MSDS - Grapefruit Pink - Citrus paradisi - Essential Oil

1.1

Product Identifier 

Product Name 

Grapefruit Oil Pink    

Biological Definition

Citrus Paradisi Peel Oil is the volatile oil expressed from the peel of the Grapefruit, Citrus paradisi, Rutaceae.

INCI Name

Citrus Paradisi Peel Oil

Synonyms & Trade Names

-

CAS-No

8016-20-4

EC No.

N/A

EINECS No.

N/A

1.2

Relative identified uses of the substance or mixture and uses advised against

Relevant uses:     Perfumery, cosmetics, food

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

Flammable Liquid, Hazard Category 3  -  H226

Skin Corrosion / Irritation Category 2  -  H315

Sensitization - Skin Category 1  -  H317

Aspiration Hazard Category 1  -  H304

Hazardous to the aquatic environment - Acute hazard, Category 1 (Aquatic Acute 1, H400).

Hazardous to the Aquatic Environment – Aquatic Chronic  Category 1  -  H410

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

      GHS02GHS07          GHS08  GHS09

Signal Word

Danger.

Contains

601-029-00-7 (R)-P-MENTHA-1,8-DIENE

EC 204-622-5 MYRCENE

Hazard Statements

H226, Flammable liquid and vapour.

H304, May be fatal if swallowed and enters airways.

H315, Causes skin irritation.

H317, May cause an allergic skin reaction.

H410, Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking.

P273, Avoid release to the environment.

P280, Wear protective gloves/eye protection/face protection.

P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

P331, Do not induce vomiting.

Supplementary Precautionary Statements

P391 collect spillage.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

The substance does not satisfy the PBT or vPvP criteria in accordance with annexe XIII of the REACH regulations EC 1907/2006.

Adverse physio-chemical properties

No additional data available.  

Adverse effects on human health

No additional data available.  

3.2

Mixtures

≤ 95.0% Limonene CAS-No: 5989-27-5; EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Aquatic Acute 1 - H400,  M Acute = 1,   Aquatic Chronic 1 - H410, M Chronic = 1

≤ 93.0% Hydrocarbons

Classification (EC 1272/2008)Acute Tox. 4, H302,  Acute Tox. 4, H312

≤ 2.0% Myrcene CAS No: 123-35-3 ; EC No: 204-622-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Aquatic Chronic 3 - H412

4.1

Description of first aid measures

Inhalation 

Remove from exposure area to fresh air. Obtain medical advice if irritation persists.

Ingestion

Do not give the patient anything orally.

In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.

Seek medical attention immediately, showing the label.

If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital immediately by ambulance. Show the label to the doctor.

Skin Contact 

Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.

Watch out for any remaining product between skin and clothing, watches, shoes, etc.

In the event of an allergic reaction, seek medical attention.

If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.

Eye Contact   

Flush with plenty of water and seek medical advice.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Flammable.

Suitable extinguishing media:CO₂, Dry chemical powders and other extinguishing gases suitable fro small fires.

Keep packages near the fire cool, to prevent pressurised containers from bursting.

Prevent the effluent of fire-fighting measures from entering drains or waterways.

5.2 

Special hazards arising from the product

A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.  Do not breathe in smoke.

In the event of a fire, the following may be formed:     carbon monoxide (CO) and carbon dioxide (CO₂)

5.3 

Advice for firefighters

Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.

6.1 

Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under headings 7 and 8.

For non first aid worker

Avoid any contact with the skin and eyes.

For first aid worker

First aid workers will be equipped with suitable personal protective equipment (See section 8).

6.2 

Environmental Precautions

Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.

Prevent any material from entering drains or waterways.

If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures.

Use drums to dispose of collected waste in compliance with current regulations (see section 13).

6.3 

Methods and material for containment and cleaning up.

Remove ignition sources. Ensure adequate ventilation. Absorb with inert, non-combustible, inorganic absorbent material, sweep up and remove to an approved disposal container. Clean preferably with a detergent, do not use solvents.

6.4 

Reference to other sections

No additional data available.

7.1 

Precautions for safe handling

Requirements relating to storage premises apply to all facilities where the substance is handled.

Individuals with a history of skin sensitisation should not, under any circumstance, handle this substance.

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention:

Handle in well-ventilated areas. Prevent the formation of flammable or explosive concentrations in air and avoid vapour concentrations higher than the occupational exposure limits. Never inhale this substance. Prevent the accumulation of electrostatic charges with connections to earth. Use the mixture in premises free of naked flames or other sources of ignition and ensure that electrical equipment is suitably protected. Keep packages tightly closed and away from sources of heat, sparks and naked flames. Do not use tools which may produce sparks. Do not smoke. Prevent access by unauthorised personnel.

