MSDS - Clove Leaf - Eugenia caryophyllus - Essential Oil

CLOVE LEAF ESSENTIAL OIL
SAFETY DATA SHEET (SDS)

01. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & THE COMPANY/UNDERTAKING

1.1	Product Identifier
Product Name			Clove Leaf Oil.
Biological Definition			Eugenia Caroyphyllus Leaf Oil is an essential oil steam-distilled from the leaves of the Clove, Eugenia caryophyllus, Myrtaceae.
INCI Name			Eugenia Caroyphyllus Leaf Oil.
Synonyms & Trade Names			-
CAS-No		8015-97-2 / 8000-34-8 / 84961-50-2	EC No.		- / - / 284-638-7	EINECS No.	- / - / 284-638-7
1.2	Relative identified uses of the substance or mixture and uses advised against
	Industry Use.
1.3	Details of the supplier of the safety data sheet
	Essential Oils Direct Ltd 13 Parkside Industrial Estate, Royton, Oldham OL2 6DS - Reg No 04199912
1.4	Emergency Tel. No.			+ 44 (0) 161 633 3952

02. HAZARDS IDENTIFICATION

2.1	Classification of the substance or mixture
	The Full Text for all Hazard Statements displayed in Section 16.
Classification (EC 1272/2008)
	Physical and Chemical:Hazards Not classified. Human health: Skin Sensitisation cat. 1 - H317, Aspiration Toxicity cat 1 - H304, Serious eye damage/ eye irritation cat 2 – H319 Environment:Toxic to aquatic life.
2.2		Label Elements
Label in accordance with (EC) No 1272/2008
	GHS07 GHS08 $C:\SharedDrive\Callum\Images & Logo\download.png$
Signal Word			Danger.
Contains			CARYOPHYLLENE, EUGENOL
Hazard Statements
	H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation.
Precautionary Statements
	P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 - IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 - Do NOT induce vomiting.
Supplementary Precautionary Statements
	No additional data available.
2.3		Other Hazards
PBT or vPvB according to Annex XIII			No additional data available.
Adverse physio-chemical properties			No additional data available.
Adverse effects on human health			May be harmful if swallowed.

03. COMPOSITION/INFORMATION ON INGREDIENTS

3.2

Mixtures

84.0 – 88.0% EUGENOL CAS-No: 97-53-0 EC No: 202-589-1

Classification (EC 1272/2008) Aquatic Acute 2 (H401) Skin Sens. 1 (H317) Eye Irrit. 1 (H319), Skin Irrit. 3 (H316) Acute Tox. 5 (H303), Aquatic Acute 2 (H401) (EFFA), Skin Sens. 1 (H317) (EFFA) Eye Irrit. 1 (H319) (EFFA) Skin Irrit. 3 (316) (EFFA), Acute Tox. 5 (H303)(EFFA)

9.0 – 12.0% CARYOPHYLLENE CAS: 87-44-5 EC No: 201-746-1

Classification (EC 1272/2008) Skin Irrit. 3 (H316), Skin Irrit. 3 (316) (EFFA) Asp. Tox. 1 (H304) (EFFA)

04. FIRST AID MEASURES

4.1	Description of first aid measures
Inhalation		Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Ingestion		Rinse mouth with water. DO NOT induce vomiting. Get medical attention.
Skin Contact		Remove contaminated clothing. Wash skin with soap and plenty of water. Get medical attention if any discomfort continues.
Eye Contact		Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if irritation continues.
4.2	Most important symptoms and effects, both acute and delayed
	No additional data available.
4.3	Indication of any immediate medical attention and special treatment needed
	Treat symptomatically.

05. FIRE-FIGHTING MEASURES

5.1	Extinguishing Media
	EXTINGUISHING MEDIA Use as appropriate: CO2, Foam, dry chemical powder.
5.2	Special hazards arising from the product
	Thermal decomposition can lead to release of irritating and toxic gases and vapours. Hazardous combustion products: Irritating or toxic substances may be emitted upon burning, combustion, or decomposition.
5.3	Advice for firefighters
	Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

06. ACCIDENTAL RELEASE MEASURES

6.1	Personal precautions, protective equipment and emergency procedures
	Ensure adequate ventilation, especially in confined areas. Wear protective clothing as described in Section 8 of this safety data sheet.
6.2	Environmental Precautions
	Do not discharge into drains, water courses or onto the ground. Collect spillage.
6.3	Methods and material for containment and cleaning up.
	Absorb with inert, non-combustible, inorganic absorbent material (e.g. sand, earth, diatomaceous earth, vermiculite). Sweep up and remove to an approved disposal container.
6.4	Reference to other sections
	See section 12.

