MSDS - Sage (Spanish) - Salvia officinalis - Essential Oil

1.1

Product Identifier 

Product Name 

Sage Oil Spanish

Biological Definition

The volatile oil steam distilled from the leaves of Salvia officinalis L.

INCI Name

Salvia officinalis oil

Synonyms & Trade Names

Sage oil Dalmatian

CAS-No

8016-64-6

EC No.

282-025-9

EINECS No.

282-025-9

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text, for all Hazard Statements, is displayed in Section 16.

Human health

May be fatal if swallowed and enters airways.

Environment

The product contains a substance which is toxic to aquatic life and may cause long term adverse effects.

Classification (EC 1272/2008)

Flam. Liq. 3     H226 Flammable liquid and vapour.

STOT SE 2     H371 May cause damage to organs.

Asp. Tox. 1     H304 May be fatal if swallowed and enters airways.

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

Acute Tox. 4     H302 Harmful if swallowed.

Skin Irrit. 2     H315 Causes skin irritation.

Skin Sens. 1     H317 May cause an allergic skin reaction.

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS08           GHS09          GHS07          GHS02

Signal Word

Danger

Contains

Thujone, Eucalyptol, Camphor, pin-2(3)-ene

Hazard Statements

H226                Flammable liquid and vapour.

H302                Harmful if swallowed.

H315                Causes skin irritation.

H317                May cause an allergic skin reaction.

H371                May cause damage to organs.

H304                May be fatal if swallowed and enters airways.

H411                Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210                Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P241                Use explosion-proof electrical/ventilating/lighting/equipment.

P301+P310          IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin  with water/shower.

P405                Store locked up.

P501                Dispose of contents/container in accordance with local/regional/national/international           regulations.

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

Not applicable.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

25-50% Thujone  CAS: 546-80-5  EINECS: 208-912-2

Classification (EC 1272/2008):  Acute Tox. 4, H302

10-25%  Camphor CAS: 21368-68-3 EINECS: 244-350-4

Classification (EC 1272/2008):  Flam. Sol. 2, H228; STOT SE 2, H371; Acute Tox. 4, H302; Acute Tox. 4, H332

10-25% Eucalyptol CAS: 470-82-6  EINECS: 207-431-5

Classification (EC 1272/2008):  Flam. Liq. 3, H226; Skin Sens. 1, H317

2.5-10% pinenesCAS: 80-56-8  EINECS: 201-291-9

Classification (EC 1272/2008):  Flam. Liq. 3, H226; Asp. Tox. 1, H304; Skin Irrit. 2, H315; Skin Sens. 1, H317

2.5-10% beta-caryophyllene CAS: 87-44-5  EINECS: 201-746-1

Classification (EC 1272/2008):  Asp. Tox. 1, H304

2.5-10% CampheneCAS: 79-92-5  EINECS: 201-234-8

Classification (EC 1272/2008):  Flam. Sol. 1, H228; Aquatic Acute 1, H400; Aquatic Chronic 1, H410;
Eye Irrit. 2, H319.

2.5-10% DL-borneolCAS: 507-70-0  EINECS: 208-080-0

Classification (EC 1272/2008):  Flam. Sol. 2, H228

≤ 2.5% beta pineneCAS: 127-91-3  EINECS: 204-872-5

Classification (EC 1272/2008):  Flam. Liq. 3, H226; Asp. Tox. 1, H304; Skin Irrit. 2, H315; Skin Sens. 1, H317

≤ 2.5% bornyl acetateCAS: 76-49-3   EINECS: 200-964-4

Classification (EC 1272/2008):  Aquatic Chronic 2, H411; Skin Irrit. 2, H315

≤ 2.5% d-limoneneCAS: 5989-27-5   EINECS: 227-813-5

Classification (EC 1272/2008):  Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Acute 1, H400;
Aquatic Chronic 1, H410; Skin Irrit. 2, H315; Skin Sens. 1, H317

≤ 2.5% p-cymeneCAS: 99-87-6   EINECS: 202-796-7

Classification (EC 1272/2008):  Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2, H411

4.1

Description of first aid measures

Inhalation 

Remove immediately from source of exposure. Seek medical attention if any discomfort continues.

 Ingestion

Do not give milk or fatty oils.  Immediately rinse mouth and provide fresh air. Seek medical attention immediately.

