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ESTABLISHED 1993

MSDS - Marigold - Calendula Officinalis - Absolute


MARIGOLD ABSOLUTE
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Marigold (Calendula) Absolute

Biological Definition

Calendula Officinalis Flower Extract is an extract obtained from the flowers of the Calendula, Calendula officinalis L., Compositae

INCI Name

Calendula Officinalis Flower Extract

Synonyms & Trade Names

-

CAS-No

84776-23-8

EC No.

283-949-5

EINECS No.

283-949-5

1.2

Relative identified uses of the substance or mixture and uses advised against

 

No additional data available.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements are Displayed in Section 16.

 

Physical and Chemical Hazards Not classified.

Human health Skin Sens. 1 - H317

Environment Aquatic Chronic 2 - H411

Classification (EC 1272/2008)

 

H317 May cause an allergic skin reaction

H411 Toxic to aquatic life with long lasting effects.

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

   GHS09            GHS07

 

 

Signal Word

Warning

Contains

d-Limonene.

Hazard Statements

 

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

 

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

Supplementary Precautionary Statements

 

P261 Avoid breathing vapour/spray.

P321 Specific treatment (see medical advice on this label).

P391 Collect spillage.

P501 Dispose of contents/container to …

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available

Adverse physio-chemical properties

No additional data available

Adverse effects on human health

No additional data available

03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2

Mixtures

 

<1.0% Citronellal CAS-No.: 106-23-0 EC No.: 203-376-6

 

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Aquatic Chronic 2 - H411

 

 

<1.0% Citronellol CAS-No.: 106-22-9, EC No.: 203-375-0

 

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Skin Sens. 1 - H317

 

 

 

<1.0% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

 

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

 

 

<1.0% Geraniol CAS-No.: 106-24-1 EC No.: 203-377-1

 

Classification (EC 1272/2008) Skin Irrit. 2 – H315, Eye Dam. 1 – H318, Skin Sens. 1 –H317

 

 

<1.0% Phenyl Ethyl Alcohol CAS-No.: 60-12-8 EC No.: 200-456-2

 

Classification (EC 1272/2008)  Eye Irrit. 2 - H319

 

 

<1.0% Phytol CAS-No.: 150-86-7 EC No.: 205-776-6

 

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Remove victim immediately from source of exposure. Get medical attention if any discomfort continues.

 Ingestion

Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions.

Skin Contact 

Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

 

Ingestion

May cause discomfort if swallowed.

Skin contact

May cause skin dryness and cracking.

4.3

Indication of any immediate medical attention and special treatment needed

 

No additional data available

05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Extinguishing media

Use as appropriate: CO2, powder or waterspray. Large fires to be extinguished with alcohol resistant foam.

Unsuitable extinguishing media

Do not use a direct stream of water.

5.2 

Special hazards arising from the product

 

Hazardous combustion products

Not known.

Unusual Fire & Explosion Hazards

Toxic vapours may be released during fire, respiratory protection should be provided.

5.3 

Advice for firefighters

 

Special Fire Fighting Procedures

Avoid inhalation of generated fumes or vapours. Use appropriate respiratory equipment.

Protective equipment for fire-fighters

Wear full protective clothing.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2 

Environmental Precautions

 

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

 

Absorb with liquid binding material i.e., sand, acid binders, universal binders, sawdust.

6.4 

Reference to other sections

 

Wear protective clothing as described in Section 8 of this safety data sheet.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Close packaging after use. Reproduce labelling if transferring into another container.

7.2 

Conditions for safe storage, including any incompatibilities

 

Keep in original containers. Keep away from food, drink and animal feeding stuffs. Keep away from heat sources and protected from light.

7.3 

Specific end use(s) 

 

No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

No additional data available.  

8.2 

Exposure controls 

Protective Equipment

 

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Process Conditions 

Safety shower and eye bath.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

For high concentrations use respiratory equipment.

Hand Protection

Chemical resistant gloves (PVC)

Eye Protection

Wear approved safety goggles.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Viscous liquid

Colour

Dark brown to orange

Odour

Characteristic

Relative Density

0.955 - 0.980 @ 20⁰C

Flash Point (°C)

>100⁰C

Refractive Index

1.480 - 1.505 @ 20⁰C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.

10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

No dangerous reactions known.

10.2 

Chemical stability

 

Stable under normal temperature conditions.

10.3 

Possible hazardous reactions

 

No dangerous reactions known.

10.4 

Conditions to Avoid

 

Avoid exposure to high temperatures or direct sunlight.

10.5 

Incompatible materials

 

Materials To Avoid

Strong oxidising substances.

10.6 

Hazardous Decomposition Products

 

No additional data available

11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

Toxicological information

We have no data available on this product. It must be considered, handled and should be dealt with the highest possible caution.

 

Skin corrosion / irritation

No additional data available.

 

Serious eye damage / irritation

No additional data available.

 

Respiratory or skin sensitisation

No additional data available.

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

No additional data available.

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available.

 

STOT-repeated exposure

No additional data available

 

Aspiration hazard

No additional data available.

 

Photo-toxicity

No additional data available.

 

Other Information

No additional data available.

12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

No additional data available.

12.2 

Persistence & degradability

 

No additional data available.

12.3 

Bioaccumulation Potential

 

No additional data available.

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

No additional data available

12.6 

Other adverse effects

 

No additional data available.

13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

General information

Do not re-use empty containers. Empty residue into a suitable disposal site.

 

Dispose of in compliance with all local and national regulations.

14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

3082

 

UN No. SEA

3082

 

UN No. AIR

3082

14.2 

UN proper shipping name

 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S (d-Limonene)

14.3 

Transport hazard class(es)

 

ADR/RID/ADN - Class 9: Miscellaneous dangerous substances and articles.

ADR/RID/ADN - 9

IMDG - 9

ICAO - 9

 

Transport Labels

 

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14.4 

Packing group

 

ADR/RID/ADN Packing group – III

IMDG Packing group – III

ICAO Packing group – III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant

 

 

 

14.6 

Special precautions for user

 

EMS F-A-S-F

Hazard No. (ADR) 3YE

Hazard No. (ADR) 90 Environmentally hazardous substance; miscellaneous dangerous substances.

Tunnel Restriction Code (E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

Tariff Number 33012941

15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

 

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

 

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.

16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None

Revision Date

19/08/15

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Absolute, MSDS, Aromatherapy, Marigold, Calendula Officinalis