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MSDS - Neroli - Citrus aurantium - Essential Oil

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NEROLI ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1	Product Identifier
Product Name			Neroli Oil
Biological Definition			A natural blend of the volatile oil obtained by steam distillation of the fragrant white blossoms of the bitter orange tree Citrus aurantium L. subsp. amara Engl.
INCI Name			Citrus aurantium amara Flower Oil
Synonyms & Trade Names			Bitter Orange Flower Oil, Neroli Oil True
CAS-No		68916-04-1 / 72968-50-4	EC No.		- / 277-143-2	EINECS No.	- / 277-143-2
1.2	Relative identified uses of the substance or mixture and uses advised against
	No additional data available.
1.3	Details of the supplier of the safety data sheet
	Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912
1.4	Emergency Tel. No.			+ 44 (0) 161 633 3952

02. HAZARDS IDENTIFICATION

2.1	Classification of the substance or mixture
	The Full Text for all Hazard Statements displayed in Section 16.
Classification (EC 1272/2008)
	Serious eye damage, Category 1 (Eye Dam. 1, H318). Skin sensitisation, Category 1 (Skin Sens. 1, H317). Hazardous to the aquatic environment - Chronic hazard, Category 2 (Aquatic Chronic 2, H411). This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.
2.2		Label Elements
Label in accordance with (EC) No 1272/2008
	GHS07 GHS09 GHS05
Signal Word			Danger.
Contains			601-029-00-7 (R)-P-MENTHA-1,8-DIENE EC 203-377-1 GERANIOL EC 204-872-5 B-PINENE EC 201-291-9 ALPHA-PINENE X EC 203-375-0 CITRONELLOL EC 225-004-1 FARNESOL.
Hazard Statements
	H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
	P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplementary Precautionary Statements
	P501 Dispose of contents/container to ...
2.3		Other Hazards
PBT or vPvB according to Annex XIII			Not applicable.
Adverse physio-chemical properties			No additional data available.
Adverse effects on human health			No additional data available.

03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2	Mixtures
	< 39.6% Linalool CAS-No.: 78-70-6 EC No.: 201-134-4 Classification (EC 1272/2008) Acute Tox. 5 - H303, Skin Irrit. 2 - H315, Aquatic Acute 3 - H402
	10.0 – 25.0% Linalyl Acetate CAS: 115-95-7, EC: 204-116-4 Classification (EC 1272/2008) Skin Irrit. 2, H315; Eye Irrit. 2, H319
	< 13.9% (R)-P-MENTHA-1,8-DIENE CAS: 5989-27-5, EC: 227-813-5 Classification (EC 1272/2008) Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317, Aquatic Acute 1, H400 M Acute = 1, Aquatic Chronic 1, H410 M Chronic = 1
	2.5 - 10.0% Nerol CAS: 106-25-2, EC: 203-378-7 Classification (EC 1272/2008) Eye Irrit. 2, H319, Skin Irrit. 2, H315
	< 6.3% Geraniol CAS: 106-24-1, EINECS: 203-377-1 Classification (EC 1272/2008) Eye Dam. 1, H318; Skin Irrit. 2, H315; Skin Sens. 1, H317
	2.5 - 10.0% B-Pinene CAS: 127-91-3, EC: 204-872-5 Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317
	2.5 – 10.0% Terpinyl Acetate CAS: 80-26-2, EC: 201-265-7 Classification (EC 1272/2008) Aquatic Chronic 2, H411
	2.5 – 10.0% Alpha-Pinene X CAS: 80-56-8, EC: 201-291-9 Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317
	< 2.0% Citronellol CAS-No.: 106-22-9EC No.: 203-375-0 Classification (EC 1272/2008) Eye Irrit. 2, H319, Skin Irrit. 2, H315, Skin Sens. 1, H317
	2.5 – 10.0% Nerolidol (Isomer Unspecified) CAS: 7212-44-4, EINECS: 230-597-5 Classification (EC 1272/2008) Eye Irrit. 2, H319, Aquatic Acute 1, H400 M Acute = 1, Aquatic Chronic 1, H410 M Chronic = 1
	2.5 – 10.0% Geranyl Acetate CAS-No.: 105-87-3 EC No.: 203-341-5 Classification (EC 1272/2008) Skin Irrit. 2, H315; Skin Sens. 1B, H317; Aquatic Chronic 3, H412
	< 3.5% Farnesol CAS: 4602-84-0, EINECS: 225-004-1 Classification (EC 1272/2008) Eye Irrit. 2, H319, Skin Irrit. 2, H315, Skin Sens. 1, H317
	2.5 – 10.0% Terpineol CAS: 8000-41-7, EINECS: 232-268-1 Classification (EC 1272/2008) Eye Irrit. 2, H319, Skin Irrit. 2, H315

04. FIRST AID MEASURES

4.1	Description of first aid measures
Inhalation		Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. Supply fresh air.
Ingestion		Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor. Seek medical attention immediately, showing the label.
Skin Contact		Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. Watch out for any remaining product between skin and clothing, watches, shoes, etc. In the event of an allergic reaction, seek medical attention. If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.
Eye Contact		Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open. Regardless of the initial state, refer the patient to an ophthalmologist and show him the label.
4.2	Most important symptoms and effects, both acute and delayed
	No additional data available.
4.3	Indication of any immediate medical attention and special treatment needed
	No additional data available.