Skin Contact 

Remove contaminated clothing immediately and wash skin with soap and water. Seek medical attention if any discomfort continues or there is sign of tissue damage.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Seek medical attention immediately. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Extinguishing media: Carbon dioxide (CO2). Powder. Water spray. For larger fires, use water spray or alcohol resistant foam.

Unsuitable extinguishing media: Full water jet.

5.2 

Special hazards arising from the product

Carbon monoxide (CO) may be formed.

5.3 

Advice for firefighters

No special measures required.

6.1 

Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet. Handle the product using protective gloves resistant to the chemicals exposed. Avoid contact with skin and inhalation of its vapours or smoke. Maintain adequate ventilation in the working area after spilling.

6.2 

Environmental Precautions

Inform respective authorities in case of seepage into water course or sewage system. Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Dispose contaminated material as waste according to item 13.

Ensure adequate ventilation.

6.4 

Reference to other sections

Section 7 – for safe handling

Section 8 – for personal protection

Section 13 – for safe disposal

7.1 

Precautions for safe handling

Ensure ventilation is good. Keep away from food, drink and animal feed products. When using do not smoke. Avoid sources of ignition and contact with skin and eyes. Handle in accordance with good hygiene and safety practice.

7.2 

Conditions for safe storage, including any incompatibilities

Keep product in its original container well sealed, in a dark, dry, ventilated area, away from potential sources of ignition and protected from light. Stock according to local / national regulations and always follow the precautions indicated on labels.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

No special measures required.

Hand Protection

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

Penetration time of glove material

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye Protection

Wear approved safety goggles.

Other Protection

Keep away from foodstuffs, beverages and feed.  Immediately remove all soiled and contaminated clothing.  Wash hands before breaks and at the end of work.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Wear appropriate equipment to avoid contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid.

Colour

Pale yellow.

Odour

Characteristic – herbaceous.

Relative Density

0.905 - 0.925 @ 20°C

Flash Point (°C)

57

Refractive Index

1.460 - 1.474 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water. Soluble in ethanol.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

No dangerous reactions known.

10.4 

Conditions to Avoid

No additional data available.

10.5 

Incompatible materials

No additional data available.

10.6 

Hazardous Decomposition Products

No dangerous decomposition products known.

11.1 

Information on toxicological effects 

Acute Toxicity

No additional data available.

Skin corrosion / irritation

Irritant to skin and mucous membranes.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

Sensitisation possible through skin contact.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version:

Harmful

Irritant

12.1 

Toxicity

Toxic for fish. Do not allow product to reach ground water, water course or sewage system, even in small quantities. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

Not applicable.

12.6 

Other adverse effects

Do not allow product to enter streams, sewers or other waterways.

13.1 

Waste treatment  methods

Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Uncleaned packaging:

Recommendation: Disposal must be made according to official regulations.

14.1 

UN number

UN No. Road

1993

UN No. SEA

1993

UN No. AIR

1993

14.2 

UN proper shipping name

ADRFLAMMABLE LIQUID, N.O.S. (not viscous) (alpha- PINENE, Thujone), ENVIRONMENTALLY               HAZARDOUS
IMDGFLAMMABLE LIQUID, N.O.S. (alpha-PINENE, Thujone), MARINE POLLUTANT
IATAFLAMMABLE LIQUID, N.O.S. (alpha-PINENE, Thujone)

14.3 

Transport hazard class(es)

ADR/RID/ADN Class: 3: (F1) Flammable liquids

IMDG Class:3: Flammable liquids

ICAO Class/Division:3:  Flammable liquids

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing groupIII

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant;  Camphene

14.6 

Special precautions for user

Warning: flammable liquids

EMS  Number :  F-E, S-D

Danger  Code (Kemler): 36

Tunnel restriction code:D/E

Limited Quantities (LQ)Excepted Quantities (EQ)

ADR & IMDG5LCode: E1

Maximum net quantity per inner packaging: 30 ml

Maximum net quantity per outer packaging: 1000 ml

UN “Model Regulation”UN1993, FLAMMABLE LIQUID, N.O.S. (not viscous) (alpha-PINENE, Thujone),                                           ENVIRONMENTALLY HAZARDOUS, 3, III

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

Not applicable.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H228Flammable solid.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H371 May cause damage to organs.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None

Revision Date

10/07/2015

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01