MSDS - Ravensara - Ravensara aromatica - Essential Oil

1.1

Product Identifier 

Product Name 

Ravensara Oil.

Biological Definition

Ravensara Aromatica Leaf Oil is the volatile oil distilled from the leaves of Ravensara aromatica, Lauraceae.

INCI Name

Ravensara Aromatica Leaf Oil

Synonyms & Trade Names

Ravensara Aromatica Oil

CAS-No

91770-56-8

EC No.

294-842-8

EINECS No.

294-842-8

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

Flammable liquid, Category 3 (Flam. Liq. 3, H226).

Skin irritation, Category 2 (Skin Irrit. 2, H315).

Eye irritation, Category 2 (Eye Irrit. 2, H319).

Skin sensitisation, Category 1 (Skin Sens. 1, H317).

Germ cell mutagenicity, Category 2 (Muta. 2, H341).

Carcinogenicity, Category 2 (Carc. 2, H351).

Aspiration hazard, Category 1 (Asp. Tox. 1, H304).

Hazardous to the aquatic environment - Chronic hazard, Category 2 (Aquatic Chronic 2, H411).

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

      GHS08            GHS07            GHS09             GHS02

Signal Word

Danger.

Contains

601-029-00-7 (R)-P-MENTHA-1,8-DIENE

EC 205-427-8 ESTRAGOLE

EC 236-719-3 DELTA-3-CARENE

EC 201-291-9 ALPHA-PINENE X

EC 204-622-5 MYRCENE

EC 202-223-0 EUGENYL METHYL ETHER (METHYL EUGENOL)

EC 204-872-5 B-PINENE

EC 201-746-1 BETA-CARYOPHYLLENE

EC 202-792-5 A-PHELLANDRENE

EC 202-794-6 G-TERPINENE

EC 202-795-1 P-MENTHA-1,3-DIENE (SEE ALPHA-TERPINENE)

Hazard Statements

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H341 Suspected of causing genetic defects.

H351 Suspected of causing cancer.

H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection..

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

The substance does not satisfy the PBT or vPvP criteria in  accordance with annexe XIII of the REACH regulations EC 1907/2006..

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

10.0 - 25.0% (R)-P-MENTHA-1,8-DIENE CAS: 5989-27-5, EC: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317, Aquatic Acute 1, H400

M Acute = 1, Aquatic Chronic 1, H410, M Chronic = 1

10.0 - 25.0% 4(10)-THUJENE CAS: 3387-41-5, EC: 222-212-4

Classification (EC 1272/2008)

2.5 – 10.0% ESTRAGOLE CAS: 140-67-0, EC: 205-427-8

Classification (EC 1272/2008) Acute Tox. 4, H302, Carc. 2, H351, Muta. 2, H341, Skin Sens. 1, H317

2.5 – 10.0% DELTA-3-CARENE CAS: 13466-78-9, EC: 236-719-3

Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317

2.5 – 10.0% Alpha-pinene CAS-No.: 80-56-8 EC No.: 201-291-9

Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317

2.5 – 10.0% Linalool CAS: 78-70-6, EC: 201-134-4

Classification (EC 1272/2008) Eye Irrit. 2, H319, Skin Irrit. 2, H315

2.5 – 10.0% MYRCENE CAS: 123-35-3, EC: 204-622-5

Classification (EC 1272/2008) Asp. Tox. 1, H304, Eye Irrit. 2, H319, Flam. Liq. 3, H226, Skin Irrit. 2, H315

2.5 - 10.0% 4-TERPINENOL CAS: 562-74-3, EC: 209-235-5

Classification (EC 1272/2008); Acute Tox. 4, H302, Eye Irrit. 2, H319, Skin Irrit. 2, H315

2.5 – 10.0% EUGENYL METHYL ETHER (METHYL EUGENOL) CAS: 93-15-2, EC: 202-223-0

Classification (EC 1272/2008) Acute Tox. 4, H302, Carc. 2, H351, Muta. 2, H341

2.5 – 10.0% B-PINENE CAS: 127-91-3, EC: 204-872-5

Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226,  Skin Irrit. 2, H315, Skin Sens. 1, H317

2.5 – 10.0% EUCALYPTOL CAS: 87-44-5, EC: 201-746-1

Classification (EC 1272/2008) Asp. Tox. 1, H304

2.5 – 10.0% BETA-CARYOPHYLLENE CAS: 87-44-5, EC: 201-746-1

Classification (EC 1272/2008) Asp. Tox. 1, H304

2.5 – 10.0% A-PHELLANDRENE CAS: 99-83-2, EC: 202-792-5

Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226

<2.5% G-TERPINENE CAS: 99-85-4, EC: 202-794-6

Classification (EC 1272/2008) Asp. Tox. 1, H304, Flam. Liq. 3, H226

<2.5% CAMPHENE CAS: 79-92-5, EC: 201-234-8

Classification (EC 1272/2008) Eye Irrit. 2, H319, Aquatic Acute 1, H400, M Acute = 1, Aquatic Chronic 1, H410