Recommended equipment and procedures:

For personal protection, see section 8. Observe precautions stated on label and also industrial safety regulations.

Prohibited equipment and procedures:

No smoking, eating or drinking in areas where the substance is used. Never open the packages under pressure.

7.2 

Conditions for safe storage, including any incompatibilities

Keep the container tightly closed in a dry, well-ventilated place. Keep away from food and drink, including those for animals. Keep away from all sources of ignition - do not smoke. Keep well away from all sources of ignition, heat and direct sunlight. Avoid accumulation of electrostatic charges.

PackagingAlways keep in packaging made of an identical material to the original.

7.3 

Specific end use(s) 

Use as an odour agent / flavouring agent: Use in accordance with good manufacturing and industrial hygiene practices.

8.1 

Control parameters 

No additional data available.  

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area.

Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation,

especially in confined areas.

Respiratory Equipment

Not necessary in adequate ventilation of working area. Avoid inhalation of vapours.

Hand Protection

Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must be selected according to the application and duration of use at the workstation. Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be

handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.

Recommended properties:  Impervious gloves in accordance with standard EN374

Eye Protection

Avoid contact with eyes.

Use eye protectors designed to protect against liquid splashes

Before handling, wear safety goggles in accordance with standard EN166.

Other Protection

Avoid skin contact. Wear suitable protective clothing.

Suitable type of protective clothing:

In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact. In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact. Work clothing worn by personnel shall be laundered regularly. After contact with the product, all parts of the body that have been soiled must be washed.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear protective clothing to avoid all skin contact.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid, red orange to yellow.  

Colour

Red orange to yellow.

Odour

Characteristic –  citrus, grapefruit.

Relative Density

0.845 – 0.865 @ 20°C

Flash Point (°C)

43.0

Refractive Index

1.473 – 1.478 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water. 

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, furnaces etc.) must not be allowed on the premises.

Avoid:

- accumulation of electrostatic charges.

- heating

- heat

- flames and hot surfaces

10.5 

Incompatible materials

No additional data available.

10.6 

Hazardous Decomposition Products

The thermal decomposition may release/form:     carbon monoxide (CO) and carbon dioxide (CO₂)

11.1 

Information on toxicological effects 

Acute Toxicity

HYDROCARBONS

Oral route: LD50 = 800 mg/kg

Dermal route: LD50 = 1300 mg/kg

Skin corrosion / irritation

May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours.

May cause an allergic reaction by skin contact.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

Monograph(s) from the IARC (International Agency for Research on Cancer):

CAS 5989-27-5 : IARC Group 3 : The agent is not classifiable as to its carcinogenicity to humans.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

Aspiration toxicity includes severe acute effects such as chemical pneumonia, varying degrees of pulmonary injury or death following aspiration.

 May be fatal if swallowed and enters airways.

Aspiration toxicity includes severe acute effects such as chemical pneumonia, varying degrees of pulmonary injury or death following

aspiration.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

Very toxic to aquatic life with long lasting effects.

The product must not be allowed to run into drains or waterways.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

Do not discharge into the environment especially not into waterways, sewers and the sea.

13.1 

Waste treatment  methods

Proper waste management of the substance and/or its container must be determined in accordance with Directive 2008/98/EC.

Waste treatment methods

Do not pour into drains or waterways.

Waste:

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.  Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company. Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging:

Empty container completely. Keep label(s) on container. Give to a certified disposal contractor.

14.1 

UN number

UN No. Road

UN 1169

UN No. SEA

UN 1169

UN No. AIR

UN 1169

14.2 

UN proper shipping name

UN1169 = Extracts, Aromatic, Liquid.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:3 Flammable Liquid. 

IMDG Class:3 Flammable Liquid.

ICAO Class/Division:3 Flammable Liquid.

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant.

14.6 

Special precautions for user

ADR/RID

Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel

3 F1 III 3 30 5 L 601 640E E1 3 D/E

IMDG

Class 2°Label Pack gr. LQ EMS Provis. EQ

3 - III 5 L F-E,S-D 223 955 E1

IATA

Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ

3 - III 355 60 L 366 220 L A3 E1

3 - III Y344 10 L - - A3 E1

For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG.

For excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H312 Harmful in contact with skin.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

Other Information

No additional data available.

Revision Date

12/09/2016

Reason for revision

Update to new format

Rev No/Repl, SDS Generated

02