MSDS - Anise Star - Illicium verum - Essential Oil

1.1

Product Identifier 

Product Name 

Anise Oil China Star.

Biological Definition

Illicium Verum Fruit Oil is an essential oil distilled from the fruits of the Star Anise, Illicium verum, Illiciaceae.

INCI Name

Illicium Verum Fruit Oil.

Synonyms & Trade Names

Star Anise Oil, Aniseed Oil.

CAS-No

84650-59-9

EC No.

283-518-1

EINECS No.

283-518-1

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements is displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards: Not classified.

Human health: Acute Tox. 5 - H303;Skin Irrit. 3 - H316;Skin Sens. 1 - H317;Muta. 2 - H341;Carc. 2 - H351

Environment: Aquatic Acute 3 - H402;Aquatic Chronic 3 - H412

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS08            GHS07         

Signal Word

Warning.

Contains

Anethol, Estragole, Limonene.

Hazard Statements

H303 May be harmful if swallowed.

H316 Causes mild skin irritation.

H317 May cause an allergic skin reaction.

H341 Suspected of causing genetic defects.

H351 Suspected of causing cancer.

H402 Harmful to aquatic life.

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P262 Do not get in eyes, on skin, or on clothing.

P363 Wash contaminated clothing before reuse.

Supplementary Precautionary Statements

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P261 Avoid breathing vapour/spray.

P321 Specific treatment (see medical advice on this label).

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P308+313 IF exposed or concerned: Get medical advice/attention.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P405 Store locked up.

P501 Dispose of contents/container to …

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

87.0 -100.0% Anethol CAS-No.: 104-46-1 EC No.: 203-205-5

Classification (EC 1272/2008) Skin Sens. 1 - H317, Aquatic Chronic 2 - H411

1.0- 5.0% Estragol CAS-No.: 140-67-0 EC No.: 205-427-8

Classification (EC 1272/2008) Acute Tox. 4 - H302, Skin Sens. 1 - H317, Muta. 2 - H341,  Carc. 2 - H351

1.0 -5.0% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410

1.0 – 5.0% Linalool CAS-No.: 78-70-6 EC No.: 201-134-4

Classification (EC 1272/2008) Acute Tox. 5 - H303, Skin Irrit. 2 - H315, Aquatic Acute 3 - H402

4.1

Description of first aid measures

Inhalation 

Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues.

 Ingestion

Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. Do not induce vomiting.

Skin Contact 

Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues.

Eye Contact   

Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Do not use a direct stream of water to extinguish.  Use: Powder. Carbon dioxide (CO2).

5.2 

Special hazards arising from the product

Specific hazards:

When heated and in case of fire, toxic vapours/gases may be formed.

5.3 

Advice for firefighters

Protective equipment for fire-fighters:

Wear Self-contained breathing apparatus. Wear chemical protective clothing.

6.1 

Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Absorb with inert, non-combustible, inorganic absorbent material, sweep up and remove to an approved disposal container. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.

6.4 

Reference to other sections

No additional data available.

7.1 

Precautions for safe handling

Avoid spilling, skin and eye contact. Adopt best manual handling considerations when handling, carrying and dispensing.

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Keep away from heat, sparks and open flame.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

Linalool (CAS: 78-70-6)

Ingredient Comments :No exposure limits noted for ingredient.  

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Safety shower and eye bath.

Engineering Measures

Provide adequate ventilation.

Respiratory equipment.

Self-contained breathing apparatus.

Respiratory Equipment

Protection not required if good ventilation is maintained. Use inhalation protection in poorly ventilated areas.

Hand Protection

Use suitable protective gloves if risk of skin contact.

Eye Protection

Wear approved safety goggles.

Other Protection

Wear rubber apron.

Hygiene Measures

Remove contaminated clothing and wash the skin thoroughly with soap and water after work.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid

Colour

Pale yellow to amber.

Odour

Intensely sweet, Anise.

Relative Density

0.975 - 0.992 @ 20⁰C

Flash Point (°C)

>65⁰C

Refractive Index

1.5525 - 1.5600 @ 20⁰C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

Avoid heat, sparks and open flames.

10.5 

Incompatible materials

Materials To Avoid:

Strong acids, alkali or oxidising agents.

10.6 

Hazardous Decomposition Products

In case of fire, dangerous decomposition products can be generated, such as carbon monoxide and dioxide and nitrogen fumes and oxides.

11.1 

Information on toxicological effects 

Acute Toxicity

There is no data available on this product. It must be considered and handled and should be dealt with the highest possible caution.

Skin corrosion / irritation

No additional data available.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

No additional data available.

12.2 

Persistence & degradability

Degradability: No additional data available.

12.3 

Bioaccumulation Potential

Bioaccumulative potential:  No data available on bioaccumulation.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Dispose of in compliance with all local and national regulations.

14.1 

UN number

UN No. Road

None.

UN No. SEA

None.

UN No. AIR

None.

14.2 

UN proper shipping name

None.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:9 Miscellaneous dangerous substances and articles.

IMDG Class:9

ICAO Class/Division:9

Transport Labels

14.4 

Packing group

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

EMS F-A-S-F

Hazard No. (ADR) 9

Hazard No. (ADR) 90 Environmentally hazardous substance; miscellaneous dangerous substances.

Tunnel Restriction Code (E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H316 Causes mild skin irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

H402 Harmful to aquatic life.

H304 May be fatal if swallowed and enters airways.

H303 May be harmful if swallowed.

H317 May cause an allergic skin reaction.

H351 Suspected of causing cancer.

H341 Suspected of causing genetic defects.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None.

Revision Date

20/10/2015

Reason for revision

 Updated New Format SDS.

Rev No/Repl, SDS Generated

02