05. FIRE-FIGHTING MEASURES

5.1	Extinguishing Media
	Non-flammable.
5.2	Special hazards arising from the product
	A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not breathe in smoke. In the event of a fire, the following may be formed : - carbon monoxide (CO) - carbon dioxide (CO2)
5.3	Advice for firefighters
	No data available.

06. ACCIDENTAL RELEASE MEASURES

6.1	Personal precautions, protective equipment and emergency procedures
	Consult the safety measures listed under headings 7 and 8. For non first aid worker Avoid any contact with the skin and eyes. For first aid worker First aid workers will be equipped with suitable personal protective equipment (See section 8).
6.2	Environmental Precautions
	Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal. Prevent any material from entering drains or waterways.
6.3	Methods and material for containment and cleaning up.
	Clean preferably with a detergent, do not use solvents.
6.4	Reference to other sections
	No additional data available.

07. HANDLING AND STORAGE

7.1	Precautions for safe handling
	Requirements relating to storage premises apply to all facilities where the mixture is handled. Individuals with a history of skin sensitisation should not, under any circumstance, handle this mixture. Always wash hands after handling. Remove and wash contaminated clothing before re-using. Emergency showers and eye wash stations will be required in facilities where the mixture is handled constantly. Fire prevention : Prevent access by unauthorised personnel. Recommended equipment and procedures : For personal protection, see section 8. Observe precautions stated on label and also industrial safety regulations. Avoid eye contact with this mixture at all times. Prohibited equipment and procedures : No smoking, eating or drinking in areas where the mixture is used.
7.2	Conditions for safe storage, including any incompatibilities
	Packaging Always keep in packaging made of an identical material to the original.
7.3	Specific end use(s)
	No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1	Control parameters
		Occupational exposure limits : -ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) : CAS TWA : STEL : Ceiling : Definition : Criteria : 127-91-3 20 ppm - - - - 80-56-8 20 ppm - - - -
8.2	Exposure controls
Protective Equipment

Process Conditions			Provide eyewash station. Wash hands before breaks and at the end of work.
Engineering Measures			Provide adequate ventilation.
Respiratory Equipment			Not required.
Hand Protection			Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must be selected according to the application and duration of use at the workstation. Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required. Recommended properties : - Impervious gloves in accordance with standard EN374
Eye Protection			Avoid contact with eyes. Use eye protectors designed to protect against liquid splashes Before handling, wear safety goggles with protective sides in accordance with standard EN166. In the event of high danger, protect the face with a face shield. Prescription glasses are not considered as protection. Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours. Provide eyewash stations in facilities where the product is handled constantly.
Other Protection			Wear appropriate clothing to prevent any possibility of skin contact. Immediately remove all soiled and contaminated clothing.
Hygiene Measures			Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.
Personal Protection			Use personal protection according to Directive 89/686/EEC.
Skin Protection			Avoid skin contact. Wear suitable protective clothing. Suitable type of protective clothing : In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact. In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact. Work clothing worn by personnel shall be laundered regularly. After contact with the product, all parts of the body that have been soiled must be washed.
Environmental Exposure Controls			Avoid discharging into drainage water. Only eliminate by authorised companies.

09. PHYSICAL AND CHEMICAL PROPERTIES

9.1	Information on basic physical and chemical properties
Appearance		Mobile viscous liquid.
Colour		Light to pale yellow.
Odour		Characteristic, fresh, floral.
Relative Density		0.866 to 0.880 @ 20°C
Flash Point (°C)		61°C
Refractive Index		1.468 to 1.474 @ 20°C
Melting Point (°C)		No additional data available.
Boiling Point (°C)		No additional data available.
Vapour Pressure		No additional data available.
Solubility in Water @20°C		Insoluble in water.
Auto-ignition temperature (°C)		No additional data available.
9.2	Other information
	No additional data available.

