2008) SCI2, SS1, ATD5, ATO5, EHA2

1-3% Geraniol CAS-No.: 106-24-1 EC No.: 203-377-1

Classification (EC 1272/2008) SCI2, SS1, ATO5, EDI1, EHA2

4.1

Description of first aid measures

Inhalation 

Remove to fresh air for at least 15 minutes, in case of complaints seek medical attention.

 Ingestion

DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Get medical attention immediately.

Skin Contact 

Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of pure water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

Inhalation : Can cause slight headache.

Skin contact : Can cause slight skin rash.

Eye contact : Can cause bloodshot eyes.

4.3

Indication of any immediate medical attention and special treatment needed

Immediate medical assistance : See point 4.1.

Immediate/ special treatment: See point 4.1.

First aid specific means : Eye wash fountain/safety shower should be available in the work area.

5.1 

Extinguishing Media

Extinguishing media: Small fire use : Carbon dioxide (CO2). Foam, dry Powder. Large fire : Use water spray or fog – cool containing vessels with water jet in order to prevent pressure build up, auto-ignition or explosion.

Unsuitable extinguishing media: Pressurised water jet.

5.2 

Special hazards arising from the product

Vapours may form explosive mixture with air – in case of fire, the following can be released: carbon monoxide (CO), carbon dioxide (CO2), smoke, soot.

5.3 

Advice for firefighters

Special Fire Fighting ProceduresAvoid inhalation of generated fumes or vapours. Use appropriate respiratory equipment. Do not allow spillage into drains or waterways.

Protective equipment for fire-fightersWear full protective clothing.

6.1 

Personal precautions, protective equipment and emergency procedures

For non emergency personnel: In an emergency (i.e. unintentional important release of the product in enclosed space) respiratory protection (Gas filter A, colour code brown: consider the maximum duration of wear) must be worn. Use insulating device for respiratory protection with an independent air supply in circumstances which are unclear – use adequate protection, solvent resistant: security shoes, bodysuit, gloves and protective goggles (see point 8).

For emergency responders: As per non emergency personnel.

Emergency procedures: Remove any ignition source and ensure adequate ventilation in working areas following accidental release.

6.2 

Environmental Precautions

Do not discharge into drains. Keep away from surface and ground water.

6.3 

Methods and material for containment and cleaning up.

Keep away from heat and use non-combustible absorbing sawdust (sand, specific binder). Refer to point 13 for the appropriate method of waste treatment.

6.4 

Reference to other sections

See point 4, 8 and 13.

7.1 

Precautions for safe handling

Safe handling: During handling keep original container closed. Avoid contact with skin and eyes. Wear adequate protective gloves and eye/face protection. Avoid any sources of ignition. Avoid exposing to high temperature during processing. Maintain adequate local and general ventilation where product is handled.

Hygiene at work: Do not ingest or apply to the skin as such. No smoking. Remove contaminated clothing. Good personal washing routines should be followed. If at risk of contamination, foods, beverages and other articles of consumption must not be stored or consumed at the work areas.

7.2 

Conditions for safe storage, including any incompatibilities

Container: To be stored in stainless steel drums, preferably under inert atmosphere (nitrogen) with minimum head space, protect from day light. Take note: The container used during transportation must be considered only as a temporary container and it must not be considered in any case adequate for medium or long term warehousing.

Conditions: Store in a dry. Aerated place, away from any heat source and ignition source.

Temperature: From 5°C to 20°C

7.3 

Specific end use(s) 

Use as odour agent – the information of this section is not related to the use of the product in combination with any other material or any other process altering its characteristic.

8.1 

Control parameters 

Occupational exposure limit : Not determined.  

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

No additional data available.

Engineering Measures

No additional data available.

Respiratory Equipment

Not necessary in adequate local with general ventilation – avoid breathing vapours.

Hand Protection

Suitable gloves tested to EN374 (should be checked regularly) – always use with clean, dry hands.

