1.1 |
Product Identifier |
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Product Name |
Litsea Cubeba Oil |
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Biological Definition |
Litsea Cubeba Fruit Oil is the volatile oil obtained from the berries of the Litsea cubeba, Lauraceae |
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INCI Name |
Litsea Cubeba Fruit Oil |
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Synonyms & Trade Names |
Litsea Cubeba ext. May Chang Oil |
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CAS-No |
68855-99-2 / 90063-59-5 |
EC No. |
290-018-7 |
EINECS No. |
290-018-7 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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Industrial use only. Only for professional use. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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The full text for all hazard statements is displayed in section 16.
Human health May be fatal if swallowed and enters airways. The product is irritating to eyes and skin.
Environment The product contains a substance which is toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment. Hydrocarbon Content 19% |
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Classification (EC 1272/2008) |
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Physical and Chemical Hazards: Not classified. Human health: Skin Irrit. 2 - H315; Eye Irrit. 2 - H319; Skin Sens. 1 - H317; Asp. Tox. 1 - H304 Environment: Aquatic Chronic 2 - H411 |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS08 GHS07 GHS09
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Signal Word |
Danger |
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Contains |
Geranial, Neral, (S)-p-mentha-1,8-diene, (+)-Citronellal, Sabinene, 1, 8 cineole, 1,alpha-(-)-Pinene, Geraniol, Nerol, ß-(+)-Citronellol |
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Hazard Statements |
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H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 Do NOT induce vomiting. |
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Supplementary Precautionary Statements |
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P261 Avoid breathing vapour/spray. P264 Wash contaminated skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with national regulations. |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available. |
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Adverse physio-chemical properties |
No additional data available. |
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Adverse effects on human health |
No additional data available. |
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3.2 |
Mixtures |
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24.84 - 43.0% Geranial CAS-No: 141-27-5 EC No: 205-476-5
Classification (EC 1272/2008);Skin Irrit. 2 - H315, Skin Sens. 1 - H317
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20.24 - 35.0% Neral CAS-No: 106-26-3 EC No: 203-379-2
Classification (EC 1272/2008);Skin Irrit. 2 - H315, Skin Sens. 1 - H317
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2.3 - 18.0% (S)-p-mentha-1,8-dieneCAS-No: 5989-54-8 EC No: 227-815-6
Classification (EC 1272/2008);M factor (Acute) = 1, M factor (Chronic) = 1 Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317 Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410
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0.01 - 7.0% (+)-Citronellal CAS-No: 2385-77-5 EC No: 219-194-5
Classification (EC 1272/2008); Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Skin Sens. 1B - H317
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0.2 - 2.0% Sabinene CAS-No: 3387-41-5EC No: 222-212-4
Classification (EC 1272/2008);M factor (Acute) = 1 Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Eye Irrit. 2 - H319 Skin Sens. 1 - H317, STOT SE 3 - H335, Aquatic Acute 1 - H400
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0.74 - 1.8% 7-methyl-3-methyleneocta-1,6-dieneCAS-No: 123-35-3EC No: 204-622-5
Classification (EC 1272/2008);Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Eye Irrit. 2 - H319 Asp. Tox. 1 - H304
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0.01 - 2.2% Verbenol CAS-No: 473-67-6EC No: 207-470-8
Classification (EC 1272/2008);Skin Irrit. 2 - H315
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0.31 - 1.7% 1, 8 cineole CAS-No:470-82-6EC No: 207-431-5
Classification (EC 1272/2008);Flam. Liq. 3 - H226, Skin Sens. 1B - H317
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1.0 - 5.0% 1,alpha-(-)-Pinene CAS-No:7785-26-4EC No: 232-077-3
Classification (EC 1272/2008);M factor (Chronic) = 1 Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Eye Irrit. 2 - H319 Skin Sens. 1 - H317, STOT SE 3 - H335, Aquatic Chronic 1 - H410
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0.01 - 2.9% Geraniol CAS-No:106-24-1EC No: 203-377-1
Classification (EC 1272/2008);Skin Irrit. 2 - H315, Eye Dam. 1 - H318, Skin Sens. 1 - H317
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0.01- 5.0% 6-Methyl-5-hepten-2-one CAS-No:110-93-0EC No: 203-816-7
Classification (EC 1272/2008);Flam. Liq. 3 - H226
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0.01 - 3.3% Linalool CAS-No:126-91-0EC No: 204-811-2
Classification (EC 1272/2008);Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, STOT SE 3 - H335
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0.01 - 3.0% Beta Caryophyllene CAS-No: 87-44-5 EC No: 201-746-1
Classification (EC 1272/2008);Asp. Tox. 1 - H304
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0.18 - 1.2% Nerol CAS-No: 106-25-2 EC No: 203-378-7
Classification (EC 1272/2008);Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Skin Sens. 1 - H317
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0.01 - 1.5% ß-(+)-CitronellolCAS-No: 1117-61-9 EC No: 214-250-5
Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Skin Sens. 1B - H317
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4.1 |
Description of first aid measures |
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Inhalation |
Move affected person to fresh air at once. Get medical attention if any discomfort continues.
