Essential Oils Direct Logo
UK AROMATHERAPY SUPPLIES
Essential Oils, Carrier Oils, Base Products, Bottles & Jars and much more.
ESTABLISHED 1993

MSDS - Clove Leaf - Eugenia caryophyllus - Essential Oil


CLOVE LEAF ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Clove Leaf Oil.

Biological Definition

Eugenia Caroyphyllus Leaf Oil is an essential oil steam-distilled from the leaves of the Clove, Eugenia caryophyllus, Myrtaceae. 

INCI Name

Eugenia Caroyphyllus Leaf Oil.

Synonyms & Trade Names

-

CAS-No

8015-97-2 / 8000-34-8 / 84961-50-2

EC No.

- / - /

284-638-7

EINECS No.

- / - /

284-638-7

1.2

Relative identified uses of the substance or mixture and uses advised against

 

Industry Use.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952









02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

 

Physical and Chemical:Hazards Not classified.

Human health: Skin Sensitisation cat. 1 - H317, Aspiration Toxicity cat 1 - H304,
Serious eye damage/ eye irritation cat 2 – H319

Environment:Toxic to aquatic life.

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

      GHS07          GHS08

    C:\SharedDrive\Callum\Images & Logo\download.png

 

Signal Word

Danger.

Contains

CARYOPHYLLENE, EUGENOL

Hazard Statements

 

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

Precautionary Statements

 

P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331 - Do NOT induce vomiting.

Supplementary Precautionary Statements

 

No additional data available.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

May be harmful if swallowed.





03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2

Mixtures

 

84.0 – 88.0% EUGENOL CAS-No: 97-53-0 EC No: 202-589-1

 

Classification (EC 1272/2008) Aquatic Acute 2 (H401) Skin Sens. 1 (H317) Eye Irrit. 1 (H319), Skin Irrit. 3 (H316) Acute Tox. 5 (H303), Aquatic Acute 2 (H401) (EFFA), Skin Sens. 1 (H317) (EFFA) Eye Irrit. 1 (H319) (EFFA) Skin Irrit. 3 (316) (EFFA), Acute Tox. 5 (H303)(EFFA)

 

 

9.0 – 12.0% CARYOPHYLLENE CAS: 87-44-5 EC No: 201-746-1

 

Classification (EC 1272/2008) Skin Irrit. 3 (H316), Skin Irrit. 3 (316) (EFFA) Asp. Tox. 1 (H304) (EFFA)

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.

Ingestion

Rinse mouth with water. DO NOT induce vomiting. Get medical attention.

Skin Contact 

Remove contaminated clothing. Wash skin with soap and plenty of water. Get medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if irritation continues.

4.2

Most important symptoms and effects, both acute and delayed

 

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

 

Treat symptomatically.




05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

EXTINGUISHING MEDIA

Use as appropriate: CO2, Foam, dry chemical powder.

 

5.2 

Special hazards arising from the product

 

Thermal decomposition can lead to release of irritating and toxic gases and vapours.
Hazardous combustion products: Irritating or toxic substances may be emitted upon burning, combustion, or decomposition.

 

5.3 

Advice for firefighters

 

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Ensure adequate ventilation, especially in confined areas. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2 

Environmental Precautions

 

Do not discharge into drains, water courses or onto the ground. Collect spillage.

6.3 

Methods and material for containment and cleaning up.

 

Absorb with inert, non-combustible, inorganic absorbent material (e.g. sand, earth, diatomaceous earth, vermiculite). Sweep up and remove to an approved disposal container.

6.4 

Reference to other sections

 

See section 12.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Ensure adequate ventilation, especially in confined areas. Handle in accordance with good industrial hygiene and safety practice.

7.2 

Conditions for safe storage, including any incompatibilities

 

Store in tightly closed original container in a dry, cool and well-ventilated place.

7.3 

Specific end use(s) 

 

No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

No additional data available.  

8.2 

Exposure controls 

Protective Equipment

 

 

Process Conditions 

Provide eyewash station.

Engineering Measures

Ensure adequate ventilation, especially in confined areas.

Respiratory Equipment

Respiratory protection may be required, if ventilation is poor.

Hand Protection

Chemical resistant gloves (PVC)

Eye Protection

Avoid contact with the eyes. Wear approved safety goggles.

Other Protection

No additional data available.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.





09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

Clear pale yellow to dark yellow liquid.  

Colour

Pale yellow to dark yellow.

Odour

Characteristic.

Relative Density

1.033  -  1.054 @ 20°C

Flash Point (°C)

100

Refractive Index

1.528  -  1.538  @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

0.002

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.




10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

Stable under normal temperature conditions and recommended use.

10.2 

Chemical stability

 

Stable under normal temperature conditions and recommended use.

10.3 

Possible hazardous reactions

 

None under normal use and conditions.

10.4 

Conditions to Avoid

 

Avoid extremes of temperature and direct sunlight.

10.5 

Incompatible materials

 

No additional data available.

10.6 

Hazardous Decomposition Products

 

None under normal use conditions.




11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

Product does not present an acute toxicity hazard based on known or supplied information.

The following values are calculated based on chapter 3.1 of the GHS document: ATEmix (oral)2,809.00

 

Oral LD50Dermal LD50

EUGENOL1930mg/kg (Rat)

 

 

Skin corrosion / irritation

No additional data available.

 

Serious eye damage / irritation

No additional data available.

 

Respiratory or skin sensitisation

No additional data available.

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

No additional data available.

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available.

 

STOT-repeated exposure

No additional data available.

 

Aspiration hazard

No additional data available.

 

Photo-toxicity

No additional data available.

 

Other Information

No additional data available.





12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

14 % of the mixture consists of components(s) of unknown hazards to the aquatic environment.

12.2 

Persistence & degradability

 

No additional data available.

12.3 

Bioaccumulation Potential

 

No additional data available.

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

Not applicable.

12.6 

Other adverse effects

 

No additional data available.




13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Disposal should be in accordance with applicable regional, national and local laws and regulations. Improper disposal or reuse of the container may be dangerous and illegal.   




14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

Not regulated.

 

UN No. SEA

Not regulated.

 

UN No. AIR

Not regulated.

14.2 

UN proper shipping name

 

None.

14.3 

Transport hazard class(es)

 

Not regulated.

14.4 

Packing group

 

Not required.

14.5 

Environmental hazards

 

None.

14.6 

Special precautions for user

 

None.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

No additional data available.





15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.




16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H302 - Harmful if swallowed.

H316 - Causes mild skin irritation.

H401 - Toxic to aquatic life.

H317 - May cause an allergic skin reaction.

H319 - Causes serious eye irritation.

H303 - May be harmful if swallowed.

Other Information

None

Revision Date

05/05/2016

Reason for revision

Update to new format

Rev No/Repl, SDS Generated

02

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

Keywords: Essential Oil, MSDS, Aromatherapy, Clove Leaf, Eugenia caryophyllus