MSDS - Rose - Rosa centifolia - Absolute

1.1

Product Identifier 

Product Name 

Rose Absolute Centifolia

Biological Definition

Rosa Centifolia Flower Extract is an extract of the flowers of the Cabbage Rose, Rosa centifolia (L.), Rosaceae.

INCI Name

Rosa Centifolia Flower Extract.

Synonyms & Trade Names

Rosa Centifolia Flower  Extract.

CAS-No

84604-12-6

EC No.

283-289-8

EINECS No.

283-289-8

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements is Displayed in Section 16.

Human health

The liquid may be irritating to skin. May cause serious eye damage. 

Environment

The product contains a substance which is very toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment.

Classification (EC 1272/2008)

Physical and Chemical Hazards: Not classified.

Human health: Skin Irrit. 2 - H315

                                             Eye Dam. 1 - H318

Skin Sens. 1 - H317

Environment: Aquatic Chronic 3 - H412

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

    GHS05           GHS07  

Signal Word

Danger.

Contains

Phenethyl alcohol, Citronellol, Geraniol, Eugenol, Nerol, Eugenol Methyl Ether, benzyl alcohol, (R)-p-mentha-1,8-diene.

Hazard Statements

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing vapour/spray.

P264 Wash contaminated skin thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of water.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor.

P321 Specific treatment (see medical advice on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P501 Dispose of contents/container in accordance with national regulations.

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

> 50% Phenyl Ethyl Alcohol CAS-No.: 60-12-8, EC No 200-456-2

Classification (EC 1272/2008) : Acute Tox. 4 - H302, Eye Irrit. 2 - H319

5 - 10%Citronellol CAS-No.: 106-22-9, EC No.: 203-375-0

Classification (EC 1272/2008) : Skin Irrit. 2 - H315,  Eye Irrit. 2 - H319,  Skin Sens. 1 - H317

5 - 10% Geraniol CAS-No.: 106-24-1, EC No.: 203-377-1

Classification (EC 1272/2008) : Skin Irrit. 2 - H315,  Eye Dam. 1 - H318,  Skin Sens. 1 - H317

1 - 5% Benzyl Alcohol CAS-No.: 100-51-6, EC No.: 202-859-9

Classification (EC 1272/2008) : Acute Tox. 4 - H302,  Acute Tox. 4 - H332

1 - 5% Nerol CAS-No.: 106-25-2, EC No.: 203-378-7

Classification (EC 1272/2008) : Skin Irrit. 2 - H315,  Eye Irrit. 2 - H319,  Skin Sens. 1 - H317

1 - 5% Eugenol Methyl Ether CAS-No.: 93-15-2, EC No 202-223-0

Classification (EC 1272/2008) : Acute Tox. 4 - H302,  Muta. 2 - H341,  Carc. 2 - H351, 

1 - 5% Eugenol CAS-No.: 97-53-0, EC No.: 202-589-1

Classification (EC 1272/2008) : Eye Irrit. 2 - H319,  Skin Sens. 1 - H317

1 - 5% 7-methyl-3-methyleneocta-1,6-diene CAS-No.: 123-35-3,EC No.: 204-622-5

Classification (EC 1272/2008) : Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,  Eye Irrit. 2 - H319,  Asp. Tox. 1 - H304

<1% Linalool CAS-No.: 78-70-6, EC No 201-134-4

Classification (EC 1272/2008) : Acute Tox. 5 - H303,  Skin Irrit. 2 - H315,  Aquatic Acute 3 - H402

<1% (R)-p-mentha-1,8-diene CAS-No.: 5989-27-5, EC No 227-813-5

M factor (Acute) = 1,    M factor (Chronic) = 1

Classification (EC 1272/2008) : Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,  Skin Sens. 1 - H317,Asp. Tox. 1 - H304,  Aquatic Acute 1 - H400,  Aquatic Chronic 1 - H410

<1% Citral CAS-No.: 5392-40-5, EC No.: 226-394-6

Classification (EC 1272/2008) : Skin Irrit. 2 - H315,  Eye Irrit. 2 - H319,  Skin Sens. 1 - H317

4.1

Description of first aid measures

Inhalation 

Move affected person to fresh air at once. Get medical attention if any discomfort continues.

