1.1 |
Product Identifier |
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Product Name |
Melissa Oil Pure. |
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Biological Definition |
Melissa Officinalis Leaf Oil is a volatile oil obtained from the leaves and tops of the Balmmintoil, Melissa officinalis L., Labiatae. |
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INCI Name |
Melissa Officinalis Leaf oil |
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Synonyms & Trade Names |
- |
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CAS-No |
84082-61-1 / 8014-71-9 |
EC No. |
282-007-0 |
EINECS No. |
282-007-0 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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No additional data available. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements are Displayed in Section 16. |
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Classification (EC 1272/2008) |
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Skin irritation, Category 2 (Skin Irrit. 2, H315). Serious eye damage, Category 1 (Eye Dam. 1, H318). Skin sensitisation, Category 1 (Skin Sens. 1, H317). Hazardous to the aquatic environment - Chronic hazard, Category 2 (Aquatic Chronic 2, H411). This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site. |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS09 GHS07 GHS05
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Signal Word |
Danger |
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Contains |
EC 203-376-6 CITRONELLAL EC 203-377-1 GERANIOL EC 203-375-0 CITRONELLOL 605-019-00-3 CITRAL EC 225-004-1 FARNESOL EC 201-291-9 ALPHA-PINENE X 601-029-00-7 (R)-P-MENTHA-1,8-DIENE |
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Hazard Statements |
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H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. |
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Supplementary Precautionary Statements |
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P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
The substance does not satisfy the PBT or vPvP criteria in accordance with annexe XIII of the REACH regulations EC 1907/2006. |
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Adverse physio-chemical properties |
The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European Chemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table |
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Adverse effects on human health |
No additional data available |
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3.2 |
Mixtures |
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25.0-50.0% CITRONELLAL CAS: 106-23-0, EC: 203-376-6
Classification (EC 1272/2008) Warning Eye Irrit. 2, H319, Aquatic Chronic 2, H411, Skin Irrit. 2, H315, Skin Sens. 1, H317
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10.0 – 25.0% GERANIOL CAS: 106-24-1, EC: 203-377-1
Classification (EC 1272/2008) Danger Eye Dam. 1, H318, Skin Irrit. 2, H315, Skin Sens. 1, H317
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10.0 – 25.0% CITRONELLOL CAS: 106-22-9 EC: 203-375-0
Classification (EC 1272/2008) Warning, Eye Irrit. 2, H319, Skin Irrit. 2, H315, Skin Sens. 1, H317
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2.50 - 10.0% CITRAL CAS: 5392-40-5 EC: 226-394-6
Classification (EC 1272/2008) Warning, Skin Irrit. 2, H315, Skin Sens. 1, H317
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2.50 - 10.0% CITRONELLYL ACETATE CAS: 150-84-5, EC: 205-775-0
Classification (EC 1272/2008) Warning, Eye Irrit. 2, H319, Aquatic Chronic 2, H411, Skin Irrit. 2, H315
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0.00 – 2.50% FARNESOL CAS: 4602-84-0, EC: 225-004-1
Classification (EC 1272/2008) Warning, Eye Irrit. 2, H319, Skin Irrit. 2, H315, Skin Sens. 1, H317 |
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0.00 – 2.50% GERANYL ACETATE CAS: 105-87-3, EC: 203-341-5
Classification (EC 1272/2008) Aquatic Chronic 2, H411
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0.00 – 2.50% ISOPULEGOL CAS: 89-79-2, EC: 201-940-6
Classification (EC 1272/2008) Warning , Acute Tox. 4, H302
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0.00 – 2.50% LINALOOL CAS: 78-70-6, EC: 201-134-4
Classification (EC 1272/2008) Warning , Eye Irrit. 2, H319, Skin Irrit. 2, H315.
