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MSDS - Marigold - Calendula Officinalis - Absolute
MARIGOLD ABSOLUTE
SAFETY DATA SHEET (SDS)
01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING
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1.1 |
Product Identifier |
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Product Name |
Marigold (Calendula) Absolute |
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Biological Definition |
Calendula Officinalis Flower Extract is an extract obtained from the flowers of the Calendula, Calendula officinalis L., Compositae |
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INCI Name |
Calendula Officinalis Flower Extract |
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Synonyms & Trade Names |
- |
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CAS-No |
84776-23-8 |
EC No. |
283-949-5 |
EINECS No. |
283-949-5 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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No additional data available. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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02. HAZARDS IDENTIFICATION
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements are Displayed in Section 16.
Physical and Chemical Hazards Not classified. Human health Skin Sens. 1 - H317 Environment Aquatic Chronic 2 - H411 |
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Classification (EC 1272/2008) |
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H317 May cause an allergic skin reaction H411 Toxic to aquatic life with long lasting effects. |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS09 GHS07
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Signal Word |
Warning |
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Contains |
d-Limonene. |
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Hazard Statements |
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H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment.P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+352 IF ON SKIN: Wash with plenty of soap and water. P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse. |
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Supplementary Precautionary Statements |
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P261 Avoid breathing vapour/spray. P321 Specific treatment (see medical advice on this label). P391 Collect spillage. P501 Dispose of contents/container to … |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available |
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Adverse physio-chemical properties |
No additional data available |
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Adverse effects on human health |
No additional data available |
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03. COMPOSITION/INFORMATION ON INGREDIENTS
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3.2 |
Mixtures |
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<1.0% Citronellal CAS-No.: 106-23-0 EC No.: 203-376-6
Classification (EC 1272/2008) Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Aquatic Chronic 2 - H411
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<1.0% Citronellol CAS-No.: 106-22-9, EC No.: 203-375-0
Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319, Skin Sens. 1 - H317
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<1.0% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5
Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410
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<1.0% Geraniol CAS-No.: 106-24-1 EC No.: 203-377-1
Classification (EC 1272/2008) Skin Irrit. 2 – H315, Eye Dam. 1 – H318, Skin Sens. 1 –H317
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<1.0% Phenyl Ethyl Alcohol CAS-No.: 60-12-8 EC No.: 200-456-2
Classification (EC 1272/2008) Eye Irrit. 2 - H319
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<1.0% Phytol CAS-No.: 150-86-7 EC No.: 205-776-6
Classification (EC 1272/2008) Skin Irrit. 2 - H315, Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410
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04. FIRST AID MEASURES
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4.1 |
Description of first aid measures |
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Inhalation |
Remove victim immediately from source of exposure. Get medical attention if any discomfort continues. |
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Ingestion |
Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions. |
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Skin Contact |
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues. |
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Eye Contact |
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention immediately. Continue to rinse. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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Ingestion May cause discomfort if swallowed. Skin contact May cause skin dryness and cracking. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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No additional data available |
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05. FIRE-FIGHTING MEASURES
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5.1 |
Extinguishing Media |
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Extinguishing media Use as appropriate: CO2, powder or waterspray. Large fires to be extinguished with alcohol resistant foam. Unsuitable extinguishing media Do not use a direct stream of water. |
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5.2 |
Special hazards arising from the product |
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Hazardous combustion products Not known. Unusual Fire & Explosion Hazards Toxic vapours may be released during fire, respiratory protection should be provided. |
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5.3 |
Advice for firefighters |
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Special Fire Fighting Procedures Avoid inhalation of generated fumes or vapours. Use appropriate respiratory equipment. Protective equipment for fire-fighters Wear full protective clothing. |
06. ACCIDENTAL RELEASE MEASURES
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6.1 |
Personal precautions, protective equipment and emergency procedures |
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Wear protective clothing as described in Section 8 of this safety data sheet. |
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6.2 |
Environmental Precautions |
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Do not discharge into drains, water courses or onto the ground. |
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6.3 |
Methods and material for containment and cleaning up. |
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Absorb with liquid binding material i.e., sand, acid binders, universal binders, sawdust. |
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6.4 |
Reference to other sections |
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Wear protective clothing as described in Section 8 of this safety data sheet. |
07. HANDLING AND STORAGE
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7.1 |
Precautions for safe handling |
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Close packaging after use. Reproduce labelling if transferring into another container. |
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7.2 |
Conditions for safe storage, including any incompatibilities |
