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MSDS - Dill - Peucedanum graveolens - Essential Oil
DILL SEED ESSENTIAL OIL
SAFETY DATA SHEET (SDS)
01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING
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1.1 |
Product Identifier |
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Product Name |
Dill Seed Oil |
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Biological Definition |
Anethum Graveolens Seed Oil is an essential oil obtained from the seeds of the Dill, Anethum graveolens L., Apiaceae. It contains carvone (50%), D-limonene, phellandrene and other terpenes. |
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INCI Name |
Anethum Graveolens Seed Oil |
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Synonyms & Trade Names |
- |
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CAS-No |
90028-03-8 / 8006-75-5 |
EC No. |
289-790-8 / - |
EINECS No. |
289-790-8 / - |
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1.2 |
Relative identified uses of the substance or mixture and uses advised against |
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No additional data available. |
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1.3 |
Details of the supplier of the safety data sheet |
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Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912 |
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1.4 |
Emergency Tel. No. |
+ 44 (0) 161 633 3952 |
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02. HAZARDS IDENTIFICATION
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2.1 |
Classification of the substance or mixture |
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The Full Text for all Hazard Statements displayed in Section 16. |
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Classification (EC 1272/2008) |
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Flammable Liquid, Hazard Category 3. H226 Aspiration toxicity Category 1 - (H304) Skin corrosion/irritation Category 2 - (H315) Skin sensitisation Category 1 - (H317) |
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2.2 |
Label Elements |
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Label in accordance with (EC) No 1272/2008 |
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GHS02GHS07 GHS08 GHS09
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Signal Word |
Danger. |
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Contains |
Limonene |
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Hazard Statements |
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H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H410: Very toxic to aquatic life with long lasting effects. |
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Precautionary Statements |
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P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P370+P378: In case of fire: Use water to extinguish. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P331: Do NOT induce vomiting. P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents in accordance with local, state or national legislation. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P321: Specific treatment (see Medical Advice on this label). P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P362+P364: Take off contaminated clothing. And wash it before reuse. P302+P352: IF ON SKIN: Wash with plenty of water. P273: Avoid release to the environment. P391: Collect spillage. |
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Supplementary Precautionary Statements |
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P264: Wash hands and exposed skin thoroughly after handling. P332+P313: If skin irritation occurs: Get medical advice/attention. |
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2.3 |
Other Hazards |
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PBT or vPvB according to Annex XIII |
No additional data available. |
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Adverse physio-chemical properties |
No additional data available. |
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Adverse effects on human health |
No additional data available. |
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03. COMPOSITION/INFORMATION ON INGREDIENTS
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3.1 |
Substances |
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45 - 55% Carvone CAS No: 2244-16-8 EC No: 218-827-2
Classification (EC 1272/2008) Skin Sens. 1 – H317
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<43% Limonene CAS-No: 5989-27-5EC No: 227-813-5
Classification (EC 1272/2008) Flam Liq. 3 - H226, Asp. Tox. 1 - H304, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410
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< 4% (Z)-dihydro Carvone CAS No: 99-49-0 EC No: 202-759-5
Classification (EC 1272/2008) Skin Sens. 1 – H317
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04. FIRST AID MEASURES
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4.1 |
Description of first aid measures |
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Inhalation |
Remove from exposure area to fresh air. Obtain medical advice if discomfort occurs. |
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Ingestion |
Wash mouth out with water and obtain medical advice immediately. DO NOT INDUCE VOMITING! |
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Skin Contact |
Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical advice if irritation persists or there is any sign of tissue damage. |
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Eye Contact |
Flush with plenty of water for at least 15 minutes. Remove contact lenses. Seek medical advice. |
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4.2 |
Most important symptoms and effects, both acute and delayed |
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Symptoms Contact: may cause an allergic reaction. |
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4.3 |
Indication of any immediate medical attention and special treatment needed |
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Treat symptomatically. |
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05. FIRE-FIGHTING MEASURES
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5.1 |
Extinguishing Media |
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Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
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5.2 |
Special hazards arising from the product |
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Specific hazards arising from the Thermal decomposition can lead to release of irritating and toxic gases and vapours. |
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5.3 |
Advice for firefighters |
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Standard procedure for chemical fires. Spray extinguishing media to base of flames. Wear protective clothing. Avoid inhalation of vapours. Wear suitable respiratory equipment, if insufficient ventilation. Closed containers may build up pressure when exposed to heat and should be cooled with water spray. |
06. ACCIDENTAL RELEASE MEASURES
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6.1 |
Personal precautions, protective equipment and emergency procedures |
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Ensure adequate ventilation, especially in confined areas. For emergency responders Use personal protection recommended in Section 8. |
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6.2 |
Environmental Precautions |
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Do not discharge into drains, water courses or onto the ground. Keep away from surface and ground water. See section 12 for additional information. |
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6.3 |
Methods and material for containment and cleaning up. |
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Remove ignition sources. Ensure adequate ventilation. Absorb with inert, non-combustible, inorganic absorbent material, sweep up and remove to an approved disposal container. Dispose of according to current local authority guidelines. |
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6.4 |
Reference to other sections |
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See sections 4, 8 and 13. |
07. HANDLING AND STORAGE
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7.1 |
Precautions for safe handling |
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Apply good manufacturing practice & industrial hygiene practices, ensuring proper workplace ventilation. Keep original container closed. Avoid contact with skin and eyes. Observe good personal hygiene, and do not eat, drink or smoke whilst handling. |
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7.2 |
Conditions for safe storage, including any incompatibilities |
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Keep container tightly closed in a dry and well-ventilated place. |
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7.3 |
Specific end use(s) |
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No additional data available. |
08. EXPOSURE CONTROLS/PERSONAL PROTECTION
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8.1 |
Control parameters |
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No additional data available. |
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8.2 |
Exposure controls |
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Protective Equipment |
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Process Conditions |
Provide eyewash station. |
