MSDS - Orange Sweet - Citrus sinensis - Essential Oil

1.1

Product Identifier 

Product Name 

Orange Oil Sweet

Biological Definition

Citrus Aurantium Dulcis Peel Oil Expressed is an essential oil expressed from the fresh epicarps of the Sweet Orange, Citrus aurantium L. var. dulcis L. (syn: Citrus sinensis), Rutaceae.

INCI Name

Citrus Aurantium Dulcis Peel Oil Expressed

Synonyms & Trade Names

-

CAS-No

8028-48-6

EC No.

232-433-8

EINECS No.

232-433-8

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The full text for all hazard statements are displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards Flam. Liq. 3 - H226

Human health Skin Irrit. 2 - H315; Skin Sens. 1 - H317; Asp. Tox. 1 - H304

Environment Aquatic Chronic 1 - H410

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

     GHS07            GHS02          GHS08   GHS09

Signal Word

Danger

Contains

Alpha pinene natural, a-terpineol (p-menth-1-en-8-ol), CITRAL, Citronellal, Decanal, d-LIMONENE, Linalool, Myrcene (7-methyl-3-methyleneocta-1,6-diene), Octanal

Hazard Statements

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P262 Do not get in the eyes, on skin, or on clothing.

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

Supplementary Precautionary Statements

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash … thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P321 Specific treatment (see … on this label).

P331 Do NOT induce vomiting.

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P370+378 In case of fire: Use … for extinction.

P391 Collect spillage.

P403+235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/container to …

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.1

Substances

≤ 97.0% D-Limonene CAS-No: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008):  Flam. Liq. 3 - H226, Skin Irrit. 2 - H315,  Skin Sens. 1 - H317

            Asp. Tox. 1 - H304,  Aquatic Acute 1 - H400,  Aquatic Chronic 1 - H410

1.0 – 5.0% α-Pinene NaturalCAS-No: 80-56-8  EC No.: 201-291-9

Classification (EC 1272/2008): Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317,
Asp. Tox. 1 - H304

1.0   – 5.0% a-Terpineol (p-menth-1-en-8-ol)  CAS-No: 98-55-5  EC No.: 202-680-6

Classification (EC 1272/2008):  Skin Irrit. 2 - H315, Eye Irrit. 2 - H319

1.0 – 5.0% Citral  CAS-No: 5392-40-5 EC No.: 226-394-6

Classification (EC 1272/2008):  Skin Irrit. 2 - H315, Eye Irrit. 2 - H319,  Skin Sens. 1 - H317

1.0 – 5.0% Citronellal  CAS-No: 106-23-0  EC No.: 203-376-6

Classification (EC 1272/2008):  Skin Irrit. 2 - H315,  Skin Sens. 1 - H317,  Aquatic Chronic 2 - H411

1.0 – 5.0% Decanal CAS-No: 112-31-2  EC No.: 203-957-4

Classification (EC 1272/2008):  Skin Irrit. 2 - H315,  Aquatic Chronic 3 - H412

1.0   – 5.0  Linalool  CAS-No: 78-70-6  EC No.: 201-134-4

  Classification (EC 1272/2008): Skin Irrit. 2 - H315

1.0 – 5.0 %  Myrcene (7-methyl-3-methyleneocta-1,6-diene) CAS-No: 123-35-3EC No.: 204-622-5

  Classification (EC 1272/2008): Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Eye Irrit. 2 - H319 Asp. Tox. 1 - H304

1.0   – 5.0 %  Octanal  CAS-No: 124-13-0 EC No.: 204-683-8

  Classification (EC 1272/2008): Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Eye Irrit. 2 - H319Aquatic Chronic 3 -  H412

4.1

Description of first aid measures

Inhalation 

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air at once. Seek medical attention.

 Ingestion

Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING!

Skin Contact 

Remove contaminated clothing immediately and wash skin with soap and water. Seek medical attention f irritation or symptoms persist.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Seek medical attention. Continue to rinse.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Extinguishing media: Carbon dioxide (CO2). Foam.

Unsuitable extinguishing media: Water.

5.2 

Special hazards arising from the product

When heated to decomposition, it emits acrid smoke as well as carbon monoxide and carbon dioxide.

5.3 

Advice for firefighters

Special Fire Fighting Procedures

Water is unsuitable to use as an extinguishing method.

Protective equipment for fire-fighters

Wear suitable respiratory equipment when necessary.

6.1 

Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Wear protective clothing as described in Section 8 of this safety data sheet.

6.2 

Environmental Precautions

Avoid discharge into drains, water courses or onto the ground. Prevent further spillage if safe.

6.3 

Methods and material for containment and cleaning up.

Absorb spillage with non-combustible, absorbent material. For waste disposal, see section 13.

6.4 

Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet.

7.1 

Precautions for safe handling

Avoid spilling, skin and eye contact. Ensure adequate ventilation of the working area. Adopt best manual handling considerations when handling, carrying and dispensing. Keep away from heat, sparks and open flame.

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional data available.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

No additional data available.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Self-contained breathing apparatus.

Hand Protection

Chemical resistant gloves (PVC).

Eye Protection

Wear approved chemical safety goggles where eye exposure is reasonably probable.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. Wash hands at the end of each work shift and before eating, smoking and using the toilet.

Personal Protection 

Avoid contact with skin and eyes. Avoid inhalation of vapours.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Mobile Liquid, orange to orange-red.

Colour

orange to orange red.

Odour

Characteristic

Relative Density

0.838 - 0.850 @ 20°C

Flash Point (°C)

48

Refractive Index

1.468  - 1.480 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

176  -  180

Vapour Pressure

No additional data available.

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

Hazardous Polymerisation

Unknown.

10.4 

Conditions to Avoid

Avoid heat, sparks ad open flame.

10.5 

Incompatible materials

Avoid strong acids, alkalis and oxidising agents.

10.6 

Hazardous Decomposition Products

No additional data available.

11.1 

Information on toxicological effects 

Acute Toxicity

Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.

Skin corrosion / irritation

May cause sensitisation by skin contact.

Serious eye damage / irritation

Spray and vapour in the eyes may cause irritation and smarting.

Respiratory or skin sensitisation

In high concentrations, vapours may irritate throat and respiratory system and cause coughing.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Dispose of in compliance with all local and national regulations.

14.1 

UN number

UN No. Road

1993

UN No. SEA

1993

UN No. AIR

1993

14.2 

UN proper shipping name

FLAMMABLE LIQUID , N.O.S (Terpene Hydrocarbons).

14.3 

Transport hazard class(es)

ADR/RID/ADN Class: 3 (Flammable Liquid)

IMDG Class: 3 (Flammable Liquid)

ICAO Class/Division: 3 (Flammable Liquid)

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

EMS  F-E-S-D

Hazard No. (ADR) 30 Flammable liquid (flash-point between 23°C and 60°C, inclusive) or flammable                             liquid or solid in the molten state with a flash-point above 60°C, heated to a                                                         temperature equal to or above its flash-point, or self heating liquid.

Tunnel Restriction Code  (D/E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

Packed and transferred according to transport regulations.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H412 Harmful to aquatic life with long lasting effects.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None

Revision Date

14/07/2016

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01