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Keep in original containers. Keep away from food, drink and animal feeding stuffs. Keep away from heat sources and protected from light. |
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7.3 |
Specific end use(s) |
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No additional data available. |
08. EXPOSURE CONTROLS/PERSONAL PROTECTION
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8.1 |
Control parameters |
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No additional data available. |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Safety shower and eye bath. |
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Engineering Measures |
Provide adequate ventilation. |
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Respiratory Equipment |
For high concentrations use respiratory equipment. |
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Hand Protection |
Chemical resistant gloves (PVC) |
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Eye Protection |
Wear approved safety goggles. |
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Other Protection |
Wear appropriate clothing to prevent any possibility of skin contact. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. |
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Personal Protection |
Use personal protection according to Directive 89/686/EEC. |
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Skin Protection |
Wear apron or protective clothing in case of splashes. |
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only eliminate by authorised companies. |
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09. PHYSICAL AND CHEMICAL PROPERTIES
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Viscous liquid |
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Colour |
Dark brown to orange |
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Odour |
Characteristic |
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Relative Density |
0.955 - 0.980 @ 20⁰C |
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Flash Point (°C) |
>100⁰C |
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Refractive Index |
1.480 - 1.505 @ 20⁰C |
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Melting Point (°C) |
No additional data available. |
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Boiling Point (°C) |
No additional data available. |
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Vapour Pressure |
No additional data available. |
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Solubility in Water @20°C |
Insoluble in water. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10. STABILITY AND REACTIVITY
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10.1 |
Reactivity |
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No dangerous reactions known. |
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10.2 |
Chemical stability |
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Stable under normal temperature conditions. |
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10.3 |
Possible hazardous reactions |
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No dangerous reactions known. |
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10.4 |
Conditions to Avoid |
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Avoid exposure to high temperatures or direct sunlight. |
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10.5 |
Incompatible materials |
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Materials To Avoid Strong oxidising substances. |
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10.6 |
Hazardous Decomposition Products |
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No additional data available |
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11. TOXOLOGICAL INFORMATION
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
Toxicological information We have no data available on this product. It must be considered, handled and should be dealt with the highest possible caution. |
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Skin corrosion / irritation |
No additional data available. |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
No additional data available. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available |
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Aspiration hazard |
No additional data available. |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12. ECOLOGICAL INFORMATION
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12.1 |
Toxicity |
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No additional data available. |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available |
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12.6 |
Other adverse effects |
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No additional data available. |
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13. DISPOSAL CONSIDERATIONS
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13.1 |
Waste treatment methods |
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General information Do not re-use empty containers. Empty residue into a suitable disposal site.
Dispose of in compliance with all local and national regulations. |
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14. TRANSPORT INFORMATION
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14.1 |
UN number |
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UN No. Road |
3082 |
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UN No. SEA |
3082 |
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UN No. AIR |
3082 |
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14.2 |
UN proper shipping name |
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ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S (d-Limonene) |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN - Class 9: Miscellaneous dangerous substances and articles. ADR/RID/ADN - 9 IMDG - 9 ICAO - 9
Transport Labels
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14.4 |
Packing group |
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ADR/RID/ADN Packing group – III IMDG Packing group – III ICAO Packing group – III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant
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14.6 |
Special precautions for user |
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EMS F-A-S-F Hazard No. (ADR) 3YE Hazard No. (ADR) 90 Environmentally hazardous substance; miscellaneous dangerous substances. Tunnel Restriction Code (E) |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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Tariff Number 33012941 |
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15. REGULATORY INFORMATION
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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16. OTHER INFORMATION
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Hazard and/or Precautionary Statements in Full |
H318 Causes serious eye damage. H319 Causes serious eye irritation. H315 Causes skin irritation. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. H410 Very toxic to aquatic life with long lasting effects. H400 Very toxic to aquatic life. |
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Other Information |
None |
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Revision Date |
19/08/15 |
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Reason for revision |
New SDS |
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Rev No/Repl, SDS Generated |
01 |