1.1 |
Product Identifier |
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Product Name |
Fir Needle Oil (Sibirica) |
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Biological Definition |
Abies Sibirica Oil is the volatile oil distilled from the needles and branches of Abies sibirica, Pinaceae |
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INCI Name |
Abies Sibirica Oil |
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Synonyms & Trade Names |
- |
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CAS-No |
91697-89-1 |
EC No. |
294-351-9 |
EINECS No. |
294-351-9 |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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No additional data available. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements are displayed in Section 16. |
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Classification (EC 1272/2008) |
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Flam. Liq. 3 (H226) Asp. Tox. 1 (H304) Eye Irrit. 2 (H319) Skin Sens. 1 (H317) Aqu. Chron. 1 (H410) |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS08 GHS09 GHS07 GHS02
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Signal Word |
Danger |
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Contains |
Delta-3-Carene, alpha-Pinene, beta-Pinene, Limonene, Camphene. |
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Hazard Statements |
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H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P305+P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves/protective clothing and eye/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P310 Immediately call a POISON CENTER or doctor/physician. P273 Avoid release to the environment. P501 Dispose of contents/container to regional, national regulation. |
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Supplementary Precautionary Statements |
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None. |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available. |
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Adverse physio-chemical properties |
No additional data available. |
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Adverse effects on human health |
No additional data available. |
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3.2 |
Mixtures |
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18-30% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5
Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410
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15-25% Camphene CAS-No 79-92-5, EC 201-234-8
Classification (EC 1272/2008); Flam. Sol. 1 – H228, Eye Irrit 2 – H319, Aquatic Acute 1 – H400
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15-25% alpha-Pinene CAS-No.: 80-56-8 EC No.: 201-291-9
Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304
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2-6% beta-Pinene Cas. No: 127-91-3EC No: 204-872-5
Classification (EC 1272/2008); Danger, Flam. Liq. 3 – H226, Skin Sens. 1 – H317 , Asp Tox. 1 – H304, Aquatic Chronic 1 – H410
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1-5% delta-3-Carene CAS-No.: 13466-78-9 EC No.: 236-719-3
Classification (EC 1272/2008) Danger Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2, H411; Skin Sens. 1, H317
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4.1 |
Description of first aid measures |
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Inhalation |
Do not leave affected person unattended, Remove victim out of the danger area. Provide fresh air. |
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Ingestion |
If swallowed rinse mouth. Do NOT induce vomiting. |
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Skin Contact |
After contact with skin, wash immediately with plenty of water and soap. Remove contaminated clothing immediately. |
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Eye Contact |
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.
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4.2 |
Most important symptoms and effects, both acute and delayed |
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Observe risk of aspiration if vomiting occurs. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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Treat symptomatically |
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5.1 |
Extinguishing Media |
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Foam Extinguishing powder Carbon dioxide (CO2) Avoid full water jet |
5.2 |
Special hazards arising from the product |
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B (Fires of liquids or liquid turning substances). In case of fire toxic fumes like carbon monoxide and carbon dioxide may be liberated Burning produces heavy smoke. |
5.3 |
Advice for firefighters |
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Move undamaged containers from immediate hazard area if it can be done safely. Use suitable breathing apparatus. Regard to self protection |
6.1 |
Personal precautions, protective equipment and emergency procedures |
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Wear personal protection equipment. Avoid contact with skin, eye and clothing. Remove all sources of ignition. Provide adequate ventilation. Give a warning to persons in the hazard area |
6.2 |
Environmental Precautions |
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Do not allow to enter into surface water or drains. Cover drains. Prevent spread over a wide area (e.g. by containment or oil barriers). |
6.3 |
Methods and material for containment and cleaning up. |
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Absorb with liquid-binding material ( e.g. sand, diatomaceous earth, acid- or universal binding agents). |
6.4 |
Reference to other sections |
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See protective measures under point 7 and 8. |
7.1 |
Precautions for safe handling |
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Provide earthing of containers, equipment, pumps and ventilation facilities. Take precautionary measures against static discharges. Wear personal protective clothing (see chapter 8). Do not breathe gas/fume/vapour/spray. Use only in well-ventilated areas. When using do not eat, drink, smoke, sniff. |
7.2 |
Conditions for safe storage, including any incompatibilities |
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Keep container tightly closed. |
7.3 |
Specific end use(s) |
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No additional data available. |
8.1 |
Control parameters |
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No additional data available. |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Technical measures and the application of suitable work processes have priority over personal protection equipment. |
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Engineering Measures |
No additional data available. |
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Respiratory Equipment |
If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn. |
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Hand Protection |
Use solvent and acid resistant protection gloves according to EN 374. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Take recovery periods for skin regeneration. |
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Eye Protection |
Use protection goggles according to EN166. |
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Other Protection |
Wear appropriate clothing to prevent any possibility of skin contact. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. |
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Personal Protection |
Use personal protection according to Directive 89/686/EEC. |
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Skin Protection |
Protective work clothing solvent resistant (should be checked regularly). |
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only remove via authorised companies. |
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Liquid |
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Colour |
Colourless to slightly yellow. |
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Odour |
Characteristic. |
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Relative Density |
0.875 - 0.898 @ 20⁰C |
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Flash Point (°C) |
42⁰C |
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Refractive Index |
1.460 - 1.480 @ 20⁰C |
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Melting Point (°C) |
No additional data available. |
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Boiling Point (°C) |
No additional data available. |
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Vapour Pressure |
No additional data available. |
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Solubility in Water @20°C |
Insoluble in water. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10.1 |
Reactivity |
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No dangerous reactions known. |
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10.2 |
Chemical stability |
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Product is stable at room temperature. |
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10.3 |
Possible hazardous reactions |
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No dangerous reactions expected if used according to specifications. |
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10.4 |
Conditions to Avoid |
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Temperatures more than room temperature will benefit the transfer from liquid to vapour phase and formation of explosive atmospheres. Storing the product in open containers will benefit the formation of peroxides and derogate the quality. |
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10.5 |
Incompatible materials |
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No additional data available. |
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10.6 |
Hazardous Decomposition Products |
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No dangerous decomposition products known. |
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
Acute toxicity LD50 (oral) in mg/kg: > 5000 LD50 (dermal) in mg/kg: > 5000 |
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Skin corrosion / irritation |
No additional data available. |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
No additional data available. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
No additional data available. |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12.1 |
Toxicity |
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No additional data available. |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available. |
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12.6 |
Other adverse effects |
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No additional data available. |
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13.1 |
Waste treatment methods |
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Hazardous waste according to waste regulation Dispose according to legislation. Delivery to an approved waste disposal company. Non-contaminated packages may be recycled. |
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14.1 |
UN number |
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UN No. Road |
1272 |
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UN No. SEA |
1272 |
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UN No. AIR |
1272 |
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14.2 |
UN proper shipping name |
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PINE OIL |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class:3 ADR/RID/ADN Class:3 IMDG Class 3 ICAO Class/Division
Transport Labels
EAC – 3Y HIN – 30
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant
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14.6 |
Special precautions for user |
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See section 6 to 8. |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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Packed and transferred according to transport regulations. |
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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Hazard and/or Precautionary Statements in Full |
H226 Flammable liquid and vapour. H228 Flammable soild. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. |
Other Information |
None. |
Revision Date |
24/09/15 |
Reason for revision |
New SDS |
Rev No/Repl, SDS Generated |
01 |