M Chronic = 1

<2.5% P-MENTHA-1,3-DIENE (SEE ALPHA-TERPINENE) CAS: 99-86-5, EC: 202-795-1

Classification (EC 1272/2008) Asp. Tox. 1, H304, Acute Tox. 4, H302, Aquatic Chronic 2, H411, Flam. Liq. 3, H226

4.1

Description of first aid measures

Inhalation 

Move to fresh air for at least 15 minutes, in case of complaints seek medical attention.

Ingestion 

Do not give the patient anything orally.

In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.

Seek medical attention immediately, showing the label.

If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital immediately by ambulance. Show the label to the doctor.

Skin Contact 

Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.

Watch out for any remaining product between skin and clothing, watches, shoes, etc.

In the event of an allergic reaction, seek medical attention.

If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.

Eye Contact   

Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.

If there is any redness, pain or visual impairment, consult an ophthalmologist.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Keep packages near the fire cool, to prevent pressurised containers from bursting.

Suitable methods of extinction

Prevent the effluent of fire-fighting measures from entering drains or waterways.

5.2 

Special hazards arising from the product

A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.

Do not breathe in smoke.

In the event of a fire, the following may be formed :

- carbon monoxide (CO)

- carbon dioxide (CO2).

5.3 

Advice for firefighters

Fire-fighting personnel are to be equipped with autonomous insulating breathing apparatus.

6.1 

Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under headings 7 and 8.

For non first aid worker

Avoid any contact with the skin and eyes.

For first aid worker

First aid workers will be equipped with suitable personal protective equipment (See section 8).

6.2 

Environmental Precautions

Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.

Prevent any material from entering drains or waterways.

If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures.

Use drums to dispose of collected waste in compliance with current regulations (see section 13).

6.3 

Methods and material for containment and cleaning up.

Clean preferably with a detergent, do not use solvents.

6.4 

Reference to other sections

No additional data available.

7.1 

Precautions for safe handling

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention :

Handle in well-ventilated areas.

Prevent the formation of flammable or explosive concentrations in air and avoid vapor concentrations higher than the occupational exposure limits.

Never inhale this substance.

Prevent the accumulation of electrostatic charges with connections to earth.

Use the mixture in premises free of naked flames or other sources of ignition and ensure that electrical equipment is suitably protected.

Keep packages tightly closed and away from sources of heat, sparks and naked flames.

Do not use tools which may produce sparks. Do not smoke.

Prevent access by unauthorised personnel.

Recommended equipment and procedures :

For personal protection, see section 8.

Observe precautions stated on label and also industrial safety regulations.

Avoid skin and eye contact with this substance.

Avoid exposure - obtain special instructions before use.

Prohibited equipment and procedures :

No smoking, eating or drinking in areas where the substance is used.

Never open the packages under pressure.

7.2 

Conditions for safe storage, including any incompatibilities

Storage

Keep the container tightly closed in a dry, well-ventilated place.

Keep away from food and drink, including those for animals.

Keep away from all sources of ignition - do not smoke.

Keep well away from all sources of ignition, heat and direct sunlight.

Avoid accumulation of electrostatic charges.

Packaging

Always keep in packaging made of an identical material to the original.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

Occupational exposure limits :

ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) :

CAS                   TWA :                      STEL :                      Ceiling :             Definition :           Criteria :

13466-78-9      20 ppm                   -                               -                          -                             -

80-56-8             20 ppm                   -                               -                          -                             -

127-91-3           20 ppm                   -                               -                         -                              -

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Where appropriate, use closed system to transfer and process this material – if appropriate, isolate mixing rooms and other areas.

Where this material is used or openly handled - maintain these areas under negative air pressure relative to the rest of the plant.

Respiratory Equipment

Not necessary in adequate local with general ventilation - avoid breathing vapours.

Hand Protection

Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.

Gloves must be selected according to the application and duration of use at the workstation.

Protective gloves need to be selected according to their suitability for the workstation in question: other chemical products that may be handled, necessary physical  protections (cutting, pricking, heat protection), level of dexterity required.

Recommended properties :

- Impervious gloves in accordance with standard EN374

Eye Protection

Avoid contact with eyes.

Use eye protectors designed to protect against liquid splashes

Before handling, wear safety goggles with protective sides in accordance with standard EN166.

In the event of high danger, protect the face with a face shield.

Prescription glasses are not considered as protection.

Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours.

