1.1 |
Product Identifier |
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Product Name |
Bergamot FCF Oil. |
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Biological Definition |
Citrus Aurantium Bergamia Peel Oil is the volatile oil obtained from the peel of Citrus aurantium bergamia, Rutaceae. |
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INCI Name |
Citrus Aurantium Bergamia Peel Oil. |
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Synonyms & Trade Names |
- |
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CAS-No |
89957-91-5 |
EC No. |
289-612-9 |
EINECS No. |
289-612-9 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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Flavours, Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements displayed in Section 16. |
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Classification (EC 1272/2008) |
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Flammable Liquid, Hazard Category 3. Skin Corrosion / Irritation Category 2. Eye Damage / Irritation Category 2. Sensitization - Skin Category 1. Aspiration Hazard Category 1. Hazardous to the Aquatic Environment - Acute Hazard Category 1. Hazardous to the Aquatic Environment - Long-term Hazard Category 1. H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS02GHS07 GHS08 GHS09
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Signal Word |
Danger. |
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Contains |
- |
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Hazard Statements |
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H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. |
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Supplementary Precautionary Statements |
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None. |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available. |
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Adverse physio-chemical properties |
No additional data available. |
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Adverse effects on human health |
No additional data available. |
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3.2 |
Mixtures |
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38.39% Linalyl Acetate CAS-No: 115-95-7; EC No.: 204-116-4
Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319
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≤ 45.0% Limonene CAS-No: 5989-27-5; EC No.: 227-813-5
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304, Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410
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≤ 15.0% Linalool CAS No: 78-70-6 ; EC No: 201-134-4
Classification (EC 1272/2008) : Acute Tox. 5 - H303, Skin Irrit. 2 - H315, Aquatic Acute 3 - H402
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7.58% β-Pinene CAS No: 127-91-3 ; EC No: 20-872-5
Classification (EC 1272/2008) : Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Skin Irrit. 2 - H315, Skin Sens. 1 - H317
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7.56% γ-Terpinene (p-mentha-1,4-diene) CAS No99-85-4 ; EC No: 202-794-6
Classification (EC 1272/2008) Flam. Liq. 3 – H226, Asp Tox. 1 –H304;
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1.89% α-Pinene CAS No: 80-56-8 ; EC No: 201-291-9
Classification (EC 1272/2008) : Flam. Liq. 3, H226; Asp. Tox. 1, H304; Skin Sens.1, H317; Aquatic Acute 1, Aquatic Chronic 1, H410
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1.14% Myrcene CAS No: 123-35-3 ; EC No: 204-622-5
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Aquatic Chronic 3 - H412
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1.5% Citral CAS No: 5392-40-5 ; EC No: 226-394-6
Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Skin Sens. 1 - H317
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0.56% Geranyl Acetate CAS-No.: 105-87-3 EC No.: 203-341-5
Classification (EC 1272/2008) Aquatic Chronic 2 - H411
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0.41% Beta Caryophyllene CAS-No.: 87-44-5 EC No.: 201-746-1
Classification (EC 1272/2008) : Asp. Tox. 1 - H304
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0.22% P-Mentha-1,3-Diene CAS: 99-86-5, EC: 202-795-1
Classification (EC 1272/2008) Asp. Tox. 1, H304, Acute Tox. 4, H302, Aquatic Chronic 2, H411, Flam. Liq. 3, H226
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0.22% p-Cymene CAS-No.: 99-87-6; EC No.: 202-796-7
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Acute Tox. 5 - H303, Aquatic Chronic 2, H411, Skin Irrit. 3 ‐H316
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0.17% d,l-Limonene (isomer unspecified) CAS-No.: 7705-14-8; EC No.: 231-732-0
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Aquatic Chronic 1, H410
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4.1 |
Description of first aid measures |
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Inhalation |
Remove from exposure area to fresh air. Obtain medical advice immediately. |
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Ingestion |
Immediately call a POISON CENTER or doctor/physician. |
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Skin Contact |
Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. |
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Eye Contact |
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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None expected, see Section 4.1 for further information. |
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5.1 |
Extinguishing Media |
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Suitable extinguishing media:CO2, Dry powder, Foam. Spray to base of flames. |
5.2 |
Special hazards arising from the product |
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In case of fire, Carbon monoxide, Unidentified organic compounds may be liberated. |
5.3 |
Advice for firefighters |
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In case of insufficient ventilation, wear suitable respiratory equipment. |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. |
6.2 |
Environmental Precautions |
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Keep away from drains, surface and ground water, and soil. |
6.3 |
Methods and material for containment and cleaning up. |
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Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. |
6.4 |
Reference to other sections |
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See sections 8 and 13. |
7.1 |
Precautions for safe handling |
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Keep away from heat, sparks, open flames and hot surfaces. - No smoking. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. |
7.3 |
Specific end use(s) |
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Flavours, Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. |
8.1 |
Control parameters |
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No additional data available.