 Ingestion

Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attention if any

discomfort continues.

Skin Contact 

Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention if

any discomfort continues.

Eye Contact   

Remove any contact lenses and open eyelids wide apart. Rinse with water. Continue to rinse

for at least 15 minutes and get medical attention.

4.2

Most important symptoms and effects, both acute and delayed

Skin contact:This product is corrosive. Causes skin irritation.

Eye contact:Causes serious eye damage.

4.3

Indication of any immediate medical attention and special treatment needed

Notes for the doctor: Treat symptomatically.

5.1 

Extinguishing Media

Extinguishing media:  Carbon dioxide (CO2). Powder. Water spray. Fight larger fires with water spray or alcohol resistant foam.

Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire.

5.2 

Special hazards arising from the product

No additional data available.

5.3 

Advice for firefighters

Special Fire Fighting Procedures - In case of fire: Cool containers exposed to flames with water until well after the fire is out.
Protective equipment for fire-fighters - Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.

6.1 

Personal precautions, protective equipment and emergency procedures

Keep unnecessary and unprotected personnel away from the spillage. No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with skin, eyes and clothing. Provide adequate ventilation. For personal protection, see Section 8.ear protective clothing as described in Section 8 of this safety data sheet. Handle the product using protective gloves resistant to the chemicals exposed. Avoid contact with skin and inhalation of its vapours or smoke. Maintain adequate ventilation in the working area after spilling.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or courses of ignition. Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations.

6.4 

Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet.

7.1 

Precautions for safe handling

Do not eat, drink or smoke when using this product. Provide eyewash station and safety

shower. Read label before use. Wear protective clothing as described in Section 8 of this safety data

sheet. Avoid contact with skin and eyes. Eliminate all sources of ignition. Do not eat, drink or

smoke when using this product. 

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep away

from food and drink. 

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional data available.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

No specific requirements are anticipated under normal conditions of use.

Hand Protection

Chemical resistant gloves (PVC).

Eye Protection

Wear approved safety goggles.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid

Colour

Dark red to orange. 

Odour

Characteristic

Relative Density

0.950  -  1.100 @ 20°C

Flash Point (°C)

87

Refractive Index

1.495  -  1.520 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

There are no known reactivity hazards associated with this product.

10.2 

Chemical stability

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

None known.

10.4 

Conditions to Avoid

Avoid heat, sparks, flames and other sources of ignition.

10.5 

Incompatible materials

Avoid strong acids and strong  oxidising agents.

10.6 

Hazardous Decomposition Products

None known.

11.1 

Information on toxicological effects 

Acute Toxicity

ATE inhalation (vapours mg/l) 550.0

Skin corrosion / irritation

No additional data available.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

The product contains a substance which is very toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

Do not allow product to enter streams, sewers or other waterways. Water hazard classification WGK 2

13.1 

Waste treatment  methods

Dispose of in compliance with all local and national regulations. Residues and empty containers should be taken care of as hazardous waste according to local and national provisions.      

14.1 

UN number

UN No. Road

Not bound by transport regulations.

UN No. SEA

Not bound by transport regulations.

UN No. AIR

Not bound by transport regulations.

14.2 

UN proper shipping name

Not bound by transport regulations.

14.3 

Transport hazard class(es)

Not bound by transport regulations.

14.4 

Packing group

Not bound by transport regulations.

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

Water hazard classification WGK 2

14.6 

Special precautions for user

No additional data available.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H341 Suspected of causing genetic defects.

H351 Suspected of causing cancer.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H412 Harmful to aquatic life with long lasting effects.

Other Information

None.

Revision Date

16/03/2016

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01