Provide eyewash stations in facilities where the product is handled constantly.

Other Protection

Protective work clothing solvent resistant (should be checked regularly).

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

No additional data available.

Skin Protection 

Avoid skin contact.

Wear suitable protective clothing.

Suitable type of protective clothing :

In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact.

In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact.

Work clothing worn by personnel shall be laundered regularly.

After contact with the product, all parts of the body that have been soiled must be washed.

Environmental Exposure Controls 

The usual precautions in handling chemicals have to be observed.

9.1 

Information on basic physical and chemical properties 

Appearance

Mobile liquid.

Colour

Colourless to pale yellow.

Odour

Characteristic.

Relative Density

0.870 – 0.930 @ 20⁰C

Flash Point (°C)

50⁰C

Refractive Index

1.450 – 1.490 @ 20⁰C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

This substance is stable under the recommended handling and storage conditions in section 7.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

Any apparatus likely to produce a flame or to have a metallic surface at high temperature (burners, electric arcs, furnaces etc.) must not be allowed on the premises.

Avoid :

- accumulation of electrostatic charges.

- heating

- heat

- flames and hot surfaces.

10.5 

Incompatible materials

No additional data available.

10.6 

Hazardous Decomposition Products

The thermal decomposition may release/form :

- carbon monoxide (CO)

- carbon dioxide (CO2)

11.1 

Information on toxicological effects 

Acute Toxicity

P-MENTHA-1,3-DIENE (SEE ALPHA-TERPINENE) (CAS: 99-86-5)

Oral route : LD50 = 1680 mg/kg

G-TERPINENE (CAS: 99-85-4)

Oral route : LD50 = 3850 mg/kg

EUCALYPTOL (CAS: 470-82-6)

Oral route : LD50 = 2480 mg/kg

EUGENYL METHYL ETHER (METHYL EUGENOL) (CAS: 93-15-2)

Oral route : LD50 = 810 mg/kg

4-TERPINENOL (CAS: 562-74-3)

Oral route : LD50 = 1300 mg/kg

Dermal route : LD50 = 2500 mg/kg

LINALOOL (CAS: 78-70-6)

Oral route : LD50 = 3000 mg/kg

ALPHA-PINENE X (CAS: 80-56-8)

Oral route : LD50 = 3700 mg/kg

DELTA-3-CARENE (CAS: 13466-78-9)

Oral route : LD50 = 4800 mg/kg

ESTRAGOLE (CAS: 140-67-0)

Oral route : LD50 = 1230 mg/kg

Skin corrosion / irritation

May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours.

May cause an allergic reaction by skin contact.

Serious eye damage / irritation

May have reversible effects on the eyes, such as eye irritation which is totally reversible by the end of observation at 21 days.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

Cause for concern owing to the possibility that it may induce heritable mutations in the germ cells of humans.

Carcinogenicity

Suspected human carcinogen.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

Aspiration toxicity includes severe acute effects such as chemical  pneumonia, varying degrees of pulmonary injury or death following aspiration.

May be fatal if swallowed and enters airways.

Photo-toxicity

No additional data available.

Other Information

CAS 93-15-2 : IARC Group 2B : The agent is possibly carcinogenic to humans.

CAS 5989-27-5 : IARC Group 3 : The agent is not classifiable as to its carcinogenicity to humans..

12.1 

Toxicity

Toxic to aquatic life with long lasting effects.

The product must not be allowed to run into drains or waterways.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Do not pour into drains or waterways.

Waste :

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.

Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.

Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging :

Empty container completely. Keep label(s) on container.

Give to a certified disposal contractor.

14.1 

UN number

UN No. Road

1169

UN No. SEA

1169

UN No. AIR

1169

14.2 

UN proper shipping name

Extracts, aromatic, liquid.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class 3

ADR/RID/ADN Class 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant.

14.6 

Special precautions for user

ADR/RID

Class        Code           Pack gr.           Label         Ident.           LQ        Provis.            EQ             Cat.          Tunnel

3               F1                III                      3                30                 5 L       601 640E        E1              3               D/E

IMDG

Class        2° Label                Pack gr.          LQ        EMS            Provis.                EQ

3               -                             III                    5 L        F-E,S-D        223 955             E1

IATA

Class        2°Label                 Pack gr.        Passager         Passager       Cargo        Cargo      note       EQ

3               -                             III                   355                  60 L               366            220 L      A3           E1

3               -                             III                   Y344                10 L               -                  -              A3          E1.

For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG.

For excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H228 Flammable solid.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H341 Suspected of causing genetic defects.

H351 Suspected of causing cancer.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None.

Revision Date

24/02/2016

Reason for revision

New format and updated SDS.

Rev No/Repl, SDS Generated

02