MSDS - Eucalyptus Lemon - Eucalyptus citriodora - Essential Oil

1.1

Product Identifier 

Product Name 

Eucalyptus Lemon Oil

Biological Definition

Eucalyptus Lemon Oil is the volatile oil obtained from Eucalyptus citriodora, Myrtaceae.

INCI Name

Eucalyptus Citriodora Oil

Synonyms & Trade Names

Eucalyptus Maculata Citrodora

CAS-No

8000-48-4 / 85203-56-1

EC No.

- / 286-249-8

EINECS No.

- / 286-249-8

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements is displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards : Not classified.

Human health : Skin Irrit. 2 - H315;Eye Irrit. 2 - H319;Skin Sens. 1 - H317

Environment : Aquatic Acute 2 - H401;Aquatic Chronic 2 - H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

    GHS07   GHS09

Signal Word

None.

Contains

Alpha pinene natural, Citronellal, Citronellol, Limonene.

Hazard Statements

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H401 Toxic to aquatic life.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

-

Supplementary Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash … thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P313 Get medical advice/attention.

P321 Specific treatment (see … on this label).

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P337 If eye irritation persists:

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P501 Dispose of contents/container to …

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

60.0 – 100.0%Citronellal CAS-No.: 106-23-0 EC No.: 203-376-6

Classification (EC 1272/2008) Skin Irrit. 2 - H315,  Skin Sens. 1 - H317,  Aquatic Chronic 2 - H411

5.0 – 12.0%Citronellol CAS-No.: 106-22-9 EC No.: 203-375-0

Classification (EC 1272/2008) Skin Irrit. 2 - H315,  Eye Irrit. 2 - H319,  Skin Sens. 1 - H317

5.0 – 10.0%Iso Pulegol        CAS-No.: 89-79-2 EC No.: 201-940-6

Classification (EC 1272/2008) Acute Tox. 4 - H302

1.0   - 5.0%Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,  Skin Sens. 1 - H317,  Asp. Tox. 1 - H304,  Aquatic Acute 1 - H400,  Aquatic Chronic 1 - H410

1.0 - 5.0% Alpha pinene natural CAS-No.: 80-56-8 EC No.: 201-291-9

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

1.0 - 5.0% Beta pinene CAS-No.: 127-91-3 EC No.: 204-872-5

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

4.1

Description of first aid measures

Inhalation 

Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues.

 Ingestion

Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. Do not induce vomiting.

Skin Contact 

Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.  Get medical attention if any discomfort continues.

Eye Contact   

Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Extinguishing media: Carbon dioxide (CO2).

5.2 

Special hazards arising from the product

When heated and in case of fire, irritating vapours/gases may be formed.

5.3 

Advice for firefighters

Special Fire Fighting Procedures

Water spray should be used to cool containers.

Protective equipment for fire-fighters

Wear full protective clothing. Wear suitable respiratory equipment when necessary.

6.1 

Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation of the working area. Wear suitable protective equipment.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Absorb with inert, non-combustible, inorganic absorbant material, sweep up and remove to an approved disposal container. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.

6.4 

Reference to other sections

No additional data available.

7.1 

Precautions for safe handling

Avoid spilling, skin and eye contact.

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Protect from light, including direct sunrays. Keep away from heat, sparks and open flame.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional information available.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory Equipment

No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand Protection

Use suitable protective gloves if risk of skin contact.

Eye Protection

If risk of splashing, wear safety goggles or face shield.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. When using, do not eat, drink or smoke.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid pale yellow to greenish yellow.

Colour

Pale yellow to greenish yellow.

Odour

Characteristic.

Relative Density

0.858  -  0.877 @ 20°C

Flash Point (°C)

73. - 74 CC (Closed cup).

Refractive Index

1.451  -  1.464 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

No additional data available.

10.5 

Incompatible materials

Oxidising agents.

10.6 

Hazardous Decomposition Products

No additional data available.

11.1 

Information on toxicological effects 

Acute Toxicity

Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.

Skin corrosion / irritation

May cause discomfort if swallowed. May cause sensitisation by skin contact.  

Serious eye damage / irritation

Spray and vapour in the eyes may cause irritation and smarting.

Respiratory or skin sensitisation

In high concentrations, vapours may irritate throat and respiratory system and cause coughing.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

We have no data regarding ecotoxicity, but it must be considered that this product may be dangerous for the environment.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

Do not allow product to enter streams, sewers or other waterways.

13.1 

Waste treatment  methods

Dispose of in compliance with all local and national regulations.

14.1 

UN number

UN No. Road

3082

UN No. SEA

3082

UN No. AIR

3082

14.2 

UN proper shipping name

ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:9  Miscellaneous dangerous substances and articles.

IMDG Class:9

ICAO Class/Division:9

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group: III

IMDG Packing group: III

ICAO Packing group: III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

EMS F-A-S-F

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

H401 Toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None.

Revision Date

18/05/2016

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01