MSDS - Eucalyptus Smithii - Essential Oil

1.1

Product Identifier 

Product Name 

Eucalyptus Oil Smithii

Biological Definition

Eucalyptus Smithii Leaf Oil is an essential oil obtained from the fresh leaves of the Eucalyptus, Eucalyptus smithii, Myrtaceae. Its chief constituent is eucalyptol.

INCI Name

Eucalyptus Smithii Leaf Oil

Synonyms & Trade Names

CAS-No

91771-68-5

EC No.

294-962-0

EINECS No.

294-962-0

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards Flam. Liq. 3 - H226

Human health Skin Sens. 1 - H317; Asp. Tox. 1 - H304

Environment Aquatic Chronic 2 - H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS08            GHS09         GHS07          GHS02

Signal Word

Danger

Contains

Alpha pinene natural, Beta Pinene, Limonene.

Hazard Statements

H226                               Flammable liquid and vapour.

H304                               May be fatal if swallowed and enters airways.

H317                               May cause an allergic skin reaction.

H411                               Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P262 Do not get in eyes, on skin, or on clothing.

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331 Do NOT induce vomiting.

P391 Collect spillage.

P501 Dispose of contents/container to …

Supplementary Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P321 Specific treatment (see … on this label).

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

P370+378 In case of fire: Use … for extinction.

P403+235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

70-90% Cineol  CAS-No.: 470-67-7 EC No.: 207-428-9

Classification (EC 1272/2008) Flam. Liq. 3 – H226,

1-10% Limonene CAS-No.: 5989-27-5 EC No.: 227-813-5

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Skin Irrit 2 – H315 Asp Tox. 1 – H304, Skin Sens. 1 – H317 Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

1-5% alpha-Pinene CAS-No.: 80-56-8 EC No.: 201-291-9

Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304

1-5% beta-Pinene  Cas. No: 127-91-3EC No: 204-872-5

Classification (EC 1272/2008); Flam. Liq. 3 - H226,Skin Irrit. 2 - H315,Skin Sens. 1 - H317, Asp. Tox. 1 - H304

1-5%  para-Cymene  CAS-No.: 99-87-6 EC No.: 202-796-7

Classification (EC 1272/2008); Flam. Liq. 3 – H226, Asp. Tox. 1 – H304, Aquatic Chronic 2 – H411

4.1

Description of first aid measures

Inhalation 

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air at once. Seek medical attention.

Ingestion 

Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING!

Skin Contact 

Remove contaminated clothing. Wash the skin immediately with soap and water. Seek medical attention if irritation or symptoms persist. Seek medical attention.

Eye Contact   

Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. If symptoms persist seek medical attention.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Extinguishing media

Use as appropriate: Carbon Dioxide (CO2), dry chemical

5.2 

Special hazards arising from the product

Specific hazards

Burning can produce irritating, toxic and obnoxious fumes.

5.3 

Advice for firefighters

Special Fire Fighting Procedures

Water is unsuitable to use as an extinguishing method.

Protective equipment for fire-fighters

Wear suitable respiratory equipment when necessary.

6.1 

Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Wear suitable protective clothing.

6.2 

Environmental Precautions

Do not allow product to enter drains. Prevent further spillage if safe.

6.3 

Methods and material for containment and cleaning up.

Absorb with inert, absorbant material. Sweep up. Transfer to suitable, labelled container for disposal. Clean spillage area thoroughly with plenty of water.

6.4 

Reference to other sections

No additional data available.

7.1 

Precautions for safe handling

Avoid spilling, skin and eye contact. Ensure adequate ventilation of the working area. Adopt best manual handling considerations when handling, carrying and dispensing. Keep away from heat, sparks and open flame.

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

p-Cymene (CAS: 99-87-6)

Ingredient Comments

Contains no substances with occupational exposure limit values.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

No additional data available.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Self-contained breathing apparatus.

Hand Protection

Chemical resistant gloves required for prolonged or repeated contact.

Eye Protection

Wear approved safety goggles.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.

Personal Protection 

No additional data available.

Skin Protection 

No additional data available.

Environmental Exposure Controls 

No additional data available.

9.1 

Information on basic physical and chemical properties 

Appearance

Mobile liquid, colourless to pale yellow

Colour

Colourless to pale yellow.

Odour

Characteristic

Relative Density

0.905 - 0.925 @ 20°C

Flash Point (°C)

49°C (Closed Cup)

Refractive Index

1.457 - 1.467 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under normal temperature conditions.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

Heat, sparks and open flames.

10.5 

Incompatible materials

Materials To Avoid

Strong oxidising agents. Strong acids.

10.6 

Hazardous Decomposition Products

Combustion produces carbon dioxide, carbon monoxide and smoke.

11.1 

Information on toxicological effects 

Acute Toxicity

Toxicological information

Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.

Skin corrosion / irritation

May cause sensitisation by skin contact.

Serious eye damage / irritation

Spray and vapour in the eyes may cause irritation and smarting.

Respiratory or skin sensitisation

In high concentrations, vapours may irritate throat and respiratory system and cause coughing. 

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

No additional data available

12.2 

Persistence & degradability

No additional data available

12.3 

Bioaccumulation Potential

No additional data available

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Dispose of in compliance with all local and national regulations.

14.1 

UN number

UN No. Road

1169

UN No. SEA

1169

UN No. AIR

1169

14.2 

UN proper shipping name

EXTRACTS, AROMATIC, LIQUID

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:3

ADR/RID/ADN Class:3

IMDG Class 3

ICAO Class/Division

Transport Labels

EMS F-E, S-D

Emergency Action Code 3Y

Hazard No. (ADR) 30 Flammable liquid (flash-point between 23°C and 60°C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60°C, heated to a temperature equal to or above its flash-point, or self heating liquid.

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

See section 6 to 8.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

Packed and transferred according to transport regulations.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None

Revision Date

25/01/16

Reason for revision

Updated SDS

Rev No/Repl, SDS Generated

02