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Provide eyewash station. |
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Engineering Measures |
Provide adequate ventilation Avoid static discharges in working area. |
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Respiratory Equipment |
Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. |
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Hand Protection |
Avoid all skin contact. Wear chemical resistant gloves (PVC). |
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Eye Protection |
Avoid contact with eyes. Wear approved safety goggles. |
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Other Protection |
No additional data available. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed. |
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Personal Protection |
Avoid inhalation and contact with skin and eyes. |
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Skin Protection |
Wear apron or protective clothing in case of splashes. |
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only eliminate by authorised companies. |
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Liquid, pale yellow to yellow. |
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Colour |
Pale yellow to yellow. |
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Odour |
Characteristic citrus bergamot. |
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Relative Density |
0.870 – 0.888 @ 20°C |
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Flash Point (°C) |
54 |
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Refractive Index |
1.460 to 1.470 @ 20°C |
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Melting Point (°C) |
No additional data available. |
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Boiling Point (°C) |
No additional data available. |
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Vapour Pressure |
No additional data available. |
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Solubility in Water @20°C |
Insoluble in water. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available.
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10.1 |
Reactivity |
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Presents no significant reactivity hazards, by itself or in contact with water. |
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10.2 |
Chemical stability |
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Good stability under normal storage conditions. |
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10.3 |
Possible hazardous reactions |
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Not expected under normal temperature conditions and recommended use. |
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10.4 |
Conditions to Avoid |
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Avoid extreme heat. |
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10.5 |
Incompatible materials |
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Avoid contact with strong acids, alkalis and oxidising agents. |
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10.6 |
Hazardous Decomposition Products |
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Not expected under normal temperature conditions and recommended use. |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: 13396.24 Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: 207373.27 Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: n/a Inhalation Route: n/a |
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Skin corrosion / irritation |
Causes skin irritation (H315). |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
May cause an allergic skin reaction (H317). |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
May be fatal if swallowed and enters airways (H304). |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12.1 |
Toxicity |
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Very toxic to aquatic life with long lasting effects. |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. |
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12.6 |
Other adverse effects |
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No additional data available.
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13.1 |
Waste treatment methods |
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Do not release into the environment. Collect waste into suitable containers and contact hazardous chemical disposal company. |
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14.1 |
UN number |
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UN No. Road |
UN 1169 |
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UN No. SEA |
UN 1169 |
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UN No. AIR |
UN 1169 |
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14.2 |
UN proper shipping name |
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Extracts, Aromatic, Liquid. |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class:3 Flammable Liquid. IMDG Class:3 Flammable Liquid. ICAO Class/Division:3 Flammable Liquid.
Transport Labels |
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant.
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14.6 |
Special precautions for user |
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No additional data available.
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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No additional data available.
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.. |
Other Information |
Complies with REACH guidance for SDS as circulated by ECHA 2011. |
Revision Date |
27/05/2016 |
Reason for revision |
New SDS. |
Rev No/Repl, SDS Generated |
01 |