MSDS - Camphor - Cinnamomum camphora - Essential Oil

1.1

Product Identifier 

Product Name 

Camphor Oil White

Biological Definition

Cinnamomum Camphora Bark Oil is the volatile oil expressed, by steam distillation, from the bark of the Camphor, Cinnamomum camphora (L.), Lauraceae.

INCI Name

Cinnamomum Camphora Bark Oil

Synonyms & Trade Names

-

CAS-No

92201-50-8 / 8022-91-1 / 8008-51-3

EC No.

295-980-1 / - / -

EINECS No.

295-980-1 / - / -

1.2

Relative identified uses of the substance or mixture and uses advised against

Recommended use;Industry Use.

1.3

Details of the supplier of the safety data sheet 

Essential Oils Direct Ltd  13 Parkside Industrial Estate,  Royton, Oldham OL2 6DS - Reg No 04199912 

1.4 

Emergency Tel. No.  

+ 44 (0) 161 633 3952

2.1

Classification of the substance or mixture 

The Full Text for all Hazard Statements displayed in Section 16.

Classification (EC 1272/2008)

Aspiration toxicity Category 1 - (H304).

Skin corrosion/irritation Category 2 - (H315).

Serious eye damage/eye irritation Category 2 - (H319).

Skin sensitization Category 1 - (H317).

Chronic aquatic toxicity Category 2 - (H411).

Flammable LiquidsCategory 3 - (H226).

2.2 

Label Elements 

Label in accordance with (EC) No 1272/2008   

      GHS02GHS07           GHS08  GHS09

Signal Word

Danger.

Contains

D-LIMONENE, ALPHA-TERPINENE, D-3-CARENE, PARA-CYMENE.

Hazard Statements

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 - Causes serious eye irritation.

H411 - Toxic to aquatic life with long lasting effects.

Precautionary Statements

P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P370 + P378 - In case of fire: Use dry sodium carbonate to extinguish.

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.

P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331 - Do NOT induce vomiting.

P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.

P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 - If eye irritation persists: Get medical advice/attention.

P273 - Avoid release to the environment.

Supplementary Precautionary Statements

None.

2.3

Other Hazards 

PBT or vPvB according to Annex XIII

No additional data available.

Adverse physio-chemical properties

Toxic to aquatic life.

Adverse effects on human health

May be harmful if swallowed.

3.1

Substances

35-40% EUCALYPTOL CAS No:470-82-6EC No: 207-431-5 

Classification (EC 1272/2008) Skin Irrit. 3 (H316) Acute Tox. 5 (H303),   Skin Irrit. 3 (316) (EFFA)

Acute Tox. 5 (H303)(EFFA),   Flam. Liq. 3 (H226)(EFFA)

15-40% D-LIMONENE,CAS No: 5989-27-5EC No: 227-813-5

Classification (EC 1272/2008) Aquatic Acute 1 (H400)(EFFA),   Skin Sens. 1 (H317) (EFFA)

Skin Irrit. 2 (315) (EFFA),    Asp. Tox. 1(H304) (EFFA),  

Aquatic Chronic 1 (H410) (EFFA),   Flam. Liq. 3 (H226)(EFFA)

Skin Irrit. 2 (H315),   Skin Sens. 1 (H317)

Aquatic Acute 1 (H400),  Aquatic Chronic 1 (H410),  Flam. Liq. 3 (H226)

5-15% ALPHA-TERPINENE CAS No: 99-86-5EC No: 202-795-1

Classification (EC 1272/2008) Aquatic Acute 2 (H401) (EFFA),  Skin Irrit. 3 (316) (EFFA),

Aquatic Chronic 2 (H411) (EFFA), Asp. Tox. 1 (H304) (EFFA),

 Acute Tox. 4 (H302) (EFFA), Flam. Liq. 3 (H226)(EFFA),Aquatic Acute 2 (H401),                                           Skin Irrit. 3 (H316), Aquatic Chronic 2 (H411), Acute Tox. 4 (H302)

5-20% D-3-CARENECAS No:13466-78-9EC No: 236-719-3

Classification (EC 1272/2008) Skin Sens. 1 (H317) (EFFA), Skin Irrit. 2 (315) (EFFA), Asp. Tox. 1 (H304) (EFFA)                                           Acute Tox. 5 (H303)(EFFA), Flam. Liq. 3 (H226)(EFFA),

Skin Sens. 1 (H317), Skin Irrit. 2 (H315), Acute Tox. 5 (H303)

2.5-10% PARA-CYMENECAS No99-87-6EC No: 202-796-7

Classification (EC 1272/2008)  Aquatic Acute 2 (H401) (EFFA),  Skin Irrit. 3 (316) (EFFA),

Aquatic Chronic 2 (H411) (EFFA), Asp. Tox. 1 (H304) (EFFA),

Acute Tox. 5 (H303)(EFFA), Flam. Liq. 3 (H226)(EFFA), Aquatic Acute 2 (H401),                                           Skin Irrit. 3 (H316), Aquatic Chronic 2 (H411), Acute Tox. 5 (H303)

4.1

Description of first aid measures

Inhalation 

Move to fresh air in case of accidental inhalation of vapours. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.