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Ingestion |
Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attention immediately.
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Skin Contact |
Remove contaminated clothing immediately and wash skin with soap and water.
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Eye Contact |
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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No additional data available. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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Treat symptomatically. |
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5.1 |
Extinguishing Media |
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Extinguishing media: Use as appropriate: Carbon dioxide (CO2), Foam, dry chemical powder.
Unsuitable extinguishing media: Do not use water, if avoidable.
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5.2 |
Special hazards arising from the product |
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In case of fire, the following can be released: carbon monoxide (CO), carbon dioxide (CO2), smoke, soot.
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5.3 |
Advice for firefighters |
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Special Fire Fighting Procedures Avoid breathing fire gases or vapours. Containers close to fire should be removed or cooled with water. Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Ensure adequate ventilation of the working area, evacuate personnel to safe area, wear suitable protective equipment. No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with skin and eyes. Avoid inhalation of vapours. |
6.2 |
Environmental Precautions |
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Do not discharge into drains, water courses or onto the ground. |
6.3 |
Methods and material for containment and cleaning up. |
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Cover with inert, inorganic, non-combustible material (e.g. dry-lime, sand, soda ash). Place in covered containers and dispose of in accordance with local authority guidelines. |
6.4 |
Reference to other sections |
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For waste disposal, see Section 13. |
7.1 |
Precautions for safe handling |
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Avoid contact with skin and eyes. Do not breathe vapours. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only in well ventilated areas. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Store in tightly-closed, original container in a dry, cool and well-ventilated place. |
7.3 |
Specific end use(s) |
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No additional data available. |
8.1 |
Control parameters |
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7-methyl-3-methyleneocta-1,6-diene (CAS: 123-35-3) DNEL Workers - Dermal; Long term systemic effects: 0.83 mg/kg Workers - Inhalation; Long term systemic effects: 5.83 mg/m³ General population - Dermal; Long term systemic effects: 0.42 mg/kg General population - Inhalation; Long term systemic effects: 1.25 mg/m³ PNEC - STP; 0.2 mg/l - Soil; 1.015 mg/kg - Fresh water; 0.00028 mg/l - Marine water; 0.0008 mg/l - Sediment (Freshwater); 5.022 mg/kg - Sediment (Marine water); 0.502 mg/kg
1, 8 cineole (CAS: 470-82-6) DNEL Workers - Dermal; Long term systemic effects: 2 mg/kg General population - Oral; Long term systemic effects: 600 mg/kg General population - Dermal; Long term systemic effects: 1 mg/kg General population - Inhalation; Long term systemic effects: 1.74 mg/m³ PNEC - STP; 10 mg/l - Soil; 0.2 mg/kg - Intermittent release; 0.57 mg/l - Fresh water; 0.057 mg/l - Marine water; 0.0057 mg/l - Sediment (Freshwater); 0.06732 mg/kg - Sediment (Marine water); 0.00673 mg/kg
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Provide eyewash station. |
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Engineering Measures |
Provide adequate ventilation. |
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Respiratory Equipment |
Generally unnecessary in a well ventilated area. If ventilation is insufficient, respiratory protection must be worn. |
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Hand Protection |
To protect hands from chemicals, gloves should comply with European Standard EN374. |
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Eye Protection |
Personal protective equipment for eye and face protection should comply with European Standard EN166. |
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Other Protection |
Wear appropriate clothing to prevent any possibility of skin contact. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. |
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Personal Protection |
No additional data available. |
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Skin Protection |
Wear apron or protective clothing in case of splashes. |
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Environmental Exposure Controls |
Avoid discharging into drainage water. |
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Mobile Liquid, pale yellow to yellow. |
