MSDS - Fragonia - Agonis fragrans - Essential Oil

1.1

Product Identifier 

Product Name 

Fragonia Oil

Biological Definition

Agonis Fragrans Branch/Leaf Oil is the volatile oil obtained by steam distillation from the branches and leaves of Agonis fragrans, Myrtaceae.

INCI Name

Agonis Fragrans Branch / Leaf Oil

Synonyms & Trade Names

-

CAS-No

n/a

EC No.

n/a

EINECS No.

n/a

1.2

Relative identified uses of the substance or mixture and uses advised against

Fragrance use.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical HazardsFlammable Liquid Category 3

Human health Aspirational. Tox. 1

Skin Irritation Category 2

Skin Sensitizer Category 1A

Eye Irritation Category 2A

Environment Aquatic Chronic 1

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS02                 GHS08             GHS07         GHS09

Signal Word

Danger

Contains

α-Pinene , β-Pinene , Limonene, para-cymene, Myrcene, Geraniol

Hazard Statements

H226 Flammable liquid and vapour

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H319 Causes serious eye irritation

H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.  . 

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. 

P331: Do NOT induce vomiting. 

P501: Dispose of contents in accordance with local, state or national legislation. 

P261: Avoid breathing dust/fume/gas/mist/vapours/spray. 

P333+P313: If skin irritation or rash occurs: Get medical advice/attention. 

P362+P364: Take off contaminated clothing. And wash it before reuse. 

P302+P352: IF ON SKIN: Wash with plenty of water. 

P280: Wear protective gloves/protective clothing/eye protection/face protection. 

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 

P337+P313: If eye irritation persists: Get medical advice/attention. 

P273: Avoid release to the environment. 

P391: Collect spillage. 

Supplementary Precautionary Statements

P233: Keep container tightly closed. 

P264: Wash hands and exposed skin thoroughly after handling. 

P332+P313: If skin irritation occurs: Get medical advice/attention. 

P272: Contaminated work clothing should not be allowed out of the workplace. 

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

23.0 - 33.0% 1,8 Cineole  CAS No: 470-82-6   EC No: 207-431-5

Classification (EC 1272/2008) Flam. Liq. 3 – H226,  Skin Sens. 1 – H317

21.0  -  31.0% alpha-Pinene  CAS No:  80-56-8 EC No: 201-291-9

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 – H304, Skin Irrit. 2  - H315, Skin Sens. 1A - H317,

Aquatic Acute 1 -   H400, Aquatic Chronic 1 – H410 

6.0  -  13.0% Linalool  CAS No : 78-70-6 EC No : 201-134-4

Classification (EC 1272/2008) H315 Skin Irrit. 2 - H315,   Eye Irrit. 2 – H319

5.0 – 8.0% alpha-terpineol  CAS No:  98-55-5 EC No: 202-680-6

Classification (EC 1272/2008) H315 Skin Irrit. 2 - H315,   Eye Irrit. 2 – H319

2.0  -  6.0% Limonene CAS No: 5989-27-5 EC No: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410

1.0 – 5.0% para-cymeneCAS No:  99-87-6      EC No: 202-796-7

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Asp. Tox. 1  - H304,  Aquatic Chronic 2 –H411

2.0  -  4.5% terpinen-4-olCAS No: 562-74-3    EC No: 209-235-5

Classification (EC 1272/2008) Acute Tox. 4 -H302, Skin Irrit. 2 H315,    Eye Irrit. 2 – H319

1.0   – 2.0% beta-Pinene   CAS No: 127-91-3  EC No: 204-872-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 – H304, Skin Irrit. 2  - H315, Skin Sens. 1A - H317,

Aquatic Acute 1 -   H400, Aquatic Chronic 1 – H410 

1.0 – 2.0% Myrcene CAS No: 123-35-3 EC No: 204-622-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 – H304, Skin Irrit. 2 - H315, Eye Irrit. 2 – H319

< 2.0% CitronellolCAS No:  106-22-9    EC  No: 203-375-0

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Skin Sens. 1B – H317,   Eye Irrit. 2 – H319  

< 2.0% GeraniolCAS No: 106-24-1      EC No: 203-377-1

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Skin Sens. 1B – H317, Eye Dam. 1 – H318

4.1

Description of first aid measures

Inhalation 

Remove from exposure site to fresh air and keep at rest, seek medical advice if nausea persists.