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0.00 - 2.50% MENTHONE CAS: 10458-14-7, EC: 233-944-9
Classification (EC 1272/2008) Aquatic Chronic 3, H412
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0.00 - 2.50% ALPHA-PINENE X CAS: 80-56-8, EC: 201-291-9
Classification (EC 1272/2008) Danger, Asp. Tox. 1, H304, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317 |
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0.00 - 2.50% (R)-P-MENTHA-1,8-DIENE CAS: 5989-27-5, EC: 227-813-5
Classification (EC 1272/2008) Warning, Flam. Liq. 3, H226, Skin Irrit. 2, H315, Skin Sens. 1, H317, Aquatic Acute 1, H400, M Acute = 1, Aquatic Chronic 1, H410, M Chronic = 1
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4.1 |
Description of first aid measures |
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Inhalation |
Remove victim immediately from source of exposure. Get medical attention if any discomfort continues. |
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Ingestion |
Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor. Seek medical attention immediately, showing the label. |
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Skin Contact |
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. Watch out for any remaining product between skin and clothing, watches, shoes, etc. In the event of an allergic reaction, seek medical attention. If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital. |
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Eye Contact |
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open. Regardless of the initial state, refer the patient to an ophthalmologist and show him the label. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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No additional data available |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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No additional data available |
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5.1 |
Extinguishing Media |
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Non flammable. |
5.2 |
Special hazards arising from the product |
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A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not breathe in smoke. In the event of a fire, the following may be formed: - carbon monoxide (CO) - carbon dioxide (CO2) |
5.3 |
Advice for firefighters |
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No additional data available. |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Consult the safety measures listed under headings 7 and 8.
For non first aid worker Avoid any contact with the skin and eyes.
For first aid worker First aid workers will be equipped with suitable personal protective equipment (See section 8). |
6.2 |
Environmental Precautions |
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Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal. Prevent any material from entering drains or waterways. |
6.3 |
Methods and material for containment and cleaning up. |
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Clean preferably with a detergent, do not use solvents. |
6.4 |
Reference to other sections |
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No additional data available. |
7.1 |
Precautions for safe handling |
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Requirements relating to storage premises apply to all facilities where the mixture is handled. Individuals with a history of skin sensitisation should not, under any circumstance, handle this mixture. Always wash hands after handling. Remove and wash contaminated clothing before re-using. Emergency showers and eye wash stations will be required in facilities where the mixture is handled constantly. Fire prevention: Prevent access by unauthorised personnel. Recommended equipment and procedures: For personal protection, see section 8. Observe precautions stated on label and also industrial safety regulations. Avoid eye contact with this mixture at all times. Prohibited equipment and procedures: No smoking, eating or drinking in areas where the mixture is used. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Packaging Always keep in packaging made of an identical material to the original. |
7.3 |
Specific end use(s) |
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No additional data available. |
8.1 |
Control parameters |
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Occupational exposure limits : - ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) : CAS TWA: STEL: Ceiling: Definition: Criteria: 80-56-8 20ppm - - - - |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Provide eyewash station. |
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Engineering Measures |
Provide adequate ventilation. |
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Respiratory Equipment |
For high concentrations use respiratory equipment. |
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Hand Protection |
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must be selected according to the application and duration of use at the workstation. Protective gloves need to be selected according to their suitability for the workstation in question: other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required. Recommended properties : - Impervious gloves in accordance with standard EN374 |
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Eye Protection |
Avoid contact with eyes. Use eye protectors designed to protect against liquid splashes Before handling, wear safety goggles with protective side’s in accordance with standard EN166. In the event of high danger, protect the face with a face shield. Prescription glasses are not considered as protection. Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours. Provide eyewash stations in facilities where the product is handled constantly. |
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Other Protection |
Use personal protective equipment that is clean and has been properly maintained. Store personal protective equipment in a clean place, away from the work area. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas. |
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Personal Protection |
Use personal protection according to Directive 89/686/EEC. |
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Skin Protection |
Avoid skin contact. Wear suitable protective clothing. Suitable type of protective clothing: In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact. In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact. Work clothing worn by personnel shall be laundered regularly. After contact with the product, all parts of the body that have been soiled must be washed.
