MSDS - Eucalyptus Radiata - Essential Oil

1.1

Product Identifier 

Product Name 

Eucalyptus Oil Radiata.

Biological Definition

Eucalyptus Radiata Flower/Leaf/Stem Oil is the volatile oil obtained from the flowers, leaves and stems of Eucalyptus, Eucalyptus radiata var. Australiana, Myrtaceae.

INCI Name

Eucalyptus Radiata Flower/Leaf/Stem Oil.

Synonyms & Trade Names

CAS-No

92201-64-4

EC No.

295-995-3

EINECS No.

295-995-3

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements are Displayed in Section 16.

Classification (EC 1272/2008)

Physical: Flam. Liq. 3 – H226

Health: Skin Sens. 1 – H317; Asp. Tox. 1 – H304

Environmental: Aquatic Chronic 2 – H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS08            GHS09         GHS07          GHS02

Signal Word

Danger.

Contains

alpha-Pinene, beta-Pinene, Limonene.

Hazard Statements

H226                               Flammable liquid and vapour.

H304                               May be fatal if swallowed and enters airways.

H317                               May cause an allergic skin reaction.

H411                               Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273                               Avoid release to the environment.

P280                               Wear protective gloves/protective clothing/eye protection/face protection.

Supplementary Precautionary Statements

P210                                Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

P233                                Keep container tightly closed.

P240                                Ground/bond container and receiving equipment.

P241                                Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242                                Use only non-sparking tools.

P243                                Take precautionary measures against static discharge.

P261                                Avoid breathing dust/fume/gas/mist/vapours/spray.

P272                                Contaminated work clothing should not be allowed out of the workplace.

P301+310                       IF SWALLOWED: Immediately call a POISON CENTER or Doctor/Physician.

P302+352                       IF ON SKIN: Wash with plenty of soap and water.

P303+361+353              IF ON SKIN: (or hair): Remove/Take off immediately all contaminated clothing.

Rinse skin with water/shower.

P321                                Specific treatment (see… on this label).

P331                                Do NOT induce vomiting.

P333+313                       If skin irritation occurs: Get medical advice/attention.

P363                                Wash contaminated clothing before reuse.

P370+378                       In case of fire: Use… for extinction.

P391                                Collect spillage.

P403+235                       Store in a well-ventilated place. Keep cool.

P405                                Store locked up.

P501                                Dispose of contents/container to…

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

60-100% Cineol  CAS-No.: 470-67-7 EC No.: 207-428-9

Classification (EC 1272/2008) Flam. Liq. 3 – H226,

10-30% Alpha-terpineol  CAS-No.: 98-55-5 EC No.: 202-680-6

Classification (EC 1272/2008) Skin Irrit 2 – H315

5-10% alpha-Pinene CAS-No.: 80-56-8 EC No.: 201-291-9

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

5-10% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

1-5%  beta-Pinene Cas. No: 127-91-3EC No: 204-872-5

Classification (EC 1272/2008); Danger, Flam. Liq. 3 – H226, Skin Sens. 1 – H317 , Asp Tox. 1 – H304, Aquatic Chronic 1 – H410

1-5% 4-Terpineol CAS-No.: 562-74-3 EC No.: 209-235-5

Classification (EC 1272/2008) Acute Tox. 4 – H302, Skin Irrit. 2 – H315

1-5%  para-Cymene  CAS-No.: 99-87-6 EC No.: 202-796-7

Classification (EC 1272/2008); Flam. Liq. 3 – H226, Asp. Tox. 1 – H304, Aquatic Chronic 2 – H411

<1% Geraniol CAS-No.: 106-24-1 EC No.: 203-377-1

Classification (EC 1272/2008) Skin Irrit. 2 – H315, Eye Dam. 1 – H318, Skin Sens. 1 –H317

4.1

Description of first aid measures

Inhalation 

May cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. 

 Ingestion

If necessary, rinse mouth and provide fresh air. Get medical attention if discomfort continues.

