MSDS - Elemi - Canarium Luzonicum - Essential Oil

1.1

Product Identifier 

Product Name 

Elemi Oil

Biological Definition

"Elemi Resin Oil". Canarium Luzonicum Gum Oil is an essential oil obtained from the resin exudate of the Elemi, Canarium luzonicum syn. C. commune, Burseraceae.

INCI Name

Canarium Luzonicum Gum Oil

Synonyms & Trade Names

-

CAS-No

n/a

EC No.

n/a

EINECS No.

n/a

1.2

Relative identified uses of the substance or mixture and uses advised against

Industrial, only for professional use.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements Displayed in Section 16.

Human health

May be fatal if swallowed and enters airways. The liquid may be irritating to skin. May cause sensitisation or allergic reactions in sensitive individuals.

Environmental

The product contains a substance which is toxic to aquatic organisms and which may cause long-term adverse effects in the aquatic environment.

Physicochemical

Flammable liquid

Classification (EC 1272/2008)

Physical and Chemical Hazards: Flam. Liq. 3 - H226

Human health:Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304

Environment: Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

    GHS02 GHS07   GHS08 GHS09

Signal Word

Danger.

Contains

(R)-p-mentha-1,8-diene, 1, 8 cineole, Alpha Pinene, Beta Pinene, a terpinolene

Hazard Statements

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P331 Do NOT induce vomiting.

P391 Collect spillage.

P262 Do not get in eyes, on skin, or on clothing.

Supplementary Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

P233 Keep container tightly closed.

P240 Ground/ bond container and receiving equipment.

P241 Use explosion-proof electrical equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing vapour/ spray.

P264 Wash contaminated skin thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the workplace.

P302+P352 IF ON SKIN: Wash with plenty of water.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.

Rinse skin with water/ shower.

P321 Specific treatment (see medical advice on this label).

P332+P313 If skin irritation occurs: Get medical advice/ attention.

P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/ container in accordance with national regulations.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

> 50% (R)-p-mentha-1,8-dieneCAS-No: 5989-27-5EC No: 227-813-5

Classification (EC 1272/2008): M factor (Acute) = 1 M factor (Chronic) = 1

Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,  Skin Sens. 1 - H317,   Asp. Tox. 1 - H304,   Aquatic Acute 1 - H400,   Aquatic Chronic 1 - H410

10-15% Alpha PhellandreneCAS-No: 99-89-2EC No: 202-792-5

Classification (EC 1272/2008): Flam. Liq. 3 - H226,   Asp. Tox. 1 - H304

1-5% 1, 8 cineoleCAS-No: 470-82-6EC No: 207-431-5

Classification (EC 1272/2008): Flam. Liq. 3 - H226,   Skin Sens. 1B - H317

1-5% p-menth-1-en-8-olCAS-No: 98-55-5EC No: 202-680-6

Classification (EC 1272/2008): Skin Irrit. 2 - H315,   Eye Irrit. 2 - H319

1-5% p-CymeneCAS-No: 99-87-6EC No: 202-796-7

Classification (EC 1272/2008): Flam. Liq. 3 - H226,   Asp. Tox. 1 - H304,   Aquatic Chronic 2 - H411

< 1% Alpha PineneCAS-No: 80-56-8EC No: 201-291-9

Classification (EC 1272/2008): Flam. Liq. 3 - H226,   Skin Irrit. 2 - H315,   Skin Sens. 1 - H317,  
Asp. Tox. 1 - H304

< 1% a terpinoleneCAS-No: 586-62-9 EC No: 209-578-0

Classification (EC 1272/2008): M factor (Acute) = 1 M factor (Chronic) = 1

Skin Sens. 1 - H317,   Asp. Tox. 1 - H304,   Aquatic Acute 1 - H400,   Aquatic Chronic 1 - H410

< 1% Beta PineneCAS-No:  127-91-3EC No: 204-872-5

Classification (EC 1272/2008): Flam. Liq. 3 - H226,   Skin Irrit. 2 - H315,   Skin Sens. 1 - H317

Asp. Tox. 1 - H304

4.1

Description of first aid measures

Inhalation 

Remove person to fresh air and keep comfortable for breathing. If breathing stops, provide

artificial respiration. Get medical attention if any discomfort continues.

 Ingestion

Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attention.

Skin Contact 

Wash skin thoroughly with soap and water. Continue to rinse for at least 15 minutes. Get

medical attention if irritation persists after washing.

Eye Contact   

Remove any contact lenses and open eyelids wide apart. Rinse with water. Continue to rinse

for at least 15 minutes. Get medical attention if irritation persists after washing.

4.2

Most important symptoms and effects, both acute and delayed

Inhalation May be fatal if swallowed and enters airways.

Skin contact May cause an allergic skin reaction.

4.3

Indication of any immediate medical attention and special treatment needed

Notes for the doctor: Treat symptomatically.

