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MSDS - Parsley Seed - Carum petroselinum - Essential Oil


PARSLEY SEED ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1

Product Identifier 

Product Name 

Parsley Seed Oil

Biological Definition

Carum Petroselinum Seed Oil is a volatile oil obtained from the seeds of the Parsley, Carum petroselinum L., Apiaceae.

INCI Name

Carum Petroselinum Seed Oil

Synonyms & Trade Names

Parsley Oil

CAS-No

84012-33-9 / 8000-68-8

EC No.

281-677-1 / -

EINECS No.

281-677-1 / -

1.2

Relative identified uses of the substance or mixture and uses advised against

 

No additional data available.

1.3

Details of the supplier of the safety data sheet 

 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

02. HAZARDS IDENTIFICATION

2.1

Classification of the substance or mixture 

 

The Full Text for all Hazard Statements are Displayed in Section 16.

Classification (EC 1272/2008)

 

Physical hazards

Flammable liquid Category 3

 

Health hazards

Asp. Tox. Category 1

Skin Irrit. Category 2

Skin Sens. Category 1

 

Environmental Hazards

Aquatic Acute 1

Aquatic Chronic 1

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

 

 

 

 

 

 

 

       GHS02          GHS08               GHS07        GHS09

           

 

Signal Word

Danger

Contains

Limonene, beta-Pinene, alpha-Guaiene       

Hazard Statements

 

H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways.                                  

H315: Causes skin irritation.                                 

H317: May cause an allergic skin reaction.                                

H319: Causes serious eye irritation.                                

H410: Very toxic to aquatic life with long lasting effects                                 

Precautionary Statements

 

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.   P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. 

P331: Do NOT induce vomiting. 

P280: Wear protective gloves/protective clothing/eye protection/face protection. 

P501: Dispose of contents in accordance with local, state or national legislation. 

P261: Avoid breathing dust/fume/gas/mist/vapours/spray. 

P333+P313: If skin irritation or rash occurs: Get medical advice/attention. 

P362+P364: Take off contaminated clothing. And wash it before reuse. 

P302+P352: IF ON SKIN: Wash with plenty of water. 

P273: Avoid release to the environment. 

P391: Collect spillage. 

Supplementary Precautionary Statements

 

P264: Wash hands and exposed skin thoroughly after handling.

P332+P313: If skin irritation occurs: Get medical advice/attention.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available

Adverse physio-chemical properties

No additional data available

Adverse effects on human health

No additional data available

03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2

Mixtures

 

<36% Limonene   CAS No: 5989-27-5  EC No: 227-813-5

 

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Asp Tox. 1 – H304, Skin Irrit 2 – H315,  Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

 

 

2.0 – 5.0 % beta-Pinene     CAS No: 127-91-3  EC No: 204-872-5

 

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Asp. Tox. 1 – H304, Skin Irrit. 2 – H315, Skin Sens. 1 – H317, Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410         

 

 

2.0 – 5.0% alpha-Guaiene   CAS No: 3691-12-1 EC No: -

 

Classification (EC 1272/2008) Asp. Tox. 1 – H304, Skin Irrit. 2 – H315, Eye Irrit. 2 – H319

 

 

<1.0% Myrcene      CAS-NO: 123-35-3    EC No: 204-622-5

 

Classification (EC 1272/2008)  Flam. Liq. 3 – H226, Asp. Tox. 1 – H304, Skin Irrit. 2 – H315, Eye Irrit. 2 – H319

 

 

<1.0% alpha-Pinene CAS-No: 80-56-8 EC No: 201-291-9

 

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Asp. Tox. 1 – H304, Skin Irrit. 2 – H315, Skin Sens. 1 – H317

 

 

04. FIRST AID MEASURES

4.1

Description of first aid measures

Inhalation 

If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop or persist.

 Ingestion

Call a physician or poison control centre immediately. If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs.

Skin Contact 

Take off immediately all contaminated clothing. Get medical attention if irritation develops and persists. Wash skin thoroughly with soap and water for several minutes.

Eye Contact   

Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Promptly wash eyes with plenty of water while lifting the eye lids.

4.2

Most important symptoms and effects, both acute and delayed

 

Dermatitis. Rash. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction.

4.3

Indication of any immediate medical attention and special treatment needed

 

No additional data available.

 

05. FIRE-FIGHTING MEASURES

5.1 

Extinguishing Media

 

Suitable extinguishing media: Water spray, fog, CO2, dry chemical, or alcohol resistant foam.

Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.

5.2 

Special hazards arising from the product

 

Fire may produce irritating, corrosive and/or toxic gases.

5.3 

Advice for firefighters

 

Firefighters must use standard protective equipment including flame retardant coat, helmet with

face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective

clothing will only provide limited protection. Wear self-contained breathing apparatus with a full

facepiece operated in the positive pressure demand mode when fighting fires.

06. ACCIDENTAL RELEASE MEASURES

6.1 

Personal precautions, protective equipment and emergency procedures

 

Keep unnecessary personnel away. Do not touch damaged containers or spilled material unless

wearing appropriate protective clothing. Ventilate closed spaces before entering them. Eliminate

all sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapour.

6.2 

Environmental Precautions

 

Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic

environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Retain

and dispose of contaminated wash water.

6.3 

Methods and material for containment and cleaning up.

