MSDS - Petitgrain - Citrus aurantium - Essential Oil

1.1

Product Identifier 

Product Name 

Petitgrain oil

Biological Definition

The volatile oil obtained by steam distillation of the branches, twigs and leaves of an acclimatised variety of the Bitter Orange Tree Citrus aurantium L. subsp. aurantium

INCI Name

Citrus Aurantium Amara Leaf/Twig Oil.

Synonyms & Trade Names

-

CAS-No

68916-04-1 / 72968-50-4

EC No.

277-143-2

EINECS No.

277-143-2

1.2

Relative identified uses of the substance or mixture and uses advised against

Flavour and fragrance.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements are displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards      Flam. Liq. 3 - H226

Human health                                    Skin Irrit. 2 - H315; Eye Dam. 1 - H318; Skin Sens. 1 - H317

Environment Aquatic                       Acute 2 - H401; Aquatic Chronic 2 - H411.

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

       GHS07          GHS09          GHS02          GHS05

Signal Word

Danger

Contains

Beta Pinene, Geraniol, Limonene

Hazard Statements

H226 Flammable liquid and vapour.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H401 Toxic to aquatic life.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash … thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated

clothing. Rinse skin with water/shower.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P321 Specific treatment (see … on this label).

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+378 In case of fire: Use … for extinction.

P391 Collect spillage.

P403+235 Store in a well-ventilated place. Keep cool.

P501 Dispose of contents/container to …

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

30.0 – 60.0% Linalyl Acetate CAS: 115-95-7, EINECS: 204-116-4

Classification (EC 1272/2008) Skin Irrit. 2 - H315; Eye Irrit. 2 - H319

10.0 - 30.0% Linalool CAS-No.: 78-70-6 EC No.: 201-134-4

Classification (EC 1272/2008) Acute Tox. 5 - H303, Skin Irrit. 2 - H315, Aquatic Acute 3 - H402

5.0 - 10.0% a-terpineol (p-menth-1-en-8-ol) CAS-No.: 99-55-5 EC No.: 202-680-6

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319

1.0 - 5.0% Beta-pinene CAS-No.: 127-91-3 EC No.: 204-872-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Skin Irrit. 2 - H315, Skin Sens. 1 - H317

1.0-5.0% Geraniol CAS-No.: 106-24-1 EC No.: 203-377-1

Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Dam. 1 - H318, Skin Sens. 1 - H317

1.0-5.0% Geranyl Acetate CAS-No.: 105-87-3 EC No.: 203-341-5

Classification (EC 1272/2008) Aquatic Chronic 2 - H411

1.0 – 5.0% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

1.0 – 5.0% Myrcene (7-methyl-3-methyleneocta-1,6-diene) CAS-No.: 123-35-3 EC No.:204-622-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Asp. Tox. 1 - H304

<1.0% Alpha-pinene CAS-No.: 80-56-8 EC No.: 201-291-9

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Sens. 1 - H317, Asp. Tox. 1 - H304, Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410

<1.0% Terpinolene CAS-No.: 586-62-9-5 EC No.: 209-578-0

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 - H304, Aquatic Chronic 2 - H411

4.1

Description of first aid measures

Inhalation 

Remove victim immediately from source of exposure. Get medical attention if any discomfort continues.

 Ingestion

Rinse mouth and drink abundant water to dilute substance. Avoid vomiting, risk of aspiration!

Skin Contact 

Remove contaminated clothes. Wash affected areas with copious amounts of water.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Carbon dioxide, Dry powder or Foam. Cool containers with water.

5.2 

Special hazards arising from the product

Specific hazards

When heated to decomposition, it emits acrid smoke as well as carbonmonoxide and carbondioxide.

5.3 

Advice for firefighters

In the event of fire, combustion gas or dangerous vapours may appear. Generates explosive mixtures with air. Use chemical protection clothing and self-contained breathing apparatus.

6.1 

Personal precautions, protective equipment and emergency procedures

For personal protection, see section 8.

6.2 

Environmental Precautions

Keep away from sewerage, surface water and groundwater. Do not allow to enter sewerage system.

6.3 

Methods and material for containment and cleaning up.

Absorb with inert, non-combustible, inorganic absorbant material, sweep up and remove to an approved disposal container. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.

6.4 

Reference to other sections

No additional data available.

7.1 

Precautions for safe handling

Keep away from sources of ignition. The normal safety precautions for handling chemicals should always be observed. Do not eat, drink or smoke in work areas. Immediately change contaminated clothing. Wash hands after working with substance.

7.2 

Conditions for safe storage, including any incompatibilities

Store in full tight sealed containers in a well ventilated place, away from sources of ignition and heat, at temperature below 20 ºC and protected from light.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

Ingredient Comments

No exposure limits noted for ingredient(s).  

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Ventilation, local exhaust, or breathing protection.

Hand Protection

Use suitable protective gloves if risk of skin contact.

Eye Protection

Chemical safety goggles are compulsory.

Other Protection

Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing.

Hygiene Measures

Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Good personal hygiene practices are always advisable, especially when working with chemicals.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Avoid contact with skin. Wear suitable gloves.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid

Colour

Pale yellow to yellow brown

Odour

Characteristic

Relative Density

0.882 to 0.893 @ 20⁰C

Flash Point (°C)

>66⁰C

Refractive Index

1.450 to 1.465 @ 20⁰C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

Keep away from ignition sources. Protect from light and air.

10.5 

Incompatible materials

Strong acids, alkali or oxidizers.

10.6 

Hazardous Decomposition Products

In case of fire, dangerous decomposition products can be generated, such as carbon monoxide and dioxide and nitrogen fumes and oxides.

11.1 

Information on toxicological effects 

Acute Toxicity

There is no toxicological data available on this product.

Skin corrosion / irritation

No additional data available.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

No additional data available.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

Mobile.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

This product and its packaging must be disposed according to local regulations.

This product would be burnt (always if it is according with local regulations) and it does not generate ashes.

14.1 

UN number

UN No. Road

3082

UN No. SEA

3082

UN No. AIR

3082

14.2 

UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S.

14.3 

Transport hazard class(es)

ADR/RID/ADN – Class 9

ADR/RID/ADN – Class 9

IMDG – Class 9

ICAO – Class 9

14.4 

Packing group

ADR/RID/ADN Packing group – III

IMDG Packing group – III

ICAO Packing group – III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

Emergency Action Code 3Z

Hazard No. (ADR) 90 Environmentally hazardous substance; miscellaneous dangerous substances.

Tunnel Restriction Code (E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

-

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

H401 Toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None

Revision Date

24/08/15

Reason for revision

New updated SDS format

Rev No/Repl, SDS Generated

01