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only eliminate by authorised companies. |
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Clear liquid |
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Colour |
Pale yellow to brown/yellow |
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Odour |
Characteristic – rose and lemon notes |
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Relative Density |
0.879 - 0.893 @ 20°C |
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Flash Point (°C) |
73°C |
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Refractive Index |
1.457 - 1.477 @ 20°C |
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Melting Point (°C) |
No additional data available. |
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Boiling Point (°C) |
No additional data available. |
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Vapour Pressure |
No additional data available. |
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Solubility in Water @20°C |
Insoluble in water. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10.1 |
Reactivity |
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No additional data available. |
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10.2 |
Chemical stability |
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This mixture is stable under the recommended handling and storage conditions in section 7. |
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10.3 |
Possible hazardous reactions |
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No additional data available. |
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10.4 |
Conditions to Avoid |
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No additional data available. |
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10.5 |
Incompatible materials |
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No additional data available. |
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10.6 |
Hazardous Decomposition Products |
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The thermal decomposition may release/form: - carbon monoxide (CO) - carbon dioxide (CO2) |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
ALPHA-PINENE X (CAS: 80-56-8) Oral route : LD50 = 3700 mg/kg MENTHONE (CAS: 10458-14-7) Oral route : LD50 = 2500 mg/kg LINALOOL (CAS: 78-70-6) Oral route : LD50 = 3000 mg/kg ISOPULEGOL (CAS: 89-79-2) Oral route : LD50 = 960 mg/kg CITRONELLOL (CAS: 106-22-9) Oral route : LD50 = 2650 mg/kg Dermal route : LD50 = 2650 mg/kg GERANIOL (CAS: 106-24-1) Oral route : LD50 = 4200 mg/kg CITRONELLAL (CAS: 106-23-0) Oral route : LD50 = 2500 mg/kg |
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Skin corrosion / irritation |
May cause an allergic reaction by skin contact |
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Serious eye damage / irritation |
May have irreversible effects on the eyes, such as tissue damage in the eye, or serious physical decay of sight, which is not fully reversible by the end of observation at 21 days. Serious eye damage is typified by the destruction of cornea, persistent corneal opacity and iritis. |
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Respiratory or skin sensitisation |
May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
CAS 5989-27-5 : IARC Group 3 : The agent is not classifiable as to its carcinogenicity to humans. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
No additional data available. |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12.1 |
Toxicity |
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Toxic to aquatic life with long lasting effects. The product must not be allowed to run into drains or waterways. No aquatic toxicity data available for the mixture. |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available. |
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12.6 |
Other adverse effects |
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No additional data available. |
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13.1 |
Waste treatment methods |
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Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC. Do not pour into drains or waterways. Waste: Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals. Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company. Do not contaminate the ground or water with waste. Do not dispose of waste into the environment. Soiled packaging: Empty container completely. Keep label(s) on container. Give to a certified disposal contractor. |
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14.1 |
UN number |
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UN No. Road |
3082 |
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UN No. SEA |
3082 |
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UN No. AIR |
3082 |
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14.2 |
UN proper shipping name |
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ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Citronellal) |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class 9 IMDG Class 9 ICAO Class/Division 9
Transport Labels
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant
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14.6 |
Special precautions for user |
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ADR/RID Class Code Pack gr. Label Ident. LQ Provis. EQ Cat. Tunnel 9 M6 III 9 90 5 L 274 335 601 E1 3 E
IMDG Class 2°Label Pack gr. LQ EMS Provis. EQ 9 - III 5 L F-A,S-F 274 335 E1
IATA Class 2°Label Pack gr. Passager Passager Cargo Cargo note EQ 9 - III 964 450 L 964 450 L A97, A158, E1 9 - III Y964 30 kg G - - A97 A158, E1
For limited quantities, see part 2.7 of the OACI/IATA and chapter 3.4 of the ADR and IMDG.
For excepted quantities, see part 2.6 of the OACI/IATA and chapter 3.5 of the ADR and IMDG. |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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No additional data available |
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. |
Other Information |
None |
Revision Date |
26/10/2016 |
Reason for revision |
New SDS |
Rev No/Repl, SDS Generated |
01 |