5.1 

Extinguishing Media

Extinguishing media: Carbon dioxide (CO2). Dry Powder. Foam. Water Spray.

Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire.

5.2 

Special hazards arising from the product

Burning produces irritating, toxic and obnoxious fumes.

5.3 

Advice for firefighters

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.

6.1 

Personal precautions, protective equipment and emergency procedures

Personal precautions: Provide adequate ventilation. Avoid contact with skin and eyes. Avoid inhalation of vapours. Wear protective clothing and gloves.

For emergency responders: Wear an appropriate NIOSH / MSHA approved respirator if mist or vapour is generated.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Absorb with liquid binding material (e.g sand, diatomaceous earth, acid or universal binding agents). Collect in closed and suitable containers for disposal.

6.4 

Reference to other sections

For personal protection, see Section 8. For waste disposal, see Section 13. Click here to enter text.

7.1 

Precautions for safe handling

Usage precautions

Apply good manufacturing practice and industrial hygiene practices. Keep containers sealed when not in use. Provide adequate ventilation. Keep away from heat, sparks and open flame.

Advice on general occupational hygiene

Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.

Remove contaminated clothing and protective equipment before entering eating areas.

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly-closed, original container in a dry, cool and well-ventilated place.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

(R)-p-mentha-1,8-diene (CAS: 5989-27-5)

DNEL Workers - Inhalation; Long term systemic effects: 33.3 mg/m³

General population - Oral; Long term systemic effects: 4.76 mg/kg

PNEC - STP; 1.8 mg/l

- Soil; 0.262 mg/kg

- Fresh water; 0.0054 mg/l

- Marine water; 0.00054 mg/l

- Sediment (Fresh water); 1.32 mg/kg

- Sediment (Marine water); 0.13 mg/kg

1, 8 cineole (CAS: 470-82-6)

DNEL Workers - Dermal; Long term systemic effects: 2 mg/kg

General population - Oral; Long term systemic effects: 600 mg/kg

General population - Dermal; Long term systemic effects: 1 mg/kg

General population - Inhalation; Long term systemic effects: 1.74 mg/m³

PNEC - STP; 10 mg/l

- Soil; 0.2 mg/kg

- Intermittent release; 0.57 mg/l

- Fresh water; 0.057 mg/l

- Marine water; 0.0057 mg/l

- Sediment (Fresh water); 0.06732 mg/kg

- Sediment (Marine water); 0.00673 mg/kg

Alpha Pinene (CAS: 80-56-8)

DNEL Workers - Inhalation; Long term systemic effects: 5.98 mg/m³

General population - Oral; Long term systemic effects: 0.31 mg/kg

General population - Inhalation; Long term systemic effects: 1.06 mg/m³

PNEC - STP; 3.26 mg/l

- Soil; 0.539 mg/kg

- Fresh water; 0.004 mg/l

- Marine water; 0.0004 mg/l

- Sediment (Fresh water); 1.033 mg/kg

- Sediment (Marine water); 0.103 mg/kg

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material.

Hand Protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible.

Eye Protection

Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles or face shield.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Use personal protection according to Directive 89/686/EEC.

Skin Protection 

Wear appropriate clothing to prevent any possibility of skin contact. Wear apron or protective clothing in case of contact.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Liquid

Colour

Colourless to yellow.

Odour

Characteristic – balsamic spicy.

Relative Density

0.850  -  0.910  @ 20°C

Flash Point (°C)

54.0

Refractive Index

1.472  -  1.490  @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

Hydrocarbon content 89%

10.1 

Reactivity

The substance is stable under normal storage and handling conditions.

10.2 

Chemical stability

Stable at normal ambient temperature.

10.3 

Possible hazardous reactions

None known.

10.4 

Conditions to Avoid

Avoid heat, flames and other sources of ignition.

10.5 

Incompatible materials

Avoid strong oxidising agents and strong reducing agents.

10.6 

Hazardous Decomposition Products

Carbon dioxide (CO₂). Carbon monoxide (CO).

11.1 

Information on toxicological effects 

Acute Toxicity

No additional data available.

Skin corrosion / irritation

No additional data available.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

No additional data available.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

Do not allow product to enter streams, sewers or other waterways.

13.1 

Waste treatment  methods

Recycling is preferred to disposal or burning. Disposal must be made according to official regulations. Must not be disposed together with household waste.

14.1 

UN number

UN No. Road

1169

UN No. SEA

1169

UN No. AIR

1169

14.2 

UN proper shipping name

EXTRACTS, AROMATIC, LIQUID

14.3 

Transport hazard class(es)

ADR/RID/ADN Class: 3 Flammable liquid

IMDG Class 3

ICAO Class/Division 3

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

EmS F-E, S-D

ADR transport category 3

Emergency Action Code 3Y

Hazard Identification Number(ADR/RID)30

Tunnel restriction code (D/E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None.

Revision Date

14/10/2016

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01