MSDS - Cinnamon Leaf - Cinnamomum zeylanicum - Essential Oil

1.1

Product Identifier 

Product Name 

Cinnamon Leaf Oil.

Biological Definition

"Cinnamon Leaf Oil Ceylon". Cinnamomum Zeylanicum Leaf Oil is the volatile oil obtained from the leaves of the Ceylon Cinnamon, Cinnamomum zeylanicum, Lauraceae.

INCI Name

Cinnamomum Zeylanicum Leaf Oil.

Synonyms & Trade Names

-

CAS-No

84649-98-9

EC No.

283-479-0

EINECS No.

283-479-0

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

No additional data available.

Classification (EC 1272/2008)

Eye irritation, Category 2 (Eye Irrit. 2, H319).

Skin sensitisation, Category 1 (Skin Sens. 1, H317).

Germ cell mutagenicity, Category 2 (Muta. 2, H341).

Carcinogenicity, Category 1B (Carc. 1B, H350).

Hazardous to the aquatic environment - Chronic hazard, Category 3 (Aquatic Chronic 3, H412).

This substance does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

  GHS07     GHS08

Signal Word

Danger

Contains

EC 283-479-0 CINNAMON LEAF OIL

Hazard Statements

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H341 Suspected of causing genetic defects.

H350 May cause cancer.

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.1

Substances

100.0% Cinnamomum Zeylanicum Leaf OilCas. No: 84649-98-9EC No:  283-479-0

Classification (1272/2008):GHS07, GHS08,   Dgr

Skin Sens. 1, H317,  Eye Irrit. 2, H319,   Muta. 2, H341

Carc. 1A, H350,  Aquatic Chronic 3, H412

4.1

Description of first aid measures

Inhalation 

Move the exposed person to fresh air at once. Seek medical attention if discomfort continues.

 Ingestion

Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor. Seek medical attention immediately, showing the label.

Skin Contact 

Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner. Watch out for any remaining product between skin and clothing, watches, shoes, etc. In the event of an allergic reaction, seek medical attention. If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.

Eye Contact   

Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.

If there is any redness, pain or visual impairment, consult an ophthalmologist.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No additional data available.

5.1 

Extinguishing Media

Non Flammable.

5.2 

Special hazards arising from the product

A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not breathe in smoke.

In the event of a fire, the following may be formed:carbon monoxide (CO), carbon dioxide (CO₂).

5.3 

Advice for firefighters

Follow standard fire fighting procedures. Wear self contained breathing apparatus in confined spaces.

6.1 

Personal precautions, protective equipment and emergency procedures

Avoid any contact with skin and eyes. Wear protective equipment such as safety glasses and gloves. Consult the safety measures listed in sections 7 and 8. Fire-fighters will be equipped with suitable personal protective equipment (See section 8).   

6.2 

Environmental Precautions

Do not discharge into drains, water courses or onto the ground. Dispose of in line with Local authority guidelines. Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums.     

6.3 

Methods and material for containment and cleaning up.

Soak up spillage with sand or other inert material. Transfer soaked material to suitable waste container and dispose according to local authority regulations. Clean preferably with a detergent, do not use solvents.

6.4 

Reference to other sections

Section 8 - Exposure controls/personal protection for further information on personal precautions

Section 13 - Disposal Considerations for further information on waste treatment.

7.1 

Precautions for safe handling

Use in a well ventilated area away from sources of ignition in accordance with good occupational hygiene and safety practices. NO SMOKING.

7.2 

Conditions for safe storage, including any incompatibilities

Well filled tightly stoppered containers away from heat, light and ignition. Recommended storage at ambient temperature.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional data available.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Use personal protective equipment that is clean and has been properly maintained. Store personal protective equipment in a clean place, away from the work area. Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using.

Engineering Measures

Ensure that there is adequate ventilation, especially in confined areas.

Respiratory Equipment

Ensure area is well ventilated. Avoid vapour inhalation.

Hand Protection

Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must be selected according to the application and duration of use at the workstation. Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.

Recommended properties:  - Impervious gloves in accordance with standard EN374

Eye Protection

Avoid contact with eyes. Use eye protectors designed to protect against liquid splashes Before handling, wear safety goggles with protective sides in accordance with standard EN166. In the event of high danger, protect the face with a face shield. Prescription glasses are not considered as protection. Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours. Provide eyewash stations in facilities where the product is handled constantly.

Other Protection

Avoid contact with skin and eyes.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils.

Personal Protection 

Avoid contact with skin and eyes.

Skin Protection 

Avoid skin contact. Wear suitable protective clothing. Suitable type of protective clothing:   In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact. In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact. Work clothing worn by personnel shall be laundered regularly. After contact with the product, all parts of the body that have been soiled must be washed.

Environmental Exposure Controls 

Avoid discharging into drainage water.

9.1 

Information on basic physical and chemical properties 

Appearance

Limpid liquid, yellow brown to dark brown. 

Colour

Yellow brown to dark brown.

Odour

Characteristic – spicy, sweet.

Relative Density

1.030   -  1.050  @20°C

Flash Point (°C)

88.0

Refractive Index

1.529  -  1.537   @20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

Insoluble. (soluble in 2 volumes maximum of ethanol 70%).

Auto-ignition temperature (°C)

380.0

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Chemically stable under the recommended handling and storage conditions.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

No additional data available.

10.5 

Incompatible materials

No additional data available.

10.6 

Hazardous Decomposition Products

In the event of a fire, the following may be formed:carbon monoxide (CO), carbon dioxide (CO2).

11.1 

Information on toxicological effects 

Acute Toxicity

CINNAMON LEAF OIL (CAS: 84649-98-9)

Oral route:DL50 = 2650 mg/kg

Species : Rat (recommended by the CLP)

Dermal route: DL50 > 5000 mg/kg

Species : Rabbit (recommended by the CLP)

Skin corrosion / irritation

May cause an allergic reaction by skin contact.

Serious eye damage / irritation

May have reversible effects on the eyes, such as eye irritation which is totally reversible by the end of observation at 21 days.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

Cause for concern owing to the possibility that it may induce heritable mutations in the germ cells of humans.

Carcinogenicity

Presumed human carcinogen.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

Harmful to aquatic life with long lasting effects. The product must not be allowed to run into drains or waterways.

Substances classified as category 1 acute toxicity:

Crustacean toxicity: Duration of exposure : 48 h

CE50 = 1.61 mg/l

Species: Daphnia sp.

OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test)

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

No additional data available.  

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

Do not allow product to enter streams, sewers or other waterways.

13.1 

Waste treatment  methods

Do not pour into drains or waterways.

Waste:

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals. Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company. Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging:

Empty container completely. Keep label(s) on container. Give to a certified disposal contractor.

14.1 

UN number

UN No. Road

Not bound by transport regulations. 

UN No. SEA

Not bound by transport regulations. 

UN No. AIR

Not bound by transport regulations. 

14.2 

UN proper shipping name

Not bound by transport regulations. 

14.3 

Transport hazard class(es)

Not bound by transport regulations. 

14.4 

Packing group

Not bound by transport regulations. 

14.5 

Environmental hazards

No additional data available.

14.6 

Special precautions for user

See sections 6 – 8. 

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Approved Code of Practise

Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations.

Guidance Notes

CHIP for everyone HSG(108). Workplace Exposure Limits EH40

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional data available.

Hazard and/or Precautionary Statements in Full

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H341 Suspected of causing genetic defects.

H350 May cause cancer.

H412 Harmful to aquatic life with long lasting effects.

Other Information

None.

Revision Date

21/07/2016

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01