1.1 |
Product Identifier |
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Product Name |
Spearmint Oil. |
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Biological Definition |
Mentha Spicata Oil is an essential oil obtained from the herbs of the Spearmint, Mentha spicata L., Labiatae (syn: Mentha viridis L., Labiatae). It contains carvone (more than 50%), limonene, pinene. |
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INCI Name |
Mentha Spicata Herb Oil. |
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Synonyms & Trade Names |
- |
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CAS-No |
84696-51-5 |
EC No. |
283-656-2 |
EINECS No. |
283-656-2 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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No additional data available. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements displayed in Section 16. |
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Classification (EC 1272/2008) |
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Aspiration toxicity Category 1 - (H304). Acute toxicity - Oral Category 4 - (H302). Skin corrosion/irritation Category 2 - (H315). Serious eye damage/eye irritation Category 2 - (H319). Skin sensitization Category 1 - (H317). Chronic aquatic toxicity Category 2 - (H411). |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS08 GHS07 GHS09
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Signal Word |
Danger. |
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Contains |
- |
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Hazard Statements |
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H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 - Do NOT induce vomiting. P302 + P352 - IF ON SKIN: Wash with plenty of soap and water. P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P273 - Avoid release to the environment. |
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Supplementary Precautionary Statements |
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None. |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available. |
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Adverse physio-chemical properties |
No additional data available. |
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Adverse effects on human health |
May be harmful in contact with skin. |
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3.1 |
Substance |
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Min 60.0% L-Carvone CAS-No.: 6485-40-1 EC No.: 229-352-5 Classification (EC 1272/2008) Aquatic Acute 3 (H402), Skin Sens. 1 (H317), Skin Irrit. 3 (H316), Acute Tox. 4 (H302), Acute Tox. 5 (H313).
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5.0 - 15.0% D-Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5 Classification (EC 1272/2008) Aquatic Acute 1 (H400), Skin Sens. 1(H317), Skin Irrit. 2 (315), Asp. Tox. 1 (H304), Aquatic Chronic 1 (H410), Flam. Liq. 3 (H226)
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4.1 |
Description of first aid measures |
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Inhalation |
Move to fresh air in case of accidental inhalation of vapours. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. |
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Ingestion |
Do not induce vomiting without medical advice. Clean mouth with water. Never give anything by mouth to an unconscious person. Get medical attention. |
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Skin Contact |
Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Wash contaminated clothing before reuse. Consult a physician if necessary. |
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Eye Contact |
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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None known. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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Treat symptomatically.
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5.1 |
Extinguishing Media |
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Suitable Extinguishing MediaUse CO2, dry chemical, or foam. Unsuitable extinguishing mediaNo information available. |
5.2 |
Special hazards arising from the product |
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Thermal decomposition can lead to release of irritating and toxic gases and vapours. Hazardous combustion products: Irritating or toxic substances may be emitted upon burning, combustion, or decomposition. |
5.3 |
Advice for firefighters |
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Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Personal precautionsEnsure adequate ventilation, especially in confined areas. For emergency respondersUse personal protection recommended in Section 8. |
6.2 |
Environmental Precautions |
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Collect spillage. |
6.3 |
Methods and material for containment and cleaning up. |
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Methods for Containment: Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).