Ingestion

Give water to rinse out mouth, then provide water slowly and as much as can comfortably drink,

DO NOT INDUCE VOMITING, call a POISON CENTRE and/or seek medical advice if nausea occurs.

Skin Contact 

Wash with warm, soapy water & remove contaminated clothing, seek medical advice if irritation occurs. Pre-existing skin, eye or respiratory problems may be aggravated by exposure.

Eye Contact   

Flush with water, remove contact lenses, if present and easy to do so, seek medical advice if irritation occurs. Pre-existing skin, eye or respiratory problems may be aggravated by exposure.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Extinguishing mediaUse as appropriate: Carbon dioxide (CO2), dry chemical or foam.

5.2 

Special hazards arising from the product

Flammable liquid and vapour, avoid contamination with oxidising agents as ignition may result, heat may cause violent rupture of containers if involved in a fire – cool with water spray, when heated to decomposition will produce acrid smoke and fumes.

5.3 

Advice for firefighters

Wear Self-Contained Breathing Apparatus (S.C.B.A.) and full protective clothing. Evacuate vicinity, contain spills.

6.1 

Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

In the event of a spillage or leak, remove all sources of ignition, do not smoke. If necessary use respiratory protection, protective clothing should be worn i.e., safety glasses or googles and gloves. Gather up in an inert medium like sand or earth, avoiding contamination of drains, surface and ground water and soil. In event of such a contamination notify the relevant authority.

6.4 

Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet.

7.1 

Precautions for safe handling

No additional data available.

7.2 

Conditions for safe storage, including any incompatibilities

Keep away from heat, sparks and open flame. It is recommended that this product is stored in well filled, tightly closed containers away from heat, light and ignition sources.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional data available.  

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station. Wash hands before breaks and at the end of work.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

For high concentrations use respiratory equipment.

Hand Protection

Chemical resistant gloves (PVC).

Eye Protection

Wear approved safety goggles.

Other Protection

Oil resistant apron, eyewash and safety shower recommended. Wash contaminated clothing before reuse.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid.  

Colour

Colourless to pale yellow

Odour

Characteristic.

Relative Density

Approx. 0.900 @ 20°C

Flash Point (°C)

46°C

Refractive Index

Approx. 1.470@ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

Product is not self-igniting.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

High temperatures and ignition sources.

10.5 

Incompatible materials

Materials To Avoid

Acids and bases, strong oxidizing agents.

10.6 

Hazardous Decomposition Products

No additional data available.

11.1 

Information on toxicological effects 

Acute Toxicity

No additional data available.

Skin corrosion / irritation

Causes skin irritation

Serious eye damage / irritation

Causes serious eye irritation

Respiratory or skin sensitisation

May cause an allergic skin reaction

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

May be fatal if swallowed and enters airways.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

No additional data available.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Dispose of in compliance with all local and national regulations.

14.1 

UN number

UN No. Road

1169

UN No. SEA

1169

UN No. AIR

1169

14.2 

UN proper shipping name

EXTRACTS, AROMATIC, LIQUID.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant.

14.6 

Special precautions for user

EMS Number: F-E,S-D

Emergency Action Code 3YE

Hazard No. (ADR) 30 Flammable liquid (flash-point between 23°C and 60°C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60°C, heated to a temperature equal to or above its flash-point, or self heating liquid.

Tunnel Restriction Code (D/E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG (108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None

Revision Date

20/01/2017

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01