Skin Contact 

If necessary remove contaminated clothing and wash skin with soap and water. Get medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues.

4.2

Most important symptoms and effects, both acute and delayed

Observe risk of aspiration if vomiting occurs.

4.3

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

5.1 

Extinguishing Media

Fire can be extinguished using: Foam, carbon dioxide or dry powder.

5.2 

Special hazards arising from the product

Containers close to fire should be removed or cooled with water.

No unusual fire or explosion hazards noted.

When heated and in case of fire, toxic vapours/gases may be formed.

5.3 

Advice for firefighters

Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6.1 

Personal precautions, protective equipment and emergency procedures

Use protective gloves, goggles and suitable protective clothing.

In case of spills, beware of slippery floors and surfaces.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Absorb with inert, damp, non-combustible material, then flush area with water.

Shovel into dry containers.

Cover and move the containers.

Flush the area with water.

6.4 

Reference to other sections

See protective measures under point 7 and 8.

7.1 

Precautions for safe handling

Avoid spilling, skin and eye contact.

Ensure adequate ventilation of the working area.

Adopt best manual handling considerations when handling, carrying and dispensing.

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight.

7.2 

Conditions for safe storage, including any incompatibilities

Keep container tightly closed.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional data available.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Technical measures and the application of suitable work processes have priority over personal protection equipment.

Engineering Measures

No additional data available.

Respiratory Equipment

No specific recommendation made, but respiratory protection may still be required under exceptional circumstances, when excessive air contamination exists.

Hand Protection

Protective gloves should be used if there is a risk of direct contact or splash.
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances.

Take recovery periods for skin regeneration.

Eye Protection

If risk of splashing, wear safety goggles or face shield. Use protection goggles according to EN166.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only remove via authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid, colourless to pale yellow.

Colour

Colourless to pale yellow.

Odour

Characteristic.

Relative Density

0.900 -  0.920 @ 20°C

Flash Point (°C)

42°C

Refractive Index

1.457 - 1.467 @ 20C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No dangerous reactions known.

10.2 

Chemical stability

Stable under normal temperature conditions.

10.3 

Possible hazardous reactions

No dangerous reactions expected if used according to specifications.

10.4 

Conditions to Avoid

Avoid heat, flames and other sources of ignition.

10.5 

Incompatible materials

Strong oxidising substances.

Strong acids.

Strong Alkalis

10.6 

Hazardous Decomposition Products

In case of fire, toxic gases (CO, CO2, NOx) may be formed.

11.1 

Information on toxicological effects 

Acute Toxicity

No specific health warnings noted.

No harmful effects expected in amounts likely to be ingested by accident.

Skin corrosion / irritation

No specific health warnings noted.

Serious eye damage / irritation

Spray and vapour in the eyes may cause irritation and smarting

Respiratory or skin sensitisation

In high concentrations, vapours may irritate throat and respiratory system and.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

No additional data available.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

GENERAL INFORMATION: Waste is suitable for incineration.

DISPOSAL METHODS: Dispose of waste and residues in accordance with local authority

Requirements.

14.1 

UN number

UN No. Road

1169

UN No. SEA

1169

UN No. AIR

1169

14.2 

UN proper shipping name

EXTRACTS, AROMATIC, LIQUID

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:3

ADR/RID/ADN Class:3

IMDG Class 3

ICAO Class/Division

Transport Labels

TUNNEL RESTRICTION CODE (D/E)

HAZCHEM CODE •3YE

EMS F-E, S-D

HIN – 30

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

See section 6 to 8.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

Packed and transferred according to transport regulations.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H318                  Causes serious eye damage.

H315                  Causes skin irritation.

H226                  Flammable liquid and vapour.

H302                  Harmful if swallowed.

H304                  May be fatal if swallowed and enters airways.

H317                  May cause an allergic skin reaction.

H411                  Toxic to aquatic life with long lasting effects.

H410                  Very toxic to aquatic life with long lasting effects.

H400                  Very toxic to aquatic life..

Other Information

None.

Revision Date

27/07/15

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01