Methods for cleaning up: Cover liquid spill with sand, earth or other non-combustible absorbent material. Sweep up and shovel into suitable containers for disposal. |
6.4 |
Reference to other sections |
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See Section 12: ECOLOGICAL INFORMATION. |
7.1 |
Precautions for safe handling |
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Advice on safe handling Ensure adequate ventilation, especially in confined areas.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. |
7.3 |
Specific end use(s) |
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Risk Management Methods (RMM) The information required is contained in this Material Safety Data Sheet. |
8.1 |
Control parameters |
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Chemical Name European Union United Kingdom France Spain Germany D-Limonene - - TWA: 1000 mg/m3 - TWA: 5ppm STEL: 1500 mg/m3 TWA: 28 mg/m3 Ceiling / Peak: 20 ppm Ceiling / Peak: 112 mg/m3 Skin
Chemical Name Italy Portugal Netherlands Finland Denmark - - - TWA: 25ppm - TWA: 140 mg/m3 STEL: 50ppm STEL: 280 mg/m3
Chemical Name Austria Switzerland Poland Norway Ireland - STEL: 14ppm - TWA: 25ppm - STEL 80 mg/m3 TWA: 140 mg/m3 TWA: 7ppm TEL: 37.5 ppm TWA: 40 mg/m3 STEL: 175 mg/m3
Derived No Effect Level (DNEL)No information available Predicted No Effect Concentration (PNEC)No information available. |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
No additional data available. |
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Engineering Measures |
Ensure adequate ventilation, especially in confined areas. |
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Respiratory Equipment |
No additional data available. |
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Hand Protection |
No additional data available. |
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Eye Protection |
Avoid contact with eyes. Wear safety glasses with side shields (or goggles). |
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Other Protection |
No additional data available. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. |
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Personal Protection |
No additional data available. |
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Skin Protection |
Suitable protective clothing. |
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Environmental Exposure Controls |
No additional data available.
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Clear mobile liquid. |
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Colour |
Colourless to green yellow. |
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Odour |
Characteristic. |
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Relative Density |
0.910 – 0.938 @ 20°C. |
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Flash Point (°C) |
58 °C / 137 °F |
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Refractive Index |
1.480 – 1.495 @ 20°C. |
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Melting Point (°C) |
No additional data available. |
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Boiling Point (°C) |
No additional data available. |
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Vapour Pressure |
0.4 |
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Solubility in Water @20°C |
Insoluble in water. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10.1 |
Reactivity |
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No additional data available. |
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10.2 |
Chemical stability |
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Stable under normal conditions. Explosion data Sensitivity to Mechanical ImpactNone. Sensitivity to Static DischargeNone. |
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10.3 |
Possible hazardous reactions |
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Possibility of Hazardous ReactionsNone under normal processing. |
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10.4 |
Conditions to Avoid |
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Extremes of temperature and direct sunlight. |
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10.5 |
Incompatible materials |
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No additional data available. |
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10.6 |
Hazardous Decomposition Products |
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None under normal use conditions. |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
L-Carvone Oral LD50 = 1640 mg/kg (rat) D-LimoneneOral LD50 = 4400 mg/kg (rat) Dermal LD50 >5 g/kg (rabbit)
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Skin corrosion / irritation |
No additional data available. |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
No additional data available. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
No additional data available. |
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Photo-toxicity |
No additional data available. |
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Other Information |
None. |
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12.1 |
Toxicity |
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23 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea D-Limonene - 0.619 - 0.796: 96 h Pimephales - promelas mg/L LC50 flow-through 35: 96 h Oncorhynchus mykiss mg/L LC50 |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available. |
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12.6 |
Other adverse effects |
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No additional data available. |
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13.1 |
Waste treatment methods |
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Waste from Residues / Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal.. |
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14.1 |
UN number |
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UN No. Road |
3082 |
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UN No. SEA |
3082 |
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UN No. AIR |
3082 |
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14.2 |
UN proper shipping name |
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Environmentally Hazardous Substance, liquid n.o.s. |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class 9 IMDG Class 9 ICAO Class/Division 9
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant.
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14.6 |
Special precautions for user |
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None. |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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EmS: F-A,S-F |
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H400 - Very toxic to aquatic life H317 - May cause an allergic skin reaction H304 - May be fatal if swallowed and enters airways H410 - Very toxic to aquatic life with long lasting effects H226 - Flammable liquid and vapour H315 - Causes skin irritation H402 - Harmful to aquatic life H302 - Harmful if swallowed H313 - May be harmful in contact with skin |
Other Information |
None. |
Revision Date |
17/03/2016 |
Reason for revision |
New format and updated SDS. |
Rev No/Repl, SDS Generated |
02 |