10. STABILITY AND REACTIVITY

10.1		Reactivity
	No additional data available.
10.2		Chemical stability
	This mixture is stable under the recommended handling and storage conditions in section 7.
10.3		Possible hazardous reactions
	No additional data available.
10.4		Conditions to Avoid
	No additional data available.
10.5		Incompatible materials
	No additional data available.
10.6		Hazardous Decomposition Products
	The thermal decomposition may release/form : - carbon monoxide (CO) - carbon dioxide (CO2)

11. TOXOLOGICAL INFORMATION

11.1		Information on toxicological effects
	Acute Toxicity		Acute toxicity : TERPINEOL (CAS: 8000-41-7) Oral route : LD50 = 4300 mg/kg CITRONELLOL (CAS: 106-22-9) Oral route : LD50 = 2650 mg/kg Dermal route : LD50 = 2650 mg/kg ALPHA-PINENE X (CAS: 80-56-8) Oral route : LD50 = 3700 mg/kg GERANIOL (CAS: 106-24-1) Oral route : LD50 = 4200 mg/kg NEROL (CAS: 106-25-2) Oral route : LD50 = 4500 mg/kg LINALOOL (CAS: 78-70-6) Oral route : LD50 = 3000 mg/kg.
	Skin corrosion / irritation		May cause an allergic reaction by skin contact. Corrosivity : No observed effect.
	Serious eye damage / irritation		May have irreversible effects on the eyes, such as tissue damage in the eye, or serious physical decay of sight, which is not fully reversible by the end of observation at 21 days. Serious eye damage is typified by the destruction of cornea, persistent corneal opacity and iritis.
	Respiratory or skin sensitisation		May cause an allergic skin reaction.
	Germ Cell Mutagenicity		No additional data available.
	Carcinogenicity		CAS 5989-27-5 : IARC Group 3 : The agent is not classifiable as to its carcinogenicity to humans.
	Reproductive toxicity		No additional data available.
	STOT-single exposure		No additional data available.
	STOT-repeated exposure		No additional data available.
	Aspiration hazard		No additional data available.
	Photo-toxicity		No additional data available.
	Other Information		None.

12. ECOLOGICAL INFORMATION

12.1		Toxicity
	Toxic to aquatic life with long lasting effects. The product must not be allowed to run into drains or waterways.
12.2		Persistence & degradability
	CITRONELLOL (CAS: 106-22-9). Biodegradability : no degradability data is available, the substance is considered as not degrading quickly.
12.3		Bioaccumulation Potential
	CITRONELLOL (CAS: 106-22-9) Octanol/water partition coefficient : 3 <= log Koe < 4.
12.4		Mobility in soil
	No additional data available.
12.5		Results of PBT and vPvB Assessment
	No additional data available.
12.6		Other adverse effects
	No additional data available.

13. DISPOSAL CONSIDERATIONS

13.1

Waste treatment methods

Do not pour into drains or waterways.

Waste :

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.

Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.

Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging :

Empty container completely. Keep label(s) on container.

Give to a certified disposal contractor.

14. TRANSPORT INFORMATION

14.1		UN number
		UN No. Road	3082
		UN No. SEA	3082
		UN No. AIR	3082
14.2		UN proper shipping name
	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((r)-p-mentha-1,8-diene).
14.3		Transport hazard class(es)
	ADR/RID/ADN Class; 9 ADR/RID/ADN Class: 9 IMDG Class: 9 ICAO Class/Division: 9 Transport Labels
14.4		Packing group
	ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III
14.5		Environmental hazards
	Environmentally Hazardous Material
14.6		Special precautions for user
	ADR/RID Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel 9 M6 III 9 90 5 L 274 335 375 601 E1 3 E IMDG Class 2°Label Pack gr. LQ EMS Provis. EQ 9 - III 5 L F-A,S-F 274 335 969 E1 IATA Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ 9 - III 964 450 L 964 450 L A97 E1 A158 A197 9 - III Y964 30 kg G - - A97 E1 A158 A197 Not subject to this regulation if Q <= 5 l / 5 kg (IATA 4.4.4 - DS A197) For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG. For excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG.
14.7		Transport in bulk according to Annex II of MARPOL73/78 and the IBC code
	No additional data available.

15. REGULATORY INFORMATION

15.1		Safety, health and environmental regulations/legislation specific for the substance or mixture
	Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2		Chemical safety assessment
	No additional information available.

16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full	H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects
Other Information	None
Revision Date	24/11/15
Reason for revision	Updated SDS and new format.
Rev No/Repl, SDS Generated	02

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Neroli, Citrus aurantium

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A natural blend of the volatile oil obtained by steam distillation of the fragrant white blossoms of the bitter orange tree Citrus aurantium L. subsp. amara Engl.

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A natural blend of the volatile oil obtained by steam distillation of the fragrant white blossoms of the bitter orange tree Citrus aurantium L. subsp. amara Engl.