MSDS - Coriander - Coriandrum sativum - Essential Oil

1.1

Product Identifier 

Product Name 

Coriander Seed Oil.

Biological Definition

Coriandrum Sativum Fruit Oil is the volatile oil obtained from the dried fruit of the Coriander, Coriandrum sativum L., Umbelliferae.

INCI Name

Coriandrum Sativum Fruit Oil.

Synonyms & Trade Names

-

CAS-No

8008-52-4 / 84775-50-8

EC No.

- / 283-880-0

EINECS No.

- / 283-880-0

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements displayed in Section 16.

Hydrocarbon Content:15%

Human health :May cause serious eye damage and skin irritation May cause lung damage if swallowed.

Environment : The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.

Classification (EC 1272/2008)

Physical hazards: Not Classified.

Health hazards: Skin Irrit. 2 - H315; Eye Irrit. 2 - H319; Skin Sens. 1 - H317; Asp. Tox. 1 - H304

Environmental hazards:Aquatic Chronic 2 - H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

   GHS07    GHS08   GHS09

Signal Word

Danger.

Contains

GERANIOL,  Limonene,  pinenes

Hazard Statements

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplementary Precautionary Statements

P272 Contaminated work clothing should not be allowed out of the workplace.

P261 Avoid breathing vapour/spray.

P264 Wash contaminated skin thoroughly after handling.

P321 Specific treatment (see medical advice on this label).

P313 Get medical advice/attention.

P331 Do NOT induce vomiting.

P332+313 If skin irritation occurs: Get medical advice/attention.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

P337 If eye irritation persists:

P362 Take off contaminated clothing and wash before reuse.

P363 Wash contaminated clothing before reuse.

P391 Collect spillage.

P405 Store locked up.

P501 Dispose of contents/container to …

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

5.0 – 10.0% Camphor CAS-No: 464-49-3EC No: 207-355-2

Classification (EC 1272/2008): Flam. Liq. 2 - H225,   Acute Tox. 4 - H332,   STOT SE 2 - H371

1.0 – 5.0% GeraniolCAS-No:106-24-1EC No: 203-377-1

Classification (EC 1272/2008): Skin Irrit. 2 - H315,   Eye Dam. 1 - H318,  Skin Sens. 1 - H317

1.0 – 5.0% Geranyl AcetateCAS-No: 105-87-3EC No: 203-341-5

Classification (EC 1272/2008): Aquatic Chronic 2 - H411

1.0 – 5.0% LimoneneCAS-No:5989-27-5EC No: 227-813-5

Classification (EC 1272/2008): Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,   Skin Sens. 1 - H317, Asp. Tox. 1 - H304,   Aquatic Acute 1 - H400,   Aquatic Chronic 1 - H410

60.0 – 100.0% Linalool CAS-No: 78-70-6EC No: 201-134-4

Classification (EC 1272/2008): Skin Irrit. 2 - H315

1.0 – 5.0% p-Cymene CAS-No: 99-87-6EC No: 202-796-7

Classification (EC 1272/2008): Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,  Skin Sens. 1 - H317, Asp. Tox. 1 - H304,  Aquatic Acute 1 - H400,  Aquatic Chronic 1 - H410.

5.0 – 10.0% pinenesCAS-No: 80-56-8EC No: 201-291-9

Classification (EC 1272/2008): Flam. Liq. 3 - H226,  Skin Irrit. 2 - H315,  Skin Sens. 1 - H317, Asp. Tox. 1 - H304

4.1

Description of first aid measures

Inhalation 

Move affected person to fresh air at once. Get medical attention.

Ingestion 

DO NOT INDUCE VOMITING! Get medical attention immediately.

Skin Contact 

Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues.

Eye Contact   

Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention immediately.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Suitable extinguishing media - Foam, carbon dioxide or dry powder.

Unsuitable extinguishing media - Water.

5.2 

Special hazards arising from the product

In case of fire, may be liberated: Carbon monoxide, unidentified organic compounds.

5.3 

Advice for firefighters

Special Fire Fighting Procedures

Closed containers may build up pressure at elevated temperatures. Avoid inhalation of generated fumes or vapours. Use appropriate respiratory equipment. Do not allow spillage of the fire extinguishing to enter drainage systems or water areas.

Protective equipment for fire-fighters

Wear full protective clothing.

6.1 

Personal precautions, protective equipment and emergency procedures

Remove all sources of ignition. Provide adequate ventilation.

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Contain and absorb spillage with sand, earth or other non-combustible material. Collect and place in suitable waste disposal containers and seal securely. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Wash contaminated area with water.

6.4 

Reference to other sections

Wear protective clothing as described in section 8.

7.1 

Precautions for safe handling

Keep away from food, drink and animal feed products. When using do not smoke. Avoid contact with skin and eyes.

7.2 

Conditions for safe storage, including any incompatibilities

Keep away from heat, sparks and open flame. Store in tightly closed original container in a dry, cool and well-ventilated place.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

Linalool (CAS: 78-70-6)

Ingredient CommentsNo exposure limits noted for ingredient(s).

p-Cymene (CAS: 99-87-6)

Ingredient CommentsContains no substances with occupational exposure limit values.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

In case of inadequate ventilation use suitable respirator.

Hand Protection

Chemical resistant gloves (PVC) should be worn.

Eye Protection

Wear approved safety goggles.

Other Protection

No additional data available.

Hygiene Measures

No specific hygiene procedures recommended but good personal hygiene practices should always be observed when working with chemical products.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Wear apron or protective clothing in case of splashes.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid, colourless to pale yellow.

Colour

Colourless to pale yellow.

Odour

Characteristic

Relative Density

0.863 - 0.875 @ 20⁰C

Flash Point (°C)

62 CC (Closed cup)

Refractive Index

1.461 - 1.470 @ 20⁰C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble in water.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under the prescribed storage conditions.

10.3 

Possible hazardous reactions

None known.

10.4 

Conditions to Avoid

Avoid heat, flames and other sources of ignition.

10.5 

Incompatible materials

Avoid; Strong oxidising agents. Strong Acids. Strong Alkali

10.6 

Hazardous Decomposition Products

By fire, toxic gases (CO, CO₂, NO_x) may be formed.

11.1 

Information on toxicological effects 

Acute Toxicity

No additional data available.

Skin corrosion / irritation

No additional data available.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

14.1 

UN number

UN No. Road

3082

UN No. SEA

3082

UN No. AIR

3082

14.2 

UN proper shipping name

ENVIRONMENTALLY HAZARD SUBSTANCE LIQUID, N.O.S

14.3 

Transport hazard class(es)

ADR/RID/ADN  Class:9 Miscellaneous dangerous substances and articles.

IMDG Class:9

ICAO Class:9

Transport Label:

14.4 

Packing group

ADR/RID/ADN Packing group:III

IMDG Packing group:III

ICAO Packing group:III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant.

14.6 

Special precautions for user

EMS F-A-S-F

Emergency Action Code 3Z

Hazard No. (ADR) 90 Environmentally hazardous substance; miscellaneous dangerous                                           substances.

Tunnel Restriction Code (E)

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

-

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H315 Causes skin irritation.

H226 Flammable liquid and vapour.

H332 Harmful if inhaled.

H225 Highly flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.

H371 May cause damage to organs <<Organs>>.

H411 Toxic to aquatic life with long lasting effects.

H410 Very toxic to aquatic life with long lasting effects.

H400 Very toxic to aquatic life.

Other Information

None.

Revision Date

10/10/2016

Reason for revision

New SDS

Rev No/Repl, SDS Generated

01