1.1 |
Product Identifier |
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Product Name |
Pine Needle Oil Sylvestris |
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Biological Definition |
Pinus Sylvestris Leaf Oil is the volatile oil obtained from the needles of the Scotch Pine, Pinus sylvestris L., Pinaceae |
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INCI Name |
Pinus Sylvestris Leaf Oil |
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Synonyms & Trade Names |
- |
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CAS-No |
8023-99-2 / 84012-35-1 |
EC No. |
- / 281-679-2 |
EINECS No. |
- / 281-679-2 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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Perfumes, fragrances. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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Harmful Dangerous for the environment |
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Classification (EC 1272/2008) |
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Physical and Chemical Hazards : Flam. Liq. 3 (H226) Human health Asp. : Asp. Tox. 1 - H304 Skin Sens. 1 (H317) Environment : Aquatic Chronic 1 - H410 |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS07 GHS09 GHS08 GHS02
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Signal Word |
Danger |
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Contains |
α-pinene, β-pinene, limonene, camphene |
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Hazard Statements |
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H226Flammable liquid and vapour. H304May be fatal if swallowed and enters airways. H317May cause an allergic skin reaction. H411Very toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P280 Wear protective gloves/protective clothing/eye protection/face protection P210Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P301/P330/P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P310Immediately call a POISON CENTER or doctor/physician. P273Avoid release to the environment. P501Dispose of contents/container to regional, national regulation. |
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Supplementary Precautionary Statements |
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None |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available |
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Adverse physio-chemical properties |
No additional data available |
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Adverse effects on human health |
No additional data available |
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3.1 |
Substances |
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70-85% alpha-Pinene CAS-No.: 80-56-8 EC No.: 201-291-9
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304
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2-7% beta-Pinene Cas. No: 127-91-3EC No: 204-872-5
Classification (EC 1272/2008); Danger, Flam. Liq. 3 – H226, Skin Sens. 1 – H317 , Asp Tox. 1 – H304, Aquatic Chronic 1 – H410
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3-7% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5 Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410
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1-5% Camphene CAS-No 79-92-5, EC 201-234-8
Classification (EC 1272/2008); Flam. Sol. 1 – H228, Eye Irrit 2 – H319, Aquatic Acute 1 – H400 |
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4.1 |
Description of first aid measures |
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Inhalation |
Remove immediately from source of exposure into fresh air. Seek medical attention if any discomfort continues. |
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Ingestion |
DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Seek medical attention. |
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Skin Contact |
Remove contaminated clothing immediately and wash skin with soap and water. Seek medical attention if any discomfort continues. |
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Eye Contact |
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Seek medical attention immediately. Continue to rinse. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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Observe risk of aspiration if vomiting occurs. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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Treat symptomatically |
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5.1 |
Extinguishing Media |
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Extinguishing media: Carbon dioxide (CO2). Powder. Foam. Unsuitable extinguishing media: Full water jet. |
5.2 |
Special hazards arising from the product |
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Fires of liquids or liquid turning substances - In case of fire toxic fumes like carbon monoxide and carbon dioxide may be liberated. Burning produces heavy smoke |
5.3 |
Advice for firefighters |
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Move undamaged containers from immediate hazard area if it can be done safely. Use suitable breathing apparatus. Wear suitable equipment for self protection. |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Wear protective clothing as described in Section 8 of this safety data sheet. Handle the product using protective gloves resistant to the chemicals exposed. Avoid contact with skin, eyes and clothing. Maintain adequate ventilation in the working area after spilling. |
6.2 |
Environmental Precautions |
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Do not discharge into drains, water courses or onto the ground. Contain spillages. |
6.3 |
Methods and material for containment and cleaning up. |
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Cover with an inert, inorganic, non-combustible absorbent material (e.g dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Dispose of in accordance with current laws and regulations. |
6.4 |
Reference to other sections |
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Sections 7 and 8 |
7.1 |
Precautions for safe handling |
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Handle in accordance with good hygiene and safety practice. Provide earthing of containers, equipment, pumps and ventilation facilities. Take precautionary measures against static discharges. Wear personal protective clothing (see section 8). Do not breathe gas/fume/vapour/spray. Use only in well-ventilated areas. When using do not eat, drink, smoke, sniff. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Keep product container tightly closed, in a dry, ventilated area, away from potential sources of ignition and protected from light. |
7.3 |
Specific end use(s) |
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No additional data available. |
8.1 |
Control parameters |
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No additional data available |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Provide eyewash station. |
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Engineering Measures |
Provide adequate ventilation. |