07. HANDLING AND STORAGE

7.1	Precautions for safe handling
	Ensure adequate ventilation, especially in confined areas. Handle in accordance with good industrial hygiene and safety practice.
7.2	Conditions for safe storage, including any incompatibilities
	Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3	Specific end use(s)
	No additional data available.

08. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1	Control parameters
		No additional data available.
8.2	Exposure controls
Protective Equipment

Process Conditions			Provide eyewash station.
Engineering Measures			Ensure adequate ventilation, especially in confined areas.
Respiratory Equipment			Respiratory protection may be required, if ventilation is poor.
Hand Protection			Chemical resistant gloves (PVC)
Eye Protection			Avoid contact with the eyes. Wear approved safety goggles.
Other Protection			No additional data available.
Hygiene Measures			Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.
Personal Protection			Avoid inhalation and contact with skin and eyes.
Skin Protection			Wear apron or protective clothing in case of splashes.
Environmental Exposure Controls			Avoid discharging into drainage water. Only eliminate by authorised companies.

09. PHYSICAL AND CHEMICAL PROPERTIES

9.1	Information on basic physical and chemical properties
Appearance		Clear pale yellow to dark yellow liquid.
Colour		Pale yellow to dark yellow.
Odour		Characteristic.
Relative Density		1.033 - 1.054 @ 20°C
Flash Point (°C)		100
Refractive Index		1.528 - 1.538 @ 20°C
Melting Point (°C)		No additional data available.
Boiling Point (°C)		No additional data available.
Vapour Pressure		0.002
Solubility in Water @20°C		No additional data available.
Auto-ignition temperature (°C)		No additional data available.
9.2	Other information
	No additional data available.

10. STABILITY AND REACTIVITY

10.1		Reactivity
	Stable under normal temperature conditions and recommended use.
10.2		Chemical stability
	Stable under normal temperature conditions and recommended use.
10.3		Possible hazardous reactions
	None under normal use and conditions.
10.4		Conditions to Avoid
	Avoid extremes of temperature and direct sunlight.
10.5		Incompatible materials
	No additional data available.
10.6		Hazardous Decomposition Products
	None under normal use conditions.

11. TOXOLOGICAL INFORMATION

11.1		Information on toxicological effects
	Acute Toxicity		Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document: ATEmix (oral)2,809.00 Oral LD50Dermal LD50 EUGENOL1930mg/kg (Rat)
	Skin corrosion / irritation		No additional data available.
	Serious eye damage / irritation		No additional data available.
	Respiratory or skin sensitisation		No additional data available.
	Germ Cell Mutagenicity		No additional data available.
	Carcinogenicity		No additional data available.
	Reproductive toxicity		No additional data available.
	STOT-single exposure		No additional data available.
	STOT-repeated exposure		No additional data available.
	Aspiration hazard		No additional data available.
	Photo-toxicity		No additional data available.
	Other Information		No additional data available.

12. ECOLOGICAL INFORMATION

12.1		Toxicity
	14 % of the mixture consists of components(s) of unknown hazards to the aquatic environment.
12.2		Persistence & degradability
	No additional data available.
12.3		Bioaccumulation Potential
	No additional data available.
12.4		Mobility in soil
	No additional data available.
12.5		Results of PBT and vPvB Assessment
	Not applicable.
12.6		Other adverse effects
	No additional data available.

13. DISPOSAL CONSIDERATIONS

13.1		Waste treatment methods
	Disposal should be in accordance with applicable regional, national and local laws and regulations. Improper disposal or reuse of the container may be dangerous and illegal.

14. TRANSPORT INFORMATION

14.1		UN number
		UN No. Road	Not regulated.
		UN No. SEA	Not regulated.
		UN No. AIR	Not regulated.
14.2		UN proper shipping name
	None.
14.3		Transport hazard class(es)
	Not regulated.
14.4		Packing group
	Not required.
14.5		Environmental hazards
	None.
14.6		Special precautions for user
	None.
14.7		Transport in bulk according to Annex II of MARPOL73/78 and the IBC code
	No additional data available.

15. REGULATORY INFORMATION

15.1		Safety, health and environmental regulations/legislation specific for the substance or mixture
	Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2		Chemical safety assessment
	No additional information available.

16. OTHER INFORMATION

Hazard and/or Precautionary Statements in Full	H302 - Harmful if swallowed. H316 - Causes mild skin irritation. H401 - Toxic to aquatic life. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H303 - May be harmful if swallowed.
Other Information	None
Revision Date	05/05/2016
Reason for revision	Update to new format
Rev No/Repl, SDS Generated	02

DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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Keywords: Essential Oil, MSDS, Aromatherapy, Clove Leaf, Eugenia caryophyllus