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Colour |
Pale yellow to yellow. |
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Odour |
Characteristic. |
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Relative Density |
0.882 - 0.905 @ 25°C |
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Flash Point (°C) |
REACH dossier information. 68.3±1°c°C CC (Closed cup). |
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Refractive Index |
1.475 - 1.490 @ 20°C |
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Melting Point (°C) |
REACH dossier information. Litsea Cubeba Oil is a mobile liquid at 20°c and a mobile liquid after 2 days at -20°c. Therefore, it was concluded that the melting point of Litsea Cubeba Oil is <-20°c. |
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Boiling Point (°C) |
REACH dossier information. 83 ± 10°c°C @ 1013 hPa |
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Vapour Pressure |
REACH dossier information. 60.69 Pa @ 25°C |
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Solubility in Water @20°C |
REACH dossier information. The range of water solubilities of the known constituents of Litsea Cubeba oil was found to be 0.5 - 4364 mg/l at 25°c |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10.1 |
Reactivity |
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No hazardous reactions if stored and handled as prescribed / indicated. |
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10.2 |
Chemical stability |
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Stable under normal conditions. |
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10.3 |
Possible hazardous reactions |
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None known. |
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10.4 |
Conditions to Avoid |
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Keep away from heat, sparks and open flame. |
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10.5 |
Incompatible materials |
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Strong acids. Strong alkalis. Strong oxidising agents. |
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10.6 |
Hazardous Decomposition Products |
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Prolonged or excessive heat and/or exposure to air may cause decomposition or oxidation of the material. |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
No additional data available. |
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Skin corrosion / irritation |
No additional data available. |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
No additional data available. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
No additional data available. |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12.1 |
Toxicity |
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Acute toxicity - fish LL₅₀, 96 hour: 4.2 mg/l, Onchorhynchus mykiss (Rainbow trout)
Acute toxicity |
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12.2 |
Persistence & degradability |
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Expected to be readily biodegradable. |
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12.3 |
Bioaccumulation Potential |
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Partition coefficient REACH dossier information. The log Kow range of Litsea Cubeba oil constituents was found to be 2.06 - 6.3. 16.90% of the constituents has a log Kow >=4 |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available. |
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12.6 |
Other adverse effects |
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No additional data available. |
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13.1 |
Waste treatment methods |
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General information Dispose of in compliance with all local and national regulations. |
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14.1 |
UN number |
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UN No. Road |
3082 |
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UN No. SEA |
3082 |
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UN No. AIR |
3082 |
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14.2 |
UN proper shipping name |
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ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class 9 ADR/RID Classification CodeM6 ADR Label 9 IMDG Class 9 ICAO Class/Division 9 AND Class9
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant
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14.6 |
Special precautions for user |
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EMS F-A-S-F ADR Transport Category3 Emergency Action Code •3Z ADR/RID Hazard ID Number90 Tunnel Restriction Code (E) |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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No additional data available. |
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Guidance CHIP for everyone HSG228. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. |
Other Information |
None |
Revision Date |
01/09/2016 |
Reason for revision |
Updated SDS from supplier. |
Rev No/Repl, SDS Generated |
01 |