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Engineering Measures |
Provide adequate ventilation, especially in confined areas. |
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Respiratory Equipment |
Avoid breathing vapours. Respiratory equipment should not be necessary with adequate ventilation. |
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Hand Protection |
Avoid all skin contact. Wear chemical resistant gloves (PVC). |
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Eye Protection |
Avoid contact with eyes. Wear approved safety goggles with built in side shield. |
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Other Protection |
No additional data available. |
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Hygiene Measures |
Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed. |
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Personal Protection |
Avoid inhalation and contact with skin and eyes. |
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Skin Protection |
Wear apron or protective clothing in case of splashes. |
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Environmental Exposure Controls |
Avoid discharging into drainage water. Only eliminate by authorised companies. |
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09. PHYSICAL AND CHEMICAL PROPERTIES
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9.1 |
Information on basic physical and chemical properties |
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Appearance |
Clear liquid |
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Colour |
Pale yellow. |
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Odour |
Characteristic |
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Relative Density |
Approx. 0.900 @ 20°C |
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Flash Point (°C) |
48 °C |
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Refractive Index |
Approx. 1.485 @ 20°C |
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Melting Point (°C) |
No additional data available. |
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Boiling Point (°C) |
No additional data available. |
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Vapour Pressure |
No additional data available. |
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Solubility in Water @20°C |
No additional data available. |
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Auto-ignition temperature (°C) |
No additional data available. |
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9.2 |
Other information |
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No additional data available. |
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10. STABILITY AND REACTIVITY
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10.1 |
Reactivity |
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Stable under normal temperature and storage conditions and recommended use. |
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10.2 |
Chemical stability |
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Stable under normal temperature and storage conditions and recommended use. |
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10.3 |
Possible hazardous reactions |
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Not expected under normal temperature conditions and recommended use. |
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10.4 |
Conditions to Avoid |
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Avoid heat, sparks and open flames. |
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10.5 |
Incompatible materials |
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No additional data available. |
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10.6 |
Hazardous Decomposition Products |
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Not expected under normal temperature conditions and recommended use. In case of combustion; CO2 and CO may be released. |
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11. TOXOLOGICAL INFORMATION
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11.1 |
Information on toxicological effects |
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Acute Toxicity |
No additional data available. |
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Skin corrosion / irritation |
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Serious eye damage / irritation |
No additional data available. |
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Respiratory or skin sensitisation |
May cause an allergic skin reaction. |
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Germ Cell Mutagenicity |
No additional data available. |
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Carcinogenicity |
No additional data available. |
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Reproductive toxicity |
No additional data available. |
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STOT-single exposure |
No additional data available. |
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STOT-repeated exposure |
No additional data available. |
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Aspiration hazard |
May be fatal if swallowed and enters airways |
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Photo-toxicity |
No additional data available. |
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Other Information |
No additional data available. |
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12. ECOLOGICAL INFORMATION
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12.1 |
Toxicity |
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Very toxic to aquatic life with long lasting effects. |
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12.2 |
Persistence & degradability |
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No additional data available. |
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12.3 |
Bioaccumulation Potential |
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No additional data available. |
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12.4 |
Mobility in soil |
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No additional data available. |
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12.5 |
Results of PBT and vPvB Assessment |
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No additional data available. |
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12.6 |
Other adverse effects |
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Do not discharge into the environment especially not into waterways, sewers and the sea. |
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13. DISPOSAL CONSIDERATIONS
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13.1 |
Waste treatment methods |
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Do not release into the environment. Collect waste into suitable containers and contact hazardous chemical disposal company. Containers must be completely empty before disposal. |
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14. TRANSPORT INFORMATION
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14.1 |
UN number |
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UN No. Road |
UN 1169 |
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UN No. SEA |
UN 1169 |
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UN No. AIR |
UN 1169 |
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14.2 |
UN proper shipping name |
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Extracts, Aromatic, Liquid. |
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14.3 |
Transport hazard class(es) |
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ADR/RID/ADN Class:3 Flammable Liquid. IMDG Class:3 Flammable Liquid. ICAO Class/Division:3 Flammable Liquid.
Transport Labels
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14.4 |
Packing group |
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ADR/RID/ADN Packing group III IMDG Packing group III ICAO Packing group III |
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14.5 |
Environmental hazards |
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Environmentally Hazardous Substance/Marine Pollutant.
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14.6 |
Special precautions for user |
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No additional data available. |
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14.7 |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code |
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No additional data available.
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15. REGULATORY INFORMATION
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15.1 |
Safety, health and environmental regulations/legislation specific for the substance or mixture |
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Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. |
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15.2 |
Chemical safety assessment |
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No additional information available. |
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16. OTHER INFORMATION
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Hazard and/or Precautionary Statements in Full |
H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. |
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Other Information |
No additional data available. |
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Revision Date |
13/02/2017 |
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Reason for revision |
Updated to new SDS format |
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Rev No/Repl, SDS Generated |
03 replaces version 02 |