Ingestion

Do not induce vomiting without medical advice. Clean mouth with water. Never give anything by mouth to an unconscious person. Get medical attention.

Skin Contact 

Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water. Wash contaminated clothing before reuse. Consult a physician if necessary.

Eye Contact   

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

4.2

Most important symptoms and effects, both acute and delayed

SymptomsNone known.

4.3

Indication of any immediate medical attention and special treatment needed

Note to physiciansTreat symptomatically.

5.1 

Extinguishing Media

Suitable extinguishing media:CO₂, Dry powder, Foam.

5.2 

Special hazards arising from the product

Thermal decomposition can lead to release of irritating and toxic gases and vapours.

Hazardous combustion products - Irritating or toxic substances may be emitted upon burning, combustion, or decomposition.

5.3 

Advice for firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

6.1 

Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation, especially in confined areas. Use personal protection recommended in Section 8.

6.2 

Environmental Precautions

Collect spillage.

6.3 

Methods and material for containment and cleaning up.

Methods for Containment.

Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).

Methods for cleaning up.

Cover liquid spill with sand, earth or other non-combustible absorbent material. Sweep up and shovel into suitable containers for disposal.

6.4 

Reference to other sections

See Section 12: ECOLOGICAL INFORMATION.

7.1 

Precautions for safe handling

Advice on safe handlingEnsure adequate ventilation, especially in confined areas.

General hygiene considerationsHandle in accordance with good industrial hygiene and safety practice.

7.2 

Conditions for safe storage, including any incompatibilities

Storage

Keep container tightly closed in a dry and well-ventilated place.

7.3 

Specific end use(s) 

No additional data available.

8.1 

Control parameters 

Chemical NameEU/ UK       Italy/Austria/

Poland/Netherlands/

           IrelandFranceGermany

LimoneneTWA:1000mg/m³TWA: 5ppm

5889-27-5--STEL:1500mg/m³TWA: 28mg/m3

Ceiling/Peak: 20ppm

Ceiling/Peak: 112mg/m³ Skin

D-3-CareneTWA:1000mg/m³

13466-78-6--STEL:1500mg/m³-

Alpha-TerpineneTWA:1000mg/m³

99-86-5-STEL:1500mg/m³-

Para-CymeneTWA:150mg/m³

99-87-6-TWA:1000mg/m³-

STEL:1500mg/m³

Chemical NamePortugalFinlandDenmarkSwitzerlandNorway

LimoneneTWA: 25 ppm STEL: 14ppmSTEL: 37.5 ppm

5889-27-5-TWA: 140 mg/m³      -STEL: 80mg/m³STEL: 175 mg/m³

STEL: 50ppmTWA: 7ppmTWA: 25ppm

STEL: 260mg/m³TWA: 40mg/m³TWA: 140 mg/m³

D-3-CareneTWA: 25ppm

13466-78-6TWA: 20ppm-    -   -TWA: 140mg/m³

STEL: 25 ppm

STEL: 140mg/m³

Para-CymeneTWA:25ppm

99-87-6-TWA:135mg/m³-

Chemical NameSpain

D-3-CareneTWA: 20ppm

13466-78-6TWA: 113 mg/m³

8.2 

Exposure controls 

Protective Equipment

Process Conditions 

Provide eyewash station.

Engineering Measures

Ensure adequate ventilation, especially in confined areas.

Respiratory Equipment

Provide adequate ventilation.

Hand Protection

Wear suitable protective clothing.

Eye Protection

Avoid contact with eyes. Wear safety glasses with side shields (or goggles).

Other Protection

No additional data available.  

Hygiene Measures

Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed.

Personal Protection 

Wear suitable protective clothing.

Skin Protection 

Wear suitable protective clothing.

Environmental Exposure Controls 

Avoid discharging into drainage water. Only eliminate by authorised companies.

9.1 

Information on basic physical and chemical properties 

Appearance

Clear liquid, colourless to pale yellow.

Colour

Colourless to pale yellow.