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Respiratory Equipment |
If adequate ventilation is not provided, use respiratory equipment. |
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Hand Protection |
Wear chemical resistant gloves (PVC) according to EN374. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Take recovery periods for skin regeneration. |
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Eye Protection |
Wear approved safety goggles according to EN166. |
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Other Protection |
Wear appropriate clothing to prevent any possibility of skin contact. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. |
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Personal Protection |
Avoid contact with skin and eyes. Avoid inhalation of vapours. |
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Skin Protection |
Wear apron or protective clothing in case of splashes. |
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only eliminate by authorised companies. |
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Mobile Liquid |
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Colour |
Colourless to slight yellow |
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Odour |
Characteristic |
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Relative Density |
0.857 - 0.875 @ 20°C |
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Flash Point (°C) |
36 |
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Refractive Index |
1.465 - 1.475 @ 20°C |
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Melting Point (°C) |
No additional data available |
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Boiling Point (°C) |
No additional data available |
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Vapour Pressure |
No additional data available |
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Solubility in Water @20°C |
Insoluble in water. Soluble in Ethanol at a ratio of 1:5 |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10.1 |
Reactivity |
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Avoid contact with; strong oxidising agents, strong reducing agents, acids, bases, acid anhydride and alkali metals. |
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10.2 |
Chemical stability |
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Stable under the recommended handling and storage conditions. |
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10.3 |
Possible hazardous reactions |
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No hazardous reactions at proper usage and handling. |
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10.4 |
Conditions to Avoid |
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Temperatures more than room temperature will benefit the transfer from liquid to vapour phase and formation of explosive atmospheres. Storing the product in open containers will benefit the formation of peroxides and derogate the quality. |
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10.5 |
Incompatible materials |
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No additional data available |
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10.6 |
Hazardous Decomposition Products |
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No dangerous decomposition products known. |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
LD50 (oral) in mg/kg: > 5000 LD50 (dermal) in mg/kg: > 5000 |
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Skin corrosion / irritation |
No additional data available |
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Serious eye damage / irritation |
No additional data available |
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Respiratory or skin sensitisation |
No additional data available |
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Germ Cell Mutagenicity |
No additional data available |
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Carcinogenicity |
No additional data available |
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Reproductive toxicity |
No additional data available |
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STOT-single exposure |
No additional data available |
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STOT-repeated exposure |
No additional data available |
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Aspiration hazard |
No additional data available |
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Photo-toxicity |
No additional data available |
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Other Information |
No additional data available |
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12.1 |
Toxicity |
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No additional data available |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available |
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12.4 |
Mobility in soil |
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No additional data available |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available |
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12.6 |
Other adverse effects |
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Do not allow product to enter streams, sewers or other waterways. Water Hazard Class; WGK-2 |
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13.1 |
Waste treatment methods |
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Collect and dispose of waste product in accordance with local authority guidelines using a hazardous chemical disposal company. Product remainders should not intrude soil or waters. |
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14.1 |
UN number |
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UN No. Road |
1272 |
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UN No. SEA |
1272 |
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UN No. AIR |
1272 |
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14.2 |
UN proper shipping name |
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Pine Oil |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class; 3 Flammable Liquid ADR/RID/ADN Class: 3 Flammable Liquid IMDG Class: 3 Flammable Liquid ICAO Class/Division: 3 Flammable Liquid
Transport Labels
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant
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14.6 |
Special precautions for user |
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See sections 6-8 |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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Packed and transferred according to transport regulations. |
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H226Flammable liquid and vapour. H228 Flammable Soild H304May be fatal if swallowed and enters airways. H315 Causes skin irritation H317May cause an allergic skin reaction. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411Very toxic to aquatic life with long lasting effects. |
Other Information |
None |
Revision Date |
28/07/2015 |
Reason for revision |
New SDS |
Rev No/Repl, SDS Generated |
01 |