Eye Protection

Protective goggles with built in frame tested to EN166 (should be checked regularly).

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Protective work clothing solvent resistant (should be checked regularly).

Environmental Exposure Controls 

Avoid discharging into drainage water. Only remove via authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid.

Colour

Colourless to pale yellow.

Odour

Characteristic – strong neroli note.

Relative Density

0.914 - 0.924 @ 20°C

Flash Point (°C)

Approx. 71°C

Refractive Index

1.471 - 1.481 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

Product not reactive with water – product not reactive if used according to storage and handling conditions and identified uses (see subsection 1.2).

10.2 

Chemical stability

Product stable if used according to storage and handling conditions and identified uses (see subsection 1.2). Shelf Life: 365 days, as per recommended storage and handling conditions (see point 7).

10.3 

Possible hazardous reactions

None if used according to storage and handling conditions and identified uses (see subsection 1.2).

10.4 

Conditions to Avoid

Avoid exposure to heat.

10.5 

Incompatible materials

Highly oxidising agents.

10.6 

Hazardous Decomposition Products

Carbon monoxide, carbon dioxide and unidentified organic compounds may be formed during combustion.

11.1 

Information on toxicological effects 

Acute Toxicity

This preparation has not been subject to ecotoxicological testing as an entity but has been blended from materials with known ecotoxicological data and hazard classification (RIFM). In view of the difficulty of using current standard ecotoxicological evaluation techniques to predict potential hazards arising from unforeseen potentiation, this preparation should be considered and handled as if it displayed health hazards and treated in consequence with all possible precaution.

Skin corrosion / irritation

Hazard statement: H315 Causes skin irritation.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

Hazard statement: H317 May cause an allergic skin reaction.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

Hazard statement: H304 May be fatal if swallowed and enters airways.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

This preparation has not been subject to ecotoxicological testing as an entity but has been blended from materials with known ecotoxicological data and hazard classification (RIFM). In view of the difficulty of using current standard ecotoxicological evaluation techniques to predict the impact on vulnerable parts of the ecosystem, this preparation should be considered and handled as if it displayed potential environmental hazards and treated in consequence with all possible precaution.

Aquatic life: Hazard statement: H411 Toxic to aquatic life with long lasting effects.

12.2 

Persistence & degradability

Degradability: No data available.

12.3 

Bioaccumulation Potential

Hazard statement: H411 Toxic to aquatic life with long lasting effects

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

This product (or all its ingredients) not classified as PBT or vPvb / CMR.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

The containers used for this product must be completely empty before disposal. Dispose product and /or contaminated packaging in accordance with federal, state and local environmental control regulations – dispose through the waste water is illegal.

14.1 

UN number

UN No. Road

3082

UN No. SEA

3082

UN No. AIR

3082

14.2 

UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:9

ADR/RID/ADN Class:9 Miscellaneous dangerous substances and articles.

IMDG Class 9

ICAO Class/Division 9

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

This product contains constituents that are flammable and dangerous for the environment – in case of pouring out, make sure to label new packaging accordingly, reproducing original label with relevant symbols.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

Tariff Number 330290900

NCM (Mercosur) 33029019

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H304                May be fatal if swallowed and enters airways.

H315                Causes skin irritation

H317                May cause an allergic skin reaction.

H411                Toxic to aquatic life with long lasting effects.

P210                 Keep away from heat/sparks/open flames/hot surfaces – no smoking.

P241                 Use explosion proof electrical/ventilating/lighting/equipment.

P262                 Do not get in eyes, on skin or on clothing.

P273                 Avoid release to the environment.

P280                 Wear protective gloves/eye protection/face protection.

P301/310        IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303/361/353 If on skin (or hair): remove/take of immediately all contaminated clothing. Rinse skin with water/shower.

P331                 Do NOT induce vomiting.

P405                 Store locked up.

P501                 Dispose of contents/container in accordance with applicable regulations.

Other Information

None.

Revision Date

23/06/15

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01