 

Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Allow gas to dissipate into the atmosphere. Block any potential routes to water systems. Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Do not allow material to contaminate ground water system. Absorb in vermiculite, dry sand or earth and place into containers.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills in original containers for re-use. This material and its container must be disposed of as hazardous waste.

6.4 

Reference to other sections

 

See protective measures under point 7 and 8.

07. HANDLING AND STORAGE

7.1 

Precautions for safe handling

 

Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary

measures against static discharges. All equipment used when handling the product must be

grounded. Avoid breathing vapour. Avoid contact with eyes, skin, and clothing. Avoid prolonged

exposure. Wash thoroughly after handling.

7.2 

Conditions for safe storage, including any incompatibilities

 

Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area.

 

7.3 

Specific end use(s) 

 

No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 

Control parameters 

 

No exposure limits noted for ingredient(s).

8.2 

Exposure controls 

Protective Equipment

 

 

Process Conditions 

Technical measures and the application of suitable work processes have priority over personal protection equipment.

Engineering Measures

Use explosion-proof ventilation equipment to stay below exposure limits.

Respiratory Equipment

Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection must be provided.

Hand Protection

Use solvent and acid resistant protection gloves according to EN 374.

The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances.

Take recovery periods for skin regeneration.

Eye Protection

Use protection goggles according to EN166.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Protective work clothing solvent resistant (should be checked regularly).

Environmental Exposure Controls 

Avoid discharging into drainage water. Only remove via authorised companies.

09. PHYSICAL AND CHEMICAL PROPERTIES

9.1 

Information on basic physical and chemical properties 

Appearance

liquid

Colour

Dark yellow to amber brown

Odour

Characteristic

Relative Density

0.890  - 0.935 @ 20⁰C

Flash Point (°C)

47.8 °C Closed Cup

Refractive Index

1.466  -  1.510  @ 20⁰C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

 

No additional data available.

10. STABILITY AND REACTIVITY

10.1 

Reactivity

 

The product is stable and non-reactive under normal conditions of use, storage and transport.

10.2 

Chemical stability

 

Material is stable under normal conditions.

10.3 

Possible hazardous reactions

 

No dangerous reactions expected if used according to specifications.

10.4 

Conditions to Avoid

 

Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the

flash point. Contact with incompatible materials.

10.5 

Incompatible materials

 

Strong oxidizing agents.

10.6 

Hazardous Decomposition Products

 

No dangerous decomposition products known.

11. TOXOLOGICAL INFORMATION

11.1 

Information on toxicological effects 

 

Acute Toxicity

No additional data available.

 

Skin corrosion / irritation

Causes skin irritation

 

Serious eye damage / irritation

Causes serious eye irritation

 

Respiratory or skin sensitisation

May cause an allergic skin reaction.                                

 

Germ Cell Mutagenicity

No additional data available.

 

Carcinogenicity

No additional data available

 

Reproductive toxicity

No additional data available.

 

STOT-single exposure

No additional data available

 

STOT-repeated exposure

No additional data available

 

Aspiration hazard

May be fatal if swallowed and enters airways

 

Photo-toxicity

No additional data available

 

Other Information

No additional data available

12. ECOLOGICAL INFORMATION

12.1 

Toxicity

 

Very toxic to aquatic life with long lasting effects                                 

12.2 

Persistence & degradability

 

No additional data available

12.3 

Bioaccumulation Potential

 

No additional data available

12.4 

Mobility in soil

 

No additional data available.

12.5 

Results of PBT and vPvB Assessment

 

No additional data available

12.6 

Other adverse effects

 

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. DISPOSAL CONSIDERATIONS

13.1 

Waste treatment  methods

 

Disposal instructions

Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

 

Local disposal regulations

Dispose in accordance with all applicable regulations.

 

Hazardous waste code

Not established.

 

Waste from residues / unused products

Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

 

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling or disposal, since emptied containers may retain product residue, follow label warnings even after container is emptied.

14. TRANSPORT INFORMATION

14.1 

UN number

 

UN No. Road

1169

 

UN No. SEA

1169

 

UN No. AIR

1169

14.2 

UN proper shipping name

 

Extracts, Aromatic, Liquid.

14.3 

Transport hazard class(es)

 

ADR/RID/ADN Class:3

ADR/RID/ADN Class:3

IMDG Class 3

ICAO Class/Division

 

Transport Labels

 

 

 

Tunnel restriction code D/E

14.4 

Packing group

 

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

 

Environmentally Hazardous Substance/Marine Pollutant

 

 

14.6 

Special precautions for user

 

See section 6 to 8.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

 

Packed and transferred according to transport regulations.

15. REGULATORY INFORMATION

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

 

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

 

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

 

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

 

No additional information available.

16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full

H226                                   Flammable liquid and vapour.

H304                                   May be fatal if swallowed and enters airways.

H315                                   Causes skin irritation.

H317                                   May cause an allergic skin reaction.

H319                                   Causes serious eye irritation.

H400                                   Very toxic to aquatic life.

H410                                   Very toxic to aquatic life with long lasting effects.

H411                                   Toxic to aquatic life with long lasting effects.

Other Information

None

Revision Date

31/07/15

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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Keywords: Essential Oil, MSDS, Aromatherapy, Parsley Seed, Carum petroselinum