MSDS - Carrot Seed - Daucus carota sativa - Essential Oil

1.1

Product Identifier 

Product Name 

Carrot Seed Oil.

Biological Definition

Daucus Carota Sativa Seed Oil is the oil obtained by steam distillation from the seed of the carrot, Daucus carota L. var. sativa, Umbelliferae.

INCI Name

Daucus Carota Sativa Seed Oil

Synonyms & Trade Names

-

CAS-No

8015-88-1 / 84929-61-3

EC No.

- / 284-545-1

EINECS No.

- / 284-545-1

1.2

Relative identified uses of the substance or mixture and uses advised against

No additional data available.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements is displayed in Section 16.

Classification (EC 1272/2008)

Physical and Chemical Hazards Flam. Liq. 3  -  H226

Human healthAsp Tox 1 – H304

                                                                         Skin Irrit 2 – H315; Eye Irrit 2 – H319; Skin sens 1 – H317;
Environment Aquatic Chronic 2 – H411

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

         GHS02              GHS08    GHS07                 GHS09

Signal Word

Danger.

Contains

Beta Pinene, Trans-Beta-Farnesene, p-Cymene, Myrcene, Limonene

Hazard Statements

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 

P370+P378: In case of fire: Use water to extinguish. 

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. 

P331: Do NOT induce vomiting. 

P280: Wear protective gloves/protective clothing/eye protection/face protection. 

P501: Dispose of contents in accordance with local, state or national legislation. 

P261: Avoid breathing dust/fume/gas/mist/vapours/spray. 

P333+P313: If skin irritation or rash occurs: Get medical advice/attention. 

P362+P364: Take off contaminated clothing. And wash it before reuse. 

P302+P352: IF ON SKIN: Wash with plenty of water. 

P273: Avoid release to the environment. 

P391: Collect spillage. 

Supplementary Precautionary Statements

P233: Keep container tightly closed. 

P405: Store locked up. 

P264: Wash hands and exposed skin thoroughly after handling. 

P272: Contaminated work clothing should not be allowed out of the workplace

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

No additional data available.

Adverse effects on human health

No additional data available.

3.2

Mixtures

10 – 20 % Alpha Pinene CAS No: 80-56-8 EC No: 201-291-9

Classification (EC 1272/2008)    Flam. Liq. 3 – H226, Skin Sens. 1 – H317, Skin Irrit. 2 – H315, Asp. Tox. 1 – H304, Aquatic Acute 1 – H400, Aquatic Chronic 1 – H410

1 – 5 % Geranyl Acetate CAS No: 105-87-3 EC No: 203-341-5

Classification (EC 1272/2008)    Skin Irrit. 2 – H315, Skin Sens. 1- H317, Aquatic Chronic 3 – H412

1-5% Caryophyllene Oxide   CAS No: 1139-30-6 EC No: 214-519-7

Classification (EC 1272/2008) Aquatic Chronic 2 – H411

1 – 5% I-Beta-Bisabolene CAS No: 495-61-4  EC No: 610-461-5

Classification (EC 1272/2008) Asp. Tox. 1 – H304, Skin Irrit. 2 – H315,   Skin Sens. 1 – H317

1 - 5% Beta Pinene CAS No: 127-91-3 EC No: 204-872-5

Classification (EC 1272/2008)    Flam. Liq. 3 – H226, Skin Sens. 1 – H317, Skin Irrit. 2 – H315, Asp. Tox. 1 – H304, Aquatic Acute 1 – H400,  Aquatic Chronic 1 – H410

1 - 5% Trans-Beta-Farnesene CAS No: 18794-84-8 EC No: 242-582-0

Classification (EC 1272/2008)  Asp. Tox. 1 – H304

1 – 5% p-Cymene CAS No: 99-87-6 EC No. 202-796-7

Classification (EC 1272/2008) Flam. Liq. 3 – H226, Asp. Tox. 1 – H304, Aquatic Chronic 2 – H411       

1 – 5% Myrcene CAS No: 99-87-6 EC No:202-796-7

Classification (EC 1272/2008) Flam. Liq. 3  - H226,  Asp. Tox. 1 – H304, Aquatic Chronic 2 -H411

1 - 5% Limonene CAS No: 138-86-3 EC No: 205-341-0

Classification (EC 1272/2008)    Flam. Liq. 3 – H226, Skin Irrit. 2 – H315, Skin Sens. 1 – H317,

  Asp. Tox. 1 – H304,  Aquatic Acute 1 – H400,  Aquatic Chronic 1 – H410

4.1

Description of first aid measures

Inhalation 

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air at once Get medical attention if any discomfort continues.