Odour

Characteristic

Relative Density

0.855 – 0.910 @ 20°C

Flash Point (°C)

45.0

Refractive Index

1.462 – 1.475 @ 20°C

Melting Point (°C)

No additional data available.

Boiling Point (°C)

No additional data available.

Vapour Pressure

< 0.001

Solubility in Water @20°C

No additional data available.

Auto-ignition temperature (°C)

No additional data available.

9.2 

Other information 

No additional data available.

10.1 

Reactivity

No additional data available.

10.2 

Chemical stability

Stable under normal conditions.

Explosion data

Sensitivity to Mechanical ImpactNone.

Sensitivity to Static DischargeNone.

10.3 

Possible hazardous reactions

No possibility of hazardous reactions under normal processing.

10.4 

Conditions to Avoid

Avoid extremes of temperature and direct sunlight.

10.5 

Incompatible materials

No additional data available.

10.6 

Hazardous Decomposition Products

None under normal use conditions.

11.1 

Information on toxicological effects 

Acute Toxicity

Product does not present an acute toxicity hazard based on known or supplied information.

InhalationNo data available.

Eye ContactNo data available.

Skin contactNo data available.

IngestionNo data available.

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral)2,800.00

ATEmix (dermal)24,444.00

Unknown acute toxicity

12% of the mixture consists of ingredient(s) of unknown toxicity.

Chemical NameOral LD50      Dermal LD50      Inhalation LC50

EUCALYPTOL= 2480 mg/kg (Rat)

D-LIMONENE, = 4400 mg/kg (Rat)  > 5 g/kg (Rabbit)

ALPHA-TERPINENE= 1680 mg/kg (Rat)

D-3-CARENE= 4800 mg/kg (Rat)

PARA-CYMENE = 3669 mg/kg (Rat)

Skin corrosion / irritation

No additional data available.

Serious eye damage / irritation

No additional data available.

Respiratory or skin sensitisation

No additional data available.

Germ Cell Mutagenicity

No additional data available.

Carcinogenicity

No additional data available.

Reproductive toxicity

No additional data available.

STOT-single exposure

No additional data available.

STOT-repeated exposure

No additional data available.

Aspiration hazard

No additional data available.

Photo-toxicity

No additional data available.

Other Information

No additional data available.

12.1 

Toxicity

24 % of the mixture consists of components(s) of unknown hazards to the aquatic environment

Chemical NameEucalyptolD-Limonene

Algae/aquatic plants        -       -

Fish95.4 - 109: 96 h 0.619 - 0.796: 96 h Pimephales promelas

Pimephales promelas mg/L mg/L LC50 flow-through 35: 96 h

LC50 flow-throughOncorhynchus mykiss mg/L LC50

Crustacea        -      -

12.2 

Persistence & degradability

No additional data available.

12.3 

Bioaccumulation Potential

Para-CymenePartition Co-efficient = 4.1

12.4 

Mobility in soil

No additional data available.

12.5 

Results of PBT and vPvB Assessment

No additional data available.

12.6 

Other adverse effects

Do not discharge into the environment especially not into waterways, sewers and the sea.

13.1 

Waste treatment  methods

Waste from Residues / Unused Products

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging

Improper disposal or reuse of this container may be dangerous and illegal.

14.1 

UN number

UN No. Road

2319

UN No. SEA

2319

UN No. AIR

2319

14.2 

UN proper shipping name

Terpenes; hydrocarbons NOS

14.3 

Transport hazard class(es)

ADR/RID/ADN Class:3 Flammable Liquid. 

IMDG Class:3 Flammable Liquid.

ICAO Class/Division:3 Flammable Liquid.

Transport Labels

14.4 

Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5 

Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant.

14.6 

Special precautions for user

No additional data available.

14.7 

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code

No additional data available.

15.1 

Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Guidance Notes

Workplace Exposure Limits EH40. CHIP for everyone HSG(108).

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 

Chemical safety assessment

No additional information available.

Hazard and/or Precautionary Statements in Full

H226 - Flammable liquid and vapour.

H302 - Harmful if swallowed.

H303 - May be harmful if swallowed.

H304 - May be fatal if swallowed and enters airways.

H315 - Causes skin irritation.

H316 - Causes mild skin irritation

H317 - May cause an allergic skin reaction.

H319 - Causes serious eye irritation.

H400 - Very toxic to aquatic life.

H410 - Very toxic to aquatic life with long lasting effects.

H411 - Toxic to aquatic life with long lasting effects.

Other Information

None.

Revision Date

07/09/2016

Reason for revision

New SDS.

Rev No/Repl, SDS Generated

01