 Ingestion

No specific health warnings noted. No harmful effects expected in amounts likely to be ingested by accident. Seek medical advice if discomfort occurs.

Skin Contact 

If necessary remove contaminated clothing and wash skin with soap and water. Get medical attention if any discomfort continues.

Eye Contact   

Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues.

Ingestion: If necessary, rinse mouth and provide fresh air. Get medical attention if any discomfort continues.

4.2

Most important symptoms and effects, both acute and delayed

No additional data available.

4.3

Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

5.1 

Extinguishing Media

Suitable extinguishing media: dry chemical powder. foam. carbon dioxide (CO₂).

5.2 

Special hazards arising from the product

Containers close to fire should be removed or cooled with water. No unusual fire or explosion hazards noted. When heated and in case of fire, toxic vapours/gases may be formed.

5.3 

Advice for firefighters

Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6.1 

Personal precautions, protective equipment and emergency procedures

Use protective gloves, goggles and suitable protective clothing. In case of spills, beware of slippery floors and surfaces.

6.2 

Environmental Precautions

Avoid discharge into water courses or onto the ground.

6.3 

Methods and material for containment and cleaning up.

Absorb with inert, damp, non-combustible material, and then flush area with water. Shovel into dry containers. Cover and move the containers. Flush the area with water.

6.4 

Reference to other sections

Wear protective clothing as described in Section 8 of this safety data sheet.

7.1 

Precautions for safe handling

Avoid spilling, skin and eye contact. Ensure adequate ventilation of the working Area. Adopt best manual handling considerations when handling, carrying and dispensing.

7.2 

Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well ventilated place. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

No additional data available.

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station and safety shower.

Engineering Measures

Provide adequate ventilation.

Respiratory Equipment

No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.

Hand Protection

Protective gloves should be used if there is a risk of direct contact or splash.

Eye Protection

If risk of splashing, wear safety goggles or face shield.

Other Protection

Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area.

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas.

Personal Protection 

Avoid inhalation and contact with skin and eyes.

Skin Protection 

Avoid skin contact. Wear suitable protective clothing.

Environmental Exposure Controls 

Avoid discharging into drainage water.

9.1 

Information on basic physical and chemical properties 

Appearance

Mobile liquid

Colour

Light yellow to amber

Odour

Fresh herbaceous woody with earthy undertone

Relative Density

~0.940 @ 20°C

Flash Point (°C)

60.0

Refractive Index

~1.500@ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

No additional data available.

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under normal temperature conditions.

10.3 

Possible hazardous reactions

No additional data available.

10.4 

Conditions to Avoid

Avoid heat, flames and other sources of ignition.

10.5 

Incompatible materials

Avoid strong oxidising substances. Strong acids. Strong Alkalis.

10.6 

Hazardous Decomposition Products

In case of fire, toxic gases (CO, CO₂, NO_x) may be formed.

11.1 

Information on toxicological effects 

Acute Toxicity

No data available on this product. It must be considered, handled and should be dealt with the highest possible caution.

Skin corrosion / irritation

Causes skin irritation. May cause an allergic skin reaction.

Serious eye damage / irritation

Causes serious eye irritation.

Respiratory or skin sensitisation

In high concentrations, vapours may irritate throat and respiratory system and cause coughing.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

Ingestion: May be fatal if swallowed and enters airways Ingestion

MEDICAL CONSIDERATIONS: Persons with rash are directed to skin expert for examination of allergic eczema.

12.1 

Toxicity

Toxic to aquatic life with long lasting effects.

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

No additional data available.

12.4 

Mobility in soil

The product is insoluble in water.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

No additional data available.

13.1 

Waste treatment  methods

Do not pour into drains or waterways.

Waste is suitable for incineration.

Dispose of in accordance with local, regional and national regulations. Seek expert advice.

14.1 

UN number

UN No. Road

UN 1169

UN No. SEA

UN 1169

UN No. AIR

UN 1169

14.2 

UN proper shipping name

EXTRACTS, AROMATIC, LIQUID.

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:  3: Flammable liquid.

IMDG Class:3: Flammable liquid.

ICAO Class/Division:3: Flammable liquid.

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6 

Special precautions for user

ADR Tunnel restriction code: (D/E)

ADR Hazard No:30

ADR Label No:3

HazChem Code:•3YE

EMS:F-E, S-D

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Other Information

None.